RSC Advances,
Год журнала:
2025,
Номер
15(21), С. 16766 - 16791
Опубликована: Янв. 1, 2025
Perovskite
oxides
and
their
composites
enable
high
capacitance,
redox
activity,
cycling
stability,
making
them
ideal
for
advanced
supercapacitor
electrodes.
Advanced Materials,
Год журнала:
2024,
Номер
36(38)
Опубликована: Июль 25, 2024
Flexible
perovskite
solar
cells
(f-PSCs)
have
emerged
as
potential
candidates
for
specific
mechanical
applications
owing
to
their
high
foldability,
efficiency,
and
portability.
However,
the
power
conversion
efficiency
(PCE)
of
f-PSC
remains
limited
by
inferior
contact
between
flexible
buried
substrate.
Here,
an
asymmetric
π-extended
self-assembled
monolayer
(SAM)
(4-(9H-dibenzo[a,c]carbazol-9-yl)butyl)phosphonic
acid
(A-4PADCB)
is
reported
a
substrate
efficient
inverted
f-PSCs.
Employing
this
design
strategy,
A-4PADCB
exhibits
significant
orientation
angle
away
from
surface
normal,
homogenizing
distribution
potentials.
This
enhancement
improves
SAM/perovskite
interface
quality,
controlling
growth
favorable
films
with
low
defect
density
slight
tensile
stress.
Integration
into
small-area
f-PSCs
large-area
modules
aperture
area
20.84
cm
Advanced Functional Materials,
Год журнала:
2024,
Номер
34(33)
Опубликована: Апрель 30, 2024
Abstract
Mixed‐halide
perovskites
are
emerging
as
excellent
photovoltaic
candidates
because
of
their
tunable
bandgaps
for
semitransparent
and
tandem
perovskite
solar
cells.
However,
the
notorious
film
quality
originated
from
rapidly
downward
crystallization
process
susceptibly
propagates
enormous
detrimental
defects,
which
deteriorate
performance
accelerate
halide
segregation.
To
address
this
issue,
herein,
a
multilayer
alkalis‐intercalated‐vermiculite
is
employed
pre‐buried
interface
modifier
to
regulate
lattice
property.
The
matchable
structure
between
vermiculite
by
forming
Pb─O
bond
not
only
releases
interfacial
strain
during
growth
but
also
embedded
alkalis
ions
can
gradually
diffuse
into
form
favorable
vertical
gradient
owing
weak
interlamellar
van
der
Waals
interaction,
playing
bis‐roles
atomical
lubricant
ion‐reservoir
eliminate
defects.
As
result,
stability
significantly
improved
with
suppressed
phase
segregation
mixed‐halide
perovskites,
accompanying
champion
efficiency
11.42%
carbon‐based
CsPbIBr
2
device,
15.25%
CsPbI
Br
device
23.17%
p‐i‐n
inverted
(Cs
0.05
MA
FA
0.9
)Pb(I
0.93
0.07
)
3
cell.
This
work
provides
new
strategy
on
buried
engineering
making
high‐efficiency
stable
platforms.
Abstract
Over
the
past
10
years,
perovskite
solar
cell
(PSC)
device
technologies
have
advanced
remarkably
and
exhibited
a
notable
increase
in
efficiency.
Additionally,
significant
innovation
approaches
improved
stability
related
to
heat,
light,
moisture
of
PSC
devices.
Despite
these
developments
PSCs,
instability
PSCs
is
pressing
problem
an
urgent
matter
overcome
for
practical
application.
Recently,
polymers
been
suggested
suggestion
has
presented
solve
issues
photovoltaic
parameters
Here,
first,
fundamental
chemical
bond
types
self‐healing
are
presented.
