Polymers for Advanced Technologies,
Год журнала:
2024,
Номер
35(11)
Опубликована: Окт. 30, 2024
ABSTRACT
As
a
widely
occurring
natural
product,
alkaloids
have
garnered
increasing
attention
in
drug
research
and
development.
The
efficient,
convenient,
environmentally
friendly
separation
detection
of
alkaloid
compounds
from
diverse
products
has
recent
research.
Molecular
imprinting
technology
(MIT)
is
recognized
as
an
effective
method
for
the
selective
extraction
complex
samples
due
to
its
capacity
specific
recognition.
To
date,
no
comprehensive
review
been
published
on
purification
using
MIT,
particularly
regarding
sustainability
aspects
this
technology.
In
paper,
we
general
preparation
methods
molecularly
imprinted
polymers
(MIPs)
alkaloids,
including
bulk
polymerization,
precipitation
magnetic
emulsion
polymerization.
Additionally,
summarize
various
applications
MIPs
such
different
forms
MIP‐based
solid
phase
(MISPE)
sensors
detection.
Finally,
address
some
unresolved
issues
anticipate
future
developments
field.
The Innovation Materials,
Год журнала:
2024,
Номер
unknown, С. 100090 - 100090
Опубликована: Янв. 1, 2024
<p>Anthropogenic
climate
and
environmental
changes
increasingly
threaten
the
sustainability
of
life
on
Earth,
hindering
sustainable
development
human
societies.
These
detrimental
ecological
are
driven
by
activities
that
have
elevated
atmospheric
levels
greenhouse
gases
toxic
substances,
increased
inorganic
organic
pollutants
in
water
bodies,
led
to
accumulation
solid
waste
soils.
Over
next
two
three
decades,
impacts
change,
pollution,
soil
contamination
expected
intensify,
posing
increasing
risks
health
global
stability.
Considering
these
trends,
it
is
essential
implement
robust
mitigation
adaptation
strategies.
This
paper
analyzes
pollution
problems
from
perspectives
atmospheric,
water,
contamination.
It
summarizes
current
research
heterogeneous
catalysis
for
treating
gaseous,
liquid,
phases,
with
an
emphasis
key
challenges
applying
catalytic
conversion
technologies
cost-effective
industrial
settings.
Finally,
strategies
mitigating
via
discussed
material
flow,
energy
data
flow.
aims
offer
scientific
insights
enhance
future
practice
remediation.</p>
Molecules,
Год журнала:
2025,
Номер
30(2), С. 364 - 364
Опубликована: Янв. 17, 2025
Emerging
contaminants
(ECs),
encompassing
pharmaceuticals,
personal
care
products,
pesticides,
and
industrial
chemicals,
represent
a
growing
threat
to
ecosystems
human
health
due
their
persistence,
bioaccumulation
potential,
often-unknown
toxicological
profiles.
Addressing
these
challenges
necessitates
advanced
analytical
tools
capable
of
detecting
quantifying
trace
levels
ECs
in
complex
environmental
matrices.
This
review
highlights
the
pivotal
role
mass
spectrometry
(MS)
monitoring
ECs,
emphasizing
its
high
sensitivity,
specificity,
versatility
across
various
techniques
such
as
Gas
Chromatography-Mass
Spectrometry
(GC-MS),
Liquid
(LC-MS),
High-Resolution
Mass
(HR-MS).
The
application
MS
has
facilitated
real-time
detection
volatile
organic
compounds,
comprehensive
non-targeted
screening
unknown
contaminants,
accurate
quantification
diverse
matrices
including
water,
soil,
air.
Despite
effectiveness,
matrix
interferences,
lack
standardized
methodologies,
limited
spectral
libraries
persist.
However,
recent
advancements,
hybrid
systems
integration
artificial
intelligence
(AI),
are
paving
way
for
more
efficient
predictive
modeling
contaminant
behavior.
Continued
innovation
technologies
collaborative
efforts
essential
overcome
existing
ensure
sustainable
solutions
mitigating
risks
associated
with
emerging
contaminants.
Foods,
Год журнала:
2024,
Номер
13(18), С. 2927 - 2927
Опубликована: Сен. 15, 2024
This
study
evaluated
acrylamide
(AA)
levels
and
various
quality
parameters
in
homemade
fried
potatoes
prepared
different
sizes
by
integrating
principles
from
the
Slow
Food
Movement
with
advanced
sensor
technology.
To
this
aim,
a
surface
plasmon
resonance
(SPR)
based
on
molecularly
imprinted
polymer
(MIP)
was
first
developed
for
determination
of
AA
at
low
levels,
samples
were
established.
First
all,
monolayer
formation
allyl
mercaptane
SPR
chip
carried
out
to
form
double
bonds
that
could
polymerize
surface.
AA-imprinted
surfaces
modified
via
UV
polymerization
using
ethylene
glycol
dimethacrylate
(EGDMA)
as
cross-linker,
N,N′-azobisisobutyronitrile
(AIBN)
an
initiator,
methacryloylamidoglutamicacid
(MAGA)
monomer.
The
nonimprinted
characterized
atomic
force
microscopy
(AFM)
Fourier
transform
infrared
(FTIR)
spectroscopy
methods.
indicated
linearity
range
1.0
×
10−9–5.0
10−8
M
detection
limit
(LOD)
3.0
10−10
potatoes,
demonstrated
high
selectivity
repeatability
terms
detection.
Additionally,
highest
level
observed
potato
sample
belonging
T1
group,
15.37
nM
(p
<
0.05),
strong
positive
correlation
found
between
sensory
parameters,
a*
value,
ΔE
browning
index
(BI)
0.05).
