Halogen‐Bonded Hole‐Transport Material Enhances Open‐Circuit Voltage of Inverted Perovskite Solar Cells DOI Creative Commons
Zhaoyang Chen, Jiakang Zhang, Zilong Chen

и другие.

Advanced Science, Год журнала: 2024, Номер unknown

Опубликована: Окт. 22, 2024

Abstract Interfacial properties of a hole‐transport material (HTM) and perovskite layer are high importance, which can influence the interfacial charge transfer dynamics as well growth bulk crystals particularly in inverted structure. The halogen bonding (XB) has been recognized powerful functional group to be integrated with new small molecule HTMs. Herein, carbazole‐based halo (iodine)‐functional HTM (O1), is synthesized for first time, demonstrating hole mobility suitable energy levels that align those perovskites. strong interaction between O1 perovskite, i.e., I···I − , induces formation an ordered interlayer, verified by both theoretical experimental studies. Compared reference (O2) without any halo‐function, XB‐induced interlayer effectively enhances extraction efficiency, while significantly hindering non‐radiative recombination reducing surface traps upon passivation effect. This reflected big increase open‐circuit voltage up 114 mV fabrication devices highest power conversion efficiency 22.34%. Moreover, XB‐driven at interface mainly responsible extended lifespan under operational conditions.

Язык: Английский

Multi-color long persistent luminescence in metal-organic frameworks regulated by dual channels of distorted second building units and organic ligand and applied in printing, message encryption and writing DOI
Zheng Wang, Junjie Pan,

Xin‐Qi Chen

и другие.

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 161076 - 161076

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

1

Bifunctional π conjugated g-C3N4 for enhancing the efficiency and stability of carbon-based perovskite solar cells DOI
Zhenxing Chen, Lifeng Gui, Hao Wang

и другие.

Separation and Purification Technology, Год журнала: 2025, Номер 362, С. 131797 - 131797

Опубликована: Янв. 31, 2025

Язык: Английский

Процитировано

0

Decoding recombination dynamics in perovskite solar cells: an in-depth critical review DOI
Ramkrishna Das Adhikari, Mayur Jagdishbhai Patel, Himangshu Baishya

и другие.

Chemical Society Reviews, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

This review systematically analyses the recombination pathways in PSCs, unveils cutting-edge suppression strategies, and underscores potential of ML optimizing device performance expediting commercial integration.

Язык: Английский

Процитировано

0

Rational Design of 1,3,6-Trisubstituted Azulene Based Hole Transport Materials for Efficient and Stable Planar Perovskite Solar Cells DOI
Zhangyan Wang, Yuanqing Sun, Xinyue Liu

и другие.

Dyes and Pigments, Год журнала: 2025, Номер unknown, С. 112856 - 112856

Опубликована: Апрель 1, 2025

Язык: Английский

Процитировано

0

Surface Engineering in Perovskite Solar Cells: Recent Advances in Surface Passivation Group-Containing Hole Transport Layers DOI
Zheng Wang, Liang Gu,

Muhua Zou

и другие.

Langmuir, Год журнала: 2025, Номер unknown

Опубликована: Май 29, 2025

Perovskite solar cells (PSCs) are at the forefront of photovoltaic technology, offering exceptional power conversion efficiencies (PCEs) and promise low-cost, scalable production. Rapid progress in PSCs has largely been fueled by innovations device architecture component optimization. Among these, interface between hole transport layer (HTL) perovskite is crucial, as it not only facilitates efficient extraction but also protects from environmental degradation. This review highlights recent advancements engineering this critical interface, focusing on improvements surface morphology, adhesion, energy level alignment, defect passivation. Special attention given to roles amide, carboxylic acid, phosphonic halogenide groups enhancing HTL properties interface. By synthesizing latest research experimental insights, provides a comprehensive overview passivation's contributions high-performance PSCs. It discusses future directions challenges optimizing key further advancing promising technology.

Язык: Английский

Процитировано

0

Halogen‐Bonded Hole‐Transport Material Enhances Open‐Circuit Voltage of Inverted Perovskite Solar Cells DOI Creative Commons
Zhaoyang Chen, Jiakang Zhang, Zilong Chen

и другие.

Advanced Science, Год журнала: 2024, Номер unknown

Опубликована: Окт. 22, 2024

Abstract Interfacial properties of a hole‐transport material (HTM) and perovskite layer are high importance, which can influence the interfacial charge transfer dynamics as well growth bulk crystals particularly in inverted structure. The halogen bonding (XB) has been recognized powerful functional group to be integrated with new small molecule HTMs. Herein, carbazole‐based halo (iodine)‐functional HTM (O1), is synthesized for first time, demonstrating hole mobility suitable energy levels that align those perovskites. strong interaction between O1 perovskite, i.e., I···I − , induces formation an ordered interlayer, verified by both theoretical experimental studies. Compared reference (O2) without any halo‐function, XB‐induced interlayer effectively enhances extraction efficiency, while significantly hindering non‐radiative recombination reducing surface traps upon passivation effect. This reflected big increase open‐circuit voltage up 114 mV fabrication devices highest power conversion efficiency 22.34%. Moreover, XB‐driven at interface mainly responsible extended lifespan under operational conditions.

Язык: Английский

Процитировано

1