Then,
comprehensive
presentation
ability
rigid
flexible
enhance
various
physical,
mechanical,
optoelectronic
properties
Furthermore,
valuable
insights
innovative
solutions
perovskite‐based
optoelectronics
with
provided,
offering
guidance
future
applications.
image
Nano-Micro Letters,
Год журнала:
2024,
Номер
17(1)
Опубликована: Сен. 30, 2024
Abstract
The
rapid
advancement
of
nanotechnology
has
sparked
much
interest
in
applying
nanoscale
perovskite
materials
for
photodetection
applications.
These
are
promising
candidates
next-generation
photodetectors
(PDs)
due
to
their
unique
optoelectronic
properties
and
flexible
synthesis
routes.
This
review
explores
the
approaches
used
development
use
devices
made
different
architectures,
including
quantum
dots,
nanosheets,
nanorods,
nanowires,
nanocrystals.
Through
a
thorough
analysis
recent
literature,
also
addresses
common
issues
like
mechanisms
underlying
degradation
PDs
offers
perspectives
on
potential
solutions
improve
stability
scalability
that
impede
widespread
implementation.
In
addition,
it
highlights
encompasses
detection
light
fields
dimensions
other
than
intensity
suggests
avenues
future
research
overcome
these
obstacles
fully
realize
state-of-the-art
systems.
provides
comprehensive
overview
guides
efforts
towards
improved
performance
wider
applicability,
making
valuable
resource
researchers.
Physica Scripta,
Год журнала:
2024,
Номер
99(9), С. 095994 - 095994
Опубликована: Авг. 6, 2024
Abstract
This
study
presents
a
detailed
investigation
into
optimizing
the
novel
perovskite
Mg
3
AsBr
through
uniaxial
stress
for
enhanced
performance
in
solar
and
optoelectronic
applications.
Using
Density
Functional
Theory
(DFT),
we
examined
its
structural,
electronic,
optical
properties
under
from
0.5
to
5.0
GPa.
Key
findings
include
tuning
of
material’s
bandgap
1.485
eV
(without
stress)
an
optimized
range
closer
1.13581
GPa,
demonstrating
potential
improved
cell
efficiency.
Our
reveal
nuanced
response
absorption
coefficients
at
critical
energies
2.92
4.0
eV,
where
descending
trend
with
increasing
pressure
was
observed,
indicating
plateau
1.5
GPa
anomalous
increase
2.5
behavior
underscores
significance
between
tailoring
responses
essential
enhancing
efficiency
ultraviolet
visible
light
(300–800
nm).
Notably,
dielectric
constant
increased
gradually
stress,
peaking
6.003
slightly
diminishing
suggesting
polarization
intrinsic
electric
fields
mechanical
stress.
research
highlights
engineering
materials
renewable
energy
applications,
offering
pathway
high-efficiency,
low-cost
cells.
Abstract
Light-emitting
diodes
(LEDs)
are
an
indispensable
part
of
our
daily
life.
After
being
studied
for
a
few
decades,
this
field
still
has
some
room
improvement.
In
regard,
perovskite
materials
may
take
the
leading
role.
recent
years,
LEDs
have
become
most
explored
topic,
owing
to
their
various
applications
in
photodetectors,
solar
cells,
lasers,
and
so
on.
Noticeably,
they
exhibit
significant
characteristics
developing
LEDs.
The
luminous
efficiency
can
be
significantly
enhanced
by
combination
poor
illumination
LED
with
low-dimensional
perovskite.
2014,
first
perovskite-based
was
illuminated
at
temperature.
Furthermore,
two-dimensional
(2D)
perovskites
enriched
because
optical
electronic
properties
comparatively
high
stability
ambient
conditions.
Recent
relevant
advancements
using
including
zero-dimensional
three-dimensional
is
reported.
major
focus
article
based
on
2D
heterostructures
(i.e.,
transition
metal
dichalcogenides,
graphene,
hexagonal
boron
nitride).
comparison
perovskites,
more
potential
application
State-of-the-art
LEDs,
current
challenges,
prospects
also
discussed.
Graphical