Journal of Forestry Research,
Год журнала:
2025,
Номер
36(1)
Опубликована: Фев. 1, 2025
Abstract
To
better
understand
the
effects
of
ground-level
ozone
(O
3
)
on
nutrients
and
stoichiometry
in
different
plant
organs,
urban
tree
species
Celtis
sinensis
,
Cyclocarya
paliurus
Quercus
acutissima
nuttallii
were
subjected
to
a
constant
exposure
charcoal-filtered
air
(CF),
nonfiltered
(NF),
or
NF
+
40,
60,
80
nmol
O
mol
–1
(NF40,
NF60,
NF80)
starting
early
summer
growing
season.
At
end
summer,
net
CO
2
assimilation
rate
(
A
),
stomatal
conductance
g
s
leaf
mass
per
area
(LMA),
and/or
greenness
(SPAD)
either
not
significantly
affected
by
elevated
even
higher
some
cases
during
compared
with
CF
controls.
LMA
was
lower
autumn
only
after
highest
exposures.
Compared
NF,
NF40
caused
large
increase
across
late
more
K
Mn
stems.
season,
nutrient
status
stoichiometric
ratios
organs
variously
altered
under
stress;
many
changes
often
species-specific.
Across
treatments,
primarily
associated
C
Mg
levels
leaves
Ca
enriched
K,
P,
Fe,
stems,
relative
NF60
enhanced
NF40.
Moreover,
resulted
Ca/Mg
ratio
Q.
only,
other
regimes.
Interestingly,
species,
stress
led
modifications
(stems
branches
vs
leaves).
Thus,
ambient
exposures
can
alter
dynamics
distribution
disrupt
species-specific
manner.
Changes
reflect
an
important
defense
mechanism
plants
pollution
adds
risk
ecological
stoichiometries
areas.
Atmospheric chemistry and physics,
Год журнала:
2024,
Номер
24(2), С. 1559 - 1570
Опубликована: Фев. 1, 2024
Abstract.
Ozone
(O3)
pollution
research
and
management
in
China
have
mainly
focused
on
anthropogenic
emissions,
while
the
importance
of
natural
processes
is
often
overlooked.
With
increasing
frequency
extreme
weather
events,
role
exacerbating
O3
gaining
attention.
In
September
2022,
Pearl
River
Delta
(PRD)
southern
experienced
an
extended
period
(25
d)
regional
exceedances
high
temperatures
(second
highest
over
last
2
decades)
due
to
conditions
influenced
by
subtropical
typhoon
peripheries.
Employing
integrated
approach
involving
field
measurements,
machine
learning
numerical
model
simulations,
we
investigated
impact
weather-induced
considering
meteorological
factors,
chemistry
pathways
atmospheric
transport.
The
hot
intensified
emission
biogenic
volatile
organic
compounds
(BVOCs)
∼10
%.
Isoprene
formaldehyde
accounted
for
47
%
situ
production,
underscoring
predominant
BVOC
emissions
processes.
chemical
pathway
isoprene
contributing
formation
was
further
explored,
with
production
more
attributable
degradation
early
generation
oxidation
products
(contributed
64.5
%)
than
direct
itself
35.5
%).
Besides,
it
found
that
significantly
promoted
photochemical
reactions,
factors
additional
10.8
ppb
levels
compared
normal
conditions.
Temperature
identified
as
dominant
factor.
Furthermore,
nearing
landfall
enhanced
cross-regional
transport
from
northern
through
stratosphere–troposphere
exchange
(STE).
CAM-Chem
simulations
revealed
STE-induced
PRD
surface
could
reach
a
maximum
∼8
ppb,
highlighting
non-negligible
STE.
This
study
highlights
exacerbated
events
provides
valuable
insights
into
control
under
global
warming.
Nature Communications,
Год журнала:
2024,
Номер
15(1)
Опубликована: Ноя. 26, 2024
Tropospheric
ozone
formation
depends
on
the
emissions
of
volatile
organic
compounds
(VOC)
and
nitrogen
oxides
(NOx).
In
megacities,
abundant
VOC
NOx
sources
cause
relentlessly
high
episodes,
affecting
a
large
share
global
population.
