Zn (II) Complexes Synthesized With Salamo‐Type Ligand as a Highly Efficient Sensor to Detect MnO4− in Aqueous Solution DOI

Na Tuo,

Lele Liu, Jun Ren

и другие.

Applied Organometallic Chemistry, Год журнала: 2025, Номер 39(5)

Опубликована: Апрель 1, 2025

ABSTRACT Herein, Three Salamo‐type Zn (II) complexes [Zn 2 (L)( μ ‐OAc)]·CH 3 OH ( 1 ), 4 (L) ]Cl ](NO ) is synthesized as the fluorescence probe for ultrasensitive detection of MnO − in aqueous solution. The structure analysis shows that complex a binuclear structure, while and symmetric tetranuclear structure. exhibited high stability intensity solvent. limit 8.8, 12.8 13.8 μM. anions involved coordination undergo structural changes due to their different modes compared with , resulting better performance than other two complexes. have good selectivity applicability determination solutions. At same time, sensing effect real water samples was also detected. In addition, recognition mechanisms three above analytes were explored detail.

Язык: Английский

Zn (II) Complexes Synthesized With Salamo‐Type Ligand as a Highly Efficient Sensor to Detect MnO4− in Aqueous Solution DOI

Na Tuo,

Lele Liu, Jun Ren

и другие.

Applied Organometallic Chemistry, Год журнала: 2025, Номер 39(5)

Опубликована: Апрель 1, 2025

ABSTRACT Herein, Three Salamo‐type Zn (II) complexes [Zn 2 (L)( μ ‐OAc)]·CH 3 OH ( 1 ), 4 (L) ]Cl ](NO ) is synthesized as the fluorescence probe for ultrasensitive detection of MnO − in aqueous solution. The structure analysis shows that complex a binuclear structure, while and symmetric tetranuclear structure. exhibited high stability intensity solvent. limit 8.8, 12.8 13.8 μM. anions involved coordination undergo structural changes due to their different modes compared with , resulting better performance than other two complexes. have good selectivity applicability determination solutions. At same time, sensing effect real water samples was also detected. In addition, recognition mechanisms three above analytes were explored detail.

Язык: Английский

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