Cobalt(II) and Cadmium(II) Metal–Organic Framework with Benzene-1,3,5-tricarboxylate and Viologen Guest: Stimuli-Responsive Photochromism, Volatile Amine Detection, and Hydrogen Generation DOI Creative Commons

Ferihan Tataş Coşkun,

Kutalmış Gökkuş, Okan Zafer Yeşılel

и другие.

ACS Omega, Год журнала: 2025, Номер 10(16), С. 16938 - 16951

Опубликована: Апрель 17, 2025

Two Co(II) and Cd(II) coordination polymers, {(Me2bipy)[Co5(btc)3(Hbtc)(OH)]·2DMF·9H2O} n (CoMOF) {(Me2bipy)[Cd2(μ4-btc)2]} (OGU-2), were synthesized characterized using IR spectroscopy, elemental analysis, powder single-crystal X-ray diffraction techniques. The Cd1 ion is seven-coordinated, adopting a distorted monocapped trigonal prismatic geometry (CdO7). OGU-2 exhibits 3D porous framework with rare flu-3,6-C2/c topology. contains one-dimensional channels along the c axis dimensions of approximately 10 × Å2. photochromic behavior was investigated, revealing excellent chromic properties in response to multiple external stimuli, including UV light, temperature, organic amines. CoMOF, polymer reported previously, OGU-2, evaluated as catalyst for hydrogen gas production via methanolysis reaction NaBH4. results demonstrated that these polymers exhibited high catalytic activity production, comparable values literature.

Язык: Английский

Structure and photochromic properties of two metal-viologen complexes derived from 1-amyl-4,4′-bipyridinium ligand DOI

Haibing Han,

Li Lin,

Jinjian Liu

и другие.

Journal of Molecular Structure, Год журнала: 2025, Номер 1334, С. 141933 - 141933

Опубликована: Март 2, 2025

Язык: Английский

Процитировано

0
Cobalt(II) and Cadmium(II) Metal–Organic Framework with Benzene-1,3,5-tricarboxylate and Viologen Guest: Stimuli-Responsive Photochromism, Volatile Amine Detection, and Hydrogen Generation DOI Creative Commons

Ferihan Tataş Coşkun,

Kutalmış Gökkuş, Okan Zafer Yeşılel

и другие.

ACS Omega, Год журнала: 2025, Номер 10(16), С. 16938 - 16951

Опубликована: Апрель 17, 2025

Two Co(II) and Cd(II) coordination polymers, {(Me2bipy)[Co5(btc)3(Hbtc)(OH)]·2DMF·9H2O} n (CoMOF) {(Me2bipy)[Cd2(μ4-btc)2]} (OGU-2), were synthesized characterized using IR spectroscopy, elemental analysis, powder single-crystal X-ray diffraction techniques. The Cd1 ion is seven-coordinated, adopting a distorted monocapped trigonal prismatic geometry (CdO7). OGU-2 exhibits 3D porous framework with rare flu-3,6-C2/c topology. contains one-dimensional channels along the c axis dimensions of approximately 10 × Å2. photochromic behavior was investigated, revealing excellent chromic properties in response to multiple external stimuli, including UV light, temperature, organic amines. CoMOF, polymer reported previously, OGU-2, evaluated as catalyst for hydrogen gas production via methanolysis reaction NaBH4. results demonstrated that these polymers exhibited high catalytic activity production, comparable values literature.

Язык: Английский

Процитировано

0