Hydrogen and Oxygen Evolution on Flexible Catalysts Based on Nickel–Iron Coatings DOI Open Access

Dmytro Shyshkin,

Loreta Tamašauskaitė–Tamašiūnaitė,

Dijana Šimkūnaitė

и другие.

Catalysts, Год журнала: 2024, Номер 14(12), С. 843 - 843

Опубликована: Ноя. 22, 2024

The electrolysis of water is one low-cost green hydrogen production technologies. main challenge regarding this technology designing and developing high-activity catalysts. Herein, we present a strategy to fabricate flexible electrocatalysts based on nickel–iron (NiFe) alloy coatings. NiFe coatings were plated the copper-coated polyimide surface (Cu/PI) using straightforward electroless metal-plating method, with morpholine borane as reducing agent. It was found that Ni90Fe10, Ni80Fe20, Ni60Fe40, Ni30Fe70 deposited Cu/PI surface; then, concentration Fe2+ in plating solution 0.5, 1, 5, 10 mM, respectively. morphology, structure, composition NixFey/Cu/PI catalysts have been examined scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), diffraction (XRD), inductively coupled plasma–optical emission (ICP-OES), whereas their activity has investigated for evolution (HER) oxygen (OER) reactions 1 M KOH linear sweep voltammetry (LSVs). Ni80Fe20/Cu/PI catalyst exhibited lowest overpotential value −202.7 mV HER, obtaining current density mA cm−2 compared Ni90Fe10/Cu/PI (−211.9 mV), Ni60Fe40/Cu/PI (−276.3 Ni30Fe70/Cu/PI (−278.4 Ni (−303.4 mV). On other hand, OER (344.7 mV) observed catalyst, Ni35Fe65 (369.9 Ni80Fe20 (450.2 Ni90Fe10 (454.2 coatings, (532.1 developed exhibit cell potential 1.85 V at cm−2. obtained seem be suitable HER alkaline media.

Язык: Английский

Synergetic FeMoSe@NiCo-LDH hybrid heterostructures as a stable and effective bifunctional catalyst for sustained overall water splitting and seawater splitting DOI
Rajathsing Kalusulingam, Mariyamuthu Mariyaselvakumar,

Selvam Mathi

и другие.

Journal of Alloys and Compounds, Год журнала: 2024, Номер 1002, С. 175389 - 175389

Опубликована: Июнь 28, 2024

Язык: Английский

Процитировано

12

Financial multidimensional assessment of a green hydrogen generation process via an integrated artificial intelligence-based four-stage fuzzy decision-making model DOI
Serhat Yüksel, Hasan Dınçer, Merve Acar

и другие.

International Journal of Hydrogen Energy, Год журнала: 2024, Номер 83, С. 577 - 588

Опубликована: Авг. 13, 2024

Язык: Английский

Процитировано

4

Coherent Design of CoAl Layered Double Hydroxide-Derived Co3O4 Cubes as a Competent Electrocatalyst for Water Splitting and Urea Electrolysis DOI
Rajathsing Kalusulingam, Mariyamuthu Mariyaselvakumar,

Selvam Mathi

и другие.

Energy & Fuels, Год журнала: 2024, Номер 38(12), С. 10789 - 10800

Опубликована: Июнь 10, 2024

Here, we studied the electrocatalytic activity of a CoAl-LDH-derived Co3O4 cube, which has an amplified electrochemical surface area and conductivity, in turn escalates performance. The cubic promotes OER, HER, UOR with significantly lower potentials 1.51, 0.192, 1.36 V at 10 mA cm–2 current density; this performance addresses kinetic challenges associated electrolytic reactions effective manner. Moreover, assembled full-cell water electrolyzer employing cube//Co3O4 cube as both cathode anode, achieving various densities 10, 20, 50, 100 corresponding cell voltages 1.49, 1.72, 1.83, 1.95 V. In addition, synthesized cubes demonstrate excellent urea performance, maintaining stable 1.40, 1.47, 1.57, 1.70 under similar densities. Notably, electrocatalyst exhibited sustained stability over 24 h, voltage 1.72 alkaline 1.0 M KOH solution 1.47 + 0.5 solution, showing reduction 275 mV compared to overall density 20 cm–2.

Язык: Английский

Процитировано

3

Eco-Friendly Synthesis and Multifaceted Environmental Applications of AgCu Bimetallic Nanoparticles DOI Creative Commons

T. K. Nanditha,

P S Vishwashreelakshmi,

Shreepooja Bhat

и другие.

Materials Research Bulletin, Год журнала: 2024, Номер unknown, С. 113233 - 113233

Опубликована: Ноя. 1, 2024

Язык: Английский

Процитировано

3

Efficient hydrogen evolution of a low-cost novel green chickpea shell-derived carbon-metal composite in alkaline electrolytes DOI

Tasneem M. A. Khan,

Pradip B. Sarawade

Journal of Porous Materials, Год журнала: 2025, Номер unknown

Опубликована: Апрель 25, 2025

Язык: Английский

Процитировано

0

Development of hazelnut shell-derived biochar to support a bifunctional MoCo electrocatalyst for HER/OER in alkaline medium DOI Creative Commons

Jaime Ñanculeo,

Teresa Andreu,

Ignasi Sirés

и другие.

Biochar, Год журнала: 2025, Номер 7(1)

Опубликована: Май 12, 2025

Язык: Английский

Процитировано

0

Hydrogen and Oxygen Evolution on Flexible Catalysts Based on Nickel–Iron Coatings DOI Open Access

Dmytro Shyshkin,

Loreta Tamašauskaitė–Tamašiūnaitė,

Dijana Šimkūnaitė

и другие.

Catalysts, Год журнала: 2024, Номер 14(12), С. 843 - 843

Опубликована: Ноя. 22, 2024

The electrolysis of water is one low-cost green hydrogen production technologies. main challenge regarding this technology designing and developing high-activity catalysts. Herein, we present a strategy to fabricate flexible electrocatalysts based on nickel–iron (NiFe) alloy coatings. NiFe coatings were plated the copper-coated polyimide surface (Cu/PI) using straightforward electroless metal-plating method, with morpholine borane as reducing agent. It was found that Ni90Fe10, Ni80Fe20, Ni60Fe40, Ni30Fe70 deposited Cu/PI surface; then, concentration Fe2+ in plating solution 0.5, 1, 5, 10 mM, respectively. morphology, structure, composition NixFey/Cu/PI catalysts have been examined scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), diffraction (XRD), inductively coupled plasma–optical emission (ICP-OES), whereas their activity has investigated for evolution (HER) oxygen (OER) reactions 1 M KOH linear sweep voltammetry (LSVs). Ni80Fe20/Cu/PI catalyst exhibited lowest overpotential value −202.7 mV HER, obtaining current density mA cm−2 compared Ni90Fe10/Cu/PI (−211.9 mV), Ni60Fe40/Cu/PI (−276.3 Ni30Fe70/Cu/PI (−278.4 Ni (−303.4 mV). On other hand, OER (344.7 mV) observed catalyst, Ni35Fe65 (369.9 Ni80Fe20 (450.2 Ni90Fe10 (454.2 coatings, (532.1 developed exhibit cell potential 1.85 V at cm−2. obtained seem be suitable HER alkaline media.

Язык: Английский

Процитировано

0