Crystal orientation control in angstrom-scale channel membranes for significantly enhanced blue energy harvesting

Chemical Engineering Journal, Год журнала: 2024, Номер unknown, С. 155934 - 155934

Опубликована: Сен. 1, 2024

Язык: Английский

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Cellulose Nanocrystal Composite Membrane Enhanced with In Situ Grown Metal–Organic Frameworks for Osmotic Energy Conversion

Small, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 22, 2024

Access to clean and renewable energy, osmotic energy from salinity gradient difference, for example, is central the sustainability of human civilization. Despite numerous examples nanofluidic membranes conversion, one produced abundant biomass resources remains largely unexplored. In this work, cotton-derived cellulose nanocrystals (CNCs) are employed fabricate a membrane by self-assembly with polyvinyl alcohol (PVA) subsequent in situ growth metal-organic framework (MOF), UiO-66-(COOH)

Язык: Английский

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Turing-type nanochannel membranes with extrinsic ion transport pathways for high-efficiency osmotic energy harvesting

Nature Communications, Год журнала: 2024, Номер 15(1)

Опубликована: Ноя. 26, 2024

Two-dimensional (2D) nanofluidic channels with confined transport pathways and abundant surface functional groups have been extensively investigated to achieve osmotic energy harvesting. However, solely relying on intrinsic interlayer results in insufficient permeability, thereby limiting the output power densities, which poses a significant challenge widespread application of these materials. Herein, we present nanoconfined sacrificial template (NST) strategy create crafted channel structure, termed as Turing-type nanochannels, within membrane. Extrinsic interlaced are formed between lamellae using copper hydroxide nanowires templates. These nanochannels significantly increase areas, resulting 23% enhancement ionic current while maintaining cation selectivity 0.91. The density nanochannel membrane increases from 3.9 5.9 W m−2 remains stable for at least 120 hours. This exhibits enhanced applicability real saltwater environments across China, achieving densities 7.7 natural seawater 9.8 salt-lake brine. work demonstrates promising potential Turing-channel design conversion field. High permselectivity nanofluidics conversion. Here, authors construct two dimensional provide extrinsic improve both ion flux, efficient

Язык: Английский

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Nanofluidic osmotic energy devices based on metal–organic frameworks

Materials Science and Engineering B, Год журнала: 2024, Номер 313, С. 117931 - 117931

Опубликована: Дек. 21, 2024

Язык: Английский

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