Heliyon,
Год журнала:
2024,
Номер
10(16), С. e36189 - e36189
Опубликована: Авг. 1, 2024
This
review
underscores
the
fundamentals
of
MIP-CMs
and
systematically
summarizes
their
synthetic
strategies
applications,
potential
developments.
are
widely
acclaimed
for
versatility,
finding
applications
in
separation,
filtration,
detection,
trace
analysis,
as
well
serving
scaffolds
a
range
analytical,
biomedical
industrial
contexts.
Also
characterized
by
extraordinary
selectivity,
remarkable
sensitivity,
outstanding
capability
to
bind
molecules,
those
membranes
also
cost-effective,
highly
stable,
configurable
terms
recognition
and,
therefore,
inalienable
various
application
fields.
Issues
relating
future
paper
discussed
last
section
with
focus
on
improvement
resource
practical
across
different
areas.
Hence,
this
can
be
seen
kind
cookbook
design
fabrication
an
intention
expand
scope
application.
Polymer-Plastics Technology and Materials,
Год журнала:
2025,
Номер
unknown, С. 1 - 29
Опубликована: Янв. 12, 2025
This
manuscript
presents
a
systematic
overview
of
molecularly
imprinted
polymer-derived
nanocomposites,
discussing
fundamentals,
design
categorization,
and
technological
worth,
according
to
the
reported
literature
so
far.
In
this
concern,
nanocomposites
polymers
have
been
synthesized
with
carbonaceous
nanoparticles
(graphene,
carbon
nanotube,
fullerene)
inorganic
(metal/metal
oxide,
metal
organic
frameworks).
Principal
synthesis
methods
applied
for
consequential
include
efficient
polymerization
tactics,
like
free
radical
(bulk/emulsion),
electropolymerization,
sol-gel,
precipitation,
imprinting
approaches
(surface
or
nanoimprinting).
Ensuing
macromolecular
assemblies
nanocomposite
hybrid
depicted
valuable
characteristics,
counting
low
price,
high
surface
area,
functionalities,
microstructural
variations,
structural
stability,
facile
synthesis,
desirable
porosity,
sensitivity
toward
other
molecules
depending
upon
their
precision
choice
processing
technique.
Subsequently,
worth
mentioning
combinations
nanocarbon/inorganic
showed
scientific
potential
water
remediation
(adsorbent
materials),
gas/electrochemical
sensors,
drug
delivery,
biosensing
fields.
Although
plenty
reports
revealed
design,
processing,
practical
aspects
polymers;
nonetheless,
we
note,
field
needs
much
future
attention
precise
designs,
perfect
polymer-nanoparticle
assemblies,
well-defined
techniques/parameters
commercial-scale
utilizations.
Nanomaterials,
Год журнала:
2025,
Номер
15(3), С. 243 - 243
Опубликована: Фев. 5, 2025
The
booming
expansion
of
nanotechnology
poses
the
problem
environmental
pollution
by
nanoparticles
(NPs).
available
methods
for
sensing
and
removing
NPs
from
environment
are
typically
lengthy
instrumentally
demanding.
recent
introduction
NP-imprinted
polymers
(NPIPs),
either
as
films
or
bulk
materials,
is
an
important
step
toward
simple
fast
removal
water
air.
Similarly
to
well-established
molecularly
imprinted
polymers,
in
NPIPs,
organic
inorganic
polymeric
material
first
obtained
with
embedded
NPs.
Then,
chemically
physically
removed
acting
a
template,
i.e.,
leaving
matrix
cavities
same
shape
dimensions.
After
examples
were
published
2014,
literature
has
so
far
reported
increasing
number
NPIPs
that
capable
reuptaking
(or,
more
rarely,
air),
remarkable
size
selectivity.
By
laying
NPIP
layer
on
reporter
(typically
electrode),
devices
On
other
hand,
can
reuptake
massive
amounts
have
been
used
quantitative
water.
This
review
begins
overview
hollow
capsules,
which
be
considered
ancestors
both
conception
preparative
methods.
reviewed.
Finally,
possible
evolutions
highlighted
perspective
stepping
their
real-life,
field
use.
Chemosensors,
Год журнала:
2024,
Номер
12(11), С. 232 - 232
Опубликована: Ноя. 7, 2024
The
need
for
rapid,
on-site
contaminant
detection
is
becoming
increasingly
vital
tackling
environmental
and
public
health
challenges.
This
study
introduces
an
efficient
method
detecting
sulfamethoxazole
(SMX),
a
widely
used
antibiotic
with
significant
implications.
A
cost-effective,
scalable
approach
was
developed
using
lab-on-paper
devices
integrated
molecularly
imprinted
polymers
(MIPs),
synthesized
through
in
situ
photopolymerization
process
that
completed
just
10
min.
Using
only
2
mL
of
MIP
solution
enabled
the
mass
production
100
disks.
Traditional
template
extraction,
which
often
takes
hours
or
days,
reduced
to
min
multichannel
micropipette
absorbent
fabric.
MIP-PAD
achieved
limit
(LOD)
0.8
µg/mL
quantification
(LOQ)
2.4
µg/mL,
measurements
obtained
smartphone-based
colorimetric
system.
It
exhibited
excellent
repeatability,
relative
standard
deviation
(RSD)
3.26%
across
seven
tests,
high
reusability
up
eight
cycles,
recovery
rates
real
samples
ranging
from
81.24%
99.09%.
provides
notable
improvements
sensitivity,
reproducibility,
sustainability
over
conventional
techniques.
user-friendly
platform
integrating
highly
practical
real-time
applications,
offering
broad
potential
monitoring,
food
safety,
healthcare.