Advanced Energy Materials,
Год журнала:
2022,
Номер
12(35)
Опубликована: Июль 27, 2022
Abstract
Graphite
has
paved
the
way
for
commercial
lithium‐ion
batteries
and
shows
great
potential
as
an
anode
high‐energy
potassium‐ion
(PIBs)
due
to
its
low‐potential
charge/discharge
plateau.
However,
restricted
diffusion
of
large
K
+
in
graphite
causes
difficulties
generating
stage‐one
graphite‐intercalation
compound
(GIC)
KC
8
at
high
rates
results
a
low
plateau
capacity
inferior
rate
performance.
It
is
discovered
that
formation
high‐stage
GICs
(prior
24
)
rate‐controlling
step
intercalation,
which
key
forming
.
Here,
carbon
material
containing
medium‐size
discrete
graphitic
crystallites
reported,
produced
by
heating
non‐graphitizable
above
2800
°C.
This
promotes
accelerated
especially
sufficient
reactive
sites,
leads
record‐high
293
mAh
g
−1
excellent
performance
with
180
500
mA
For
comparison,
respective
values
are
only
242
51
study
provides
new
insights
into
‐intercalation
chemistry
shall
promote
design
materials
high‐power
PIBs
even
other
energy
storage
systems.
Abstract
Developing
novel
techniques
to
convert
lignin
into
sustainable
chemicals
and
functional
materials
is
a
critical
route
toward
the
high-value
utilization
of
lignocellulosic
biomass.
Lignin-derived
carbon
hold
great
promise
for
applications
in
energy
chemical
engineering,
catalysis
environmental
remediation.
In
this
review,
state-of-art
sciences
technologies
controllable
synthesis
lignin-derived
are
summarized,
pore
structure
crystalline
morphology
controlling
methodologies
thoroughly
outlined
critically
discussed.
Green
engineering
with
cost-effectiveness
precise
carbonization
tuning
microstructure
future
research
trends
materials.
Future
directions
that
could
be
employed
advance
commercial
then
proposed.
Angewandte Chemie International Edition,
Год журнала:
2022,
Номер
61(10)
Опубликована: Янв. 15, 2022
Covalent
organic
frameworks
(COF)
possess
a
robust
and
porous
crystalline
structure,
making
them
an
appealing
candidate
for
energy
storage.
Herein,
we
report
exfoliated
polyimide
COF
composite
(P-COF@SWCNT)
prepared
by
in
situ
condensation
of
anhydride
amine
on
the
single-walled
carbon
nanotubes
as
advanced
anode
potassium-ion
batteries
(PIBs).
Numerous
active
sites
exposed
various
open
pathways
promote
highly
efficient
ion
diffusion
P-COF@SWCNT
while
preventing
irreversible
dissolution
electrolyte.
During
charging/discharging
process,
K+
is
engaged
carbonyls
imide
group
naphthalene
rings
through
enolization
π-K+
effect,
which
demonstrated
DFT
calculation
XPS,
ex-situ
FTIR,
Raman.
As
result,
enables
incredibly
high
reversible
specific
capacity
438
mA
h
g-1
at
0.05
A
extended
stability.
The
structural
advantage
more
insights
into
design
versatility
electrode.
Advanced Energy Materials,
Год журнала:
2021,
Номер
12(6)
Опубликована: Дек. 30, 2021
Abstract
In
recent
years,
research
into
the
synthesis
and
applications
of
0D
carbon
dots
(CDs)
has
blossomed
a
vibrant
exciting
new
field.
CDs
possess
diverse
fascinating
chemical,
structural,
optical
characteristics,
which
can
be
exploited
in
both
fundamental
applied
areas.
particular,
their
superior
electrochemical
activity
ease‐of‐modification
make
very
promising
electrode
materials
electrocatalysis
electrical
energy
storage.
This
review
seeks
to
provide
an
overview
latest
ground‐breaking
relating
utilization
processes
storage,
thus
providing
timely
snapshot
advancements
this
area.
To
begin,
advances
methods,
structural
modification/functionalization
strategies
are
explored,
with
view
toward
structure‐property
relationships.
Next,
performance
various
energy‐related
summarized,
including
H
2
evolution,
O
evolution/reduction,
CO
reduction,
batteries
supercapacitors.
Finally,
future
challenges
opportunities
for
CDs‐based
devices
surveyed.
Advanced Energy Materials,
Год журнала:
2021,
Номер
11(41)
Опубликована: Сен. 24, 2021
Abstract
Potassium
ion
battery
(PIB)
is
a
potential
candidate
for
future
large‐scale
energy
storage.
A
key
challenge
that
the
(de)potassiation
stability
of
graphitic
carbon
anodes
hampered
by
limited
(002)
interlayer
spacing.
Amorphous
with
hierarchical
structure
can
buffer
volume
change
during
repeated
and
enable
stable
cycling.
Herein,
direct
pyrolysis
approach
demonstrated
to
synthesize
highly
nitrogen‐doped
(26.7
at.%)
accordion‐like
anode
composed
thin
nanosheets
turbostratic
crystalline
structure.
The
endowed
self‐assembly
process
carbonization.
accordion
enables
high
reversible
capacity
346
mAh
g
−1
superior
cycling
stability.
This
work
constitutes
general
synthesis
methodology
be
used
prepare
advanced
PIBs.
ACS Nano,
Год журнала:
2022,
Номер
16(12), С. 21443 - 21451
Опубликована: Дек. 9, 2022
The
sulfur
doping
strategy
has
been
attracting
extensive
interest
in
potassium-ion
battery
carbon
anodes
for
the
dual
potential
of
improving
capacity
and
kinetics
anodes.
