Structural, computational, fluorescent properties and antibacterial properties insights into perfect self-assembly of a novel ring-shaped dinuclear copper(Ⅱ) complex based on a bis(salamo)-type ligand

Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 141535 - 141535

Опубликована: Янв. 1, 2025

Язык: Английский

---

Experimental and computational study of Ni(II) and Zn(II) complexes of isatin-3-thiosemicarbazone: Structure, biological activity and ct-DNA binding study

Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 141846 - 141846

Опубликована: Фев. 1, 2025

Язык: Английский

---

Zn (II) Complexes Synthesized With Salamo‐Type Ligand as a Highly Efficient Sensor to Detect MnO₄⁻ in Aqueous Solution

Applied Organometallic Chemistry, Год журнала: 2025, Номер 39(5)

Опубликована: Апрель 1, 2025

ABSTRACT Herein, Three Salamo‐type Zn (II) complexes [Zn 2 (L)( μ ‐OAc)]·CH 3 OH ( 1 ), 4 (L) ]Cl ](NO ) is synthesized as the fluorescence probe for ultrasensitive detection of MnO − in aqueous solution. The structure analysis shows that complex a binuclear structure, while and symmetric tetranuclear structure. exhibited high stability intensity solvent. limit 8.8, 12.8 13.8 μM. anions involved coordination undergo structural changes due to their different modes compared with , resulting better performance than other two complexes. have good selectivity applicability determination solutions. At same time, sensing effect real water samples was also detected. In addition, recognition mechanisms three above analytes were explored detail.

Язык: Английский

---

Experimental and theoretical studies on a salamo-derived biscompartmental ligand and its rare tetranuclear Zn(II) complexes containing solvent effect

Journal of Molecular Structure, Год журнала: 2024, Номер 1321, С. 140191 - 140191

Опубликована: Сен. 26, 2024

Язык: Английский

---