This
study
uses
data
from
Ozone
Monitoring
Instrument
for
formaldehyde
(HCHO)
dioxide
(NO2)
as
proxy
emissions,
respectively,
with
their
ratio
serving
an
indicator
sensitivity.
Ground-level
(O3)
reanalysis
Copernicus
Atmosphere
is
used
to
assess
O3
trends.
We
evaluate
changes
2005
2019
relationship
warming
environment
in
41
megacities
worldwide,
applying
seasonal
Mann-Kendall,
trend
decomposition
methods,
Pearson
correlation
analysis.
reveal
significant
increases
HCHO
(0.1
0.31
×
1015
mol
cm−2
year−1)
regionally
varying
NO2
(−0.22
0.07
year−1).
trends
range
−0.31
0.70
ppb
year−1,
highlighting
relevance
precursor
abundance
levels.
The
strong
between
increasing
temperature
suggests
that
will
continue
rise
climate
change
persists.
Satellite
observations
dioxide,
key
species
contributing
formation,
rising
temperatures
are
driving
increased
levels
globally
urban
remote
environments
Environmental Science & Technology,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 20, 2025
The
satellite-based
tropospheric
column
ratio
of
HCHO
to
NO2
(FNR)
is
widely
used
diagnose
ozone
formation
sensitivity;
however,
its
representation
surface
conditions
remains
controversial.
In
this
study,
an
approach
construct
the
3D
spatial
distribution
FNR
in
lower
troposphere
was
proposed.
Based
on
satellite
and
multiaxes-differential
Optical
Absorption
Spectroscopy
(MAX-DOAS)
data,
horizontal
vertical
distributions
have
been
respectively
obtained.
To
further
enhance
generalizability
approach,
we
also
reproduced
profiles
using
a
machine
learning
model
(Bagged
trees)
feature
variables.
Here,
three-dimensional
during
summer
2019
as
example,
fourth-order
polynomial
relationship
found
between
reconstruction
factors
(fcol_i)
altitudes,
demonstrating
correlation
coefficient
0.98.
Utilizing
established
relationship,
significant
difference
reconstructed
FNR,
with
former
decreasing
by
56.9%.
Moreover,
for
summers
from
2018
2022
revealed
trend
over
five
years
Shanghai
control
regimes
gradually
shifting
toward
transition
NOx-limited
regimes.
Through
newly
not
only
can
accuracy
identifying
sensitivity
be
enhanced
spaced
observation,
but
it
helps
gaining
comprehensive
understanding
photochemical
mechanisms
direction.
Atmospheric chemistry and physics,
Год журнала:
2024,
Номер
24(14), С. 8225 - 8242
Опубликована: Июль 22, 2024
Abstract.
In
this
study,
trends
of
21st-century
ground-level
ozone
and
precursors
were
examined
across
South
America,
a
less-studied
region
where
trend
estimates
have
rarely
been
comprehensively
addressed.
Therefore,
we
provided
an
updated
regional
analysis
based
on
validated
surface
observations.
We
tested
the
hypothesis
that
recent
increasing
trends,
mostly
in
urban
environments,
resulted
from
intense
wildfires
driven
by
extreme
meteorological
events
impacting
cities
preexisting
volatile
organic
compound
(VOC)-limited
regimes
dominate.
applied
quantile
regression
method
monthly
anomalies
to
estimate
quantify
their
uncertainties
detect
change
points.
Additionally,
maximum
daily
8
h
average
(MDA8)
peak-season
metrics
used
assess
short-
long-term
exposure
levels,
respectively,
for
present
day
(2017–2021).
Our
results
showed
lower
levels
tropical
(Bogotá
Quito),
varying
between
39
43
nmol
mol−1
short-term
26
27
exposure.
contrast,
mixing
ratios
higher
extratropical
(Santiago
São
Paulo),
with
level
61
40
41
mol−1.
Santiago
(since
2017)
Paulo
2008)
exhibited
positive
0.6
0.3
yr−1,
very
high
certainty.
attributed
these
upward
or
no
evidence
variation,
such
as
Bogotá
Quito,
well-established
VOC-limited
regime.
However,
greater
increase
percentile
(≥
90th)
heat
waves
and,
case
southwestern
associated
events.