Understanding
potassium
storage
mechanism
is
crucial
to
guide
structural
design
optimization
high-performance
sulfur-doped
Herein,
presenting
a
laboratory-synthesized
hard
(SHC)
with
content
6.4
at.
%
as
an
example,
we
clarify
reveal
role
storage.
high
SHC
stems
from
selective
substitution
residual
trace
molecular
fragments
after
sulfurization.
As
result,
thanks
multifaceted
roles
doped
storage,
about
twice
much
capacity,
rate
capability,
cycling
stability
achieved
against
S-free
at
same
test
conditions.
Furthermore,
hybrid
capacitors
assembled
based
on
anode
demonstrate
energy/power
density
(139
Wh
kg-1/7.3
kW
kg-1),
along
extraordinary
stability.
ACS Nano,
Год журнала:
2022,
Номер
16(1), С. 1486 - 1501
Опубликована: Янв. 3, 2022
Metal
oxides
are
considered
as
prospective
dual-functional
anode
candidates
for
potassium
ion
batteries
(PIBs)
and
hybrid
capacitors
(PIHCs)
because
of
their
abundance
high
theoretic
gravimetric
capacity;
however,
due
to
the
inherent
insulating
property
wide
band
gaps
deficient
ion-transport
kinetics,
metal
oxide
anodes
exhibit
poor
K+
electrochemical
performance.
In
this
work,
we
report
crystal
facet
architecture
engineering
achieve
significantly
enhanced
storage
A
bismuth
antimonate
(BiSbO4)
nanonetwork
with
an
perpendicularly
crossed
single
nanorods
majorly
exposed
(001)
planes
synthesized
via
CTAB-mediated
growth.
is
found
be
preferential
surface
diffusion
path
superior
adsorption
transport,
in
addition,
interconnected
gives
rise
a
robust
matrix
enhance
electrical
conductivity
well
buffering
dramatic
volume
change
during
insertion/extraction
K+.
Thanks
synergistic
effect
structural
BiSbO4
electrodes,
stable
dual
conversion-alloying
mechanism
based
on
reversible
six-electron
transfer
per
formula
unit
ternary
realized,
proceeding
by
coexistence
peroxide
conversion
reactions
(KO2↔K2O)
BixSby
alloying
(BiSb
↔
KBiSb
K3BiSb).
As
result,
show
outstanding
terms
capacity,
cycling
life,
rate
capability.
Finally,
implementation
state-of-the-art
full
cell
configuration
both
PIBs
PIHCs
shows
satisfactory
performance
Ragone
plot
that
sheds
light
practical
applications
range
K+-based
energy
devices.
We
believe
study
will
propose
promising
avenue
design
advanced
hierarchical
nanostructures
or
binary
conversion-type
materials
PIBs,
PIHCs,
even
extensive
storage.
Nano-Micro Letters,
Год журнала:
2023,
Номер
15(1)
Опубликована: Янв. 27, 2023
Amorphous
carbons
are
promising
anodes
for
high-rate
potassium-ion
batteries.
Most
low-temperature
annealed
amorphous
display
unsatisfactory
capacities.
Heteroatom-induced
defect
engineering
of
could
enhance
their
reversible
Nevertheless,
most
lignocellulose
biomasses
lack
heteroatoms,
making
it
a
challenge
to
design
highly
heteroatom-doped
(>
10
at%).
Herein,
we
report
new
preparation
strategy
carbon
anodes.
Nitrogen/sulfur
co-doped
lignin-derived
porous
(NSLPC)
with
ultra-high
nitrogen
doping
levels
(21.6
at%
N
and
0.8
S)
from
renewable
lignin
biomacromolecule
precursors
were
prepared
through
supramolecule-mediated
pyrolysis
strategy.
This
supermolecule/lignin
composite
decomposes
forming
covalently
bonded
graphitic
carbon/amorphous
intermediate
product,
which
induces
the
formation
high
heteroatom
in
obtained
NSLPC.
unique
chemistry
NSLPC
enable
abundant
defective
active
sites
adsorption
K+
improved
kinetics.
The
anode
delivered
capacity
419
mAh
g‒1
superior
cycling
stability
(capacity
retention
96.6%
at
1
A
1000
cycles).
Potassium-ion
hybrid
capacitors
assembled
by
exhibited
excellent
(91%
2000
cycles)
energy
density
71
Wh
kg-1
power
92
W
kg-1.
Angewandte Chemie International Edition,
Год журнала:
2023,
Номер
62(17)
Опубликована: Март 1, 2023
Carbonaceous
materials
are
promising
anodes
for
practical
potassium-ion
batteries,
but
fail
to
meet
the
requirements
durability
and
high
capacities
at
low
potentials.
Herein,
we
constructed
a
durable
carbon
anode
high-energy-density
K-ion
full
cells
by
preferential
pyrolysis
strategy.
Utilizing
S
N
volatilization
from
π-π
stacked
supermolecule,
process
introduces
low-potential
active
sites
of
sp2
hybridized
vacancies,
endowing
"vacancy-adsorption/intercalation"
mechanism.
The
as-prepared
exhibits
capacity
384.2
mAh
g-1
(90
%
locates
below
1
V
vs.
K/K+
),
which
contributes
energy
density
163
Wh
kg-1
battery.
Moreover,
abundant
vacancies
alleviate
volume
variation,
boosting
cycling
stability
over
14
000
cycles
(8400
h).
Our
work
provides
new
synthesis
approach
with
densities.