Hollow
energetic
microspheres
have
attracted
great
attention
in
the
field
of
materials
due
to
their
wide
application
potential.
However,
scalable,
simple,
and
low-cost
production
methods
not
been
achieved
yet.
In
this
study,
using
nitrocellulose
(NC)
as
a
binder,
hollow
porous
CL-20
were
prepared
by
assist
microjet
droplet
technology.
The
effects
solution
concentration,
receiving
liquid
temperature,
solvent
type
on
morphology,
particle
size,
shell
thickness,
pore
size
systematically
investigated.
Furthermore,
influences
thickness
dispersibility,
crystal
structure,
thermal
decomposition,
mechanical
sensitivity,
combustion
behavior
further
studied.
results
showed
that
precise
control
over
could
be
adjusting
experimental
parameters.
Compared
raw
CL-20,
exhibited
excellent
dispersibility
improved
safety
performance.
Ignition
experiments
demonstrated
structures
significantly
enhanced
flame
energy
release
efficiency.
This
preparation
method
is
simple
efficient,
providing
new
approach
for
fabrication
multi-structured
microspheres.
Defence Technology,
Год журнала:
2024,
Номер
unknown
Опубликована: Июнь 1, 2024
Energetic
materials,
characterized
by
their
capacity
to
store
and
release
substantial
energy,
hold
pivotal
significance
in
some
fields,
particularly
defense
applications.
Microfluidics,
with
its
ability
manipulate
fluids
facilitate
droplet
formation
at
the
microscale,
enables
precise
control
of
chemical
reactions.
Recent
scholarly
endeavors
have
increasingly
harnessed
microfluidic
reactors
realm
energetic
yielding
morphologically
controllable
particles
enhanced
uniformity
explosive
efficacy.
However,
crucial
insights
into
microfluidic-based
methodologies
are
dispersed
across
various
publications,
necessitating
a
systematic
compilation.
Accordingly,
this
review
addresses
gap
concentrating
on
synthesis
materials
through
microfluidics.
Specifically,
methods
based
micro-mixing
droplets
previous
papers
summarized
strategies
critical
parameters
within
reactions
discussed
detail.
Then,
comparison
terms
advantages
disadvantages
is
attempted.
As
demonstrated
last
section
regarding
perspectives,
challenges
such
as
clogging,
dead
zones,
suboptimal
production
yields
non-ignoble
promising
fields
they
might
be
addressed
integrating
sound,
optics,
or
electrical
energy
meet
heightened
requirements.
This
comprehensive
overview
aims
consolidate
analyze
diverse
array
approaches
material
synthesis,
offering
valuable
for
future
research
directions.
Energetic Materials Frontiers,
Год журнала:
2024,
Номер
unknown
Опубликована: Июнь 1, 2024
Recent
years
have
witnessed
significant
advancements
in
methodologies
and
techniques
for
the
synthesis
of
energetic
materials,
which
are
expected
to
shape
future
manufacturing
applications.
Techniques
including
continuous
flow
chemistry,
electrochemical
synthesis,
microwave-assisted
biosynthesis
been
extensively
employed
pharmaceutical
fine
chemical
industries
and,
gratifyingly,
found
broader
This
review
comprehensively
introduces
recent
utilization
these
emerging
techniques,
aiming
provide
a
catalyst
development
novel
green
methods
synthesizing
materials.
Molecules,
Год журнала:
2025,
Номер
30(5), С. 1176 - 1176
Опубликована: Март 6, 2025
As
a
typical
high-energy-density
material,
the
sensitivity
of
CL-20
severely
limits
its
application
in
explosives
and
propellants.
Adjusting
structure
at
microscopic
level
can
effectively
solve
such
problems.
In
this
study,
microfluidic
recrystallization
technique
was
used
to
prepare
ε-CL-20
with
three
different
particle
sizes,
narrow
size
distributions
(D50
=
2.77
μm,
17.22
μm
50.35
μm).
The
prepared
samples
had
fewer
surface
defects
compared
raw
material.
decreased,
density
increased
impact
significantly
reduced.
activation
energy
using
technology
increases
size.
Laser
ignition
experiments
revealed
that
smaller
particles
highest
release
efficiency,
while
larger
exhibited
higher
more
stable
release.
combustion
performance
safety
be
improved
by
improving
crystal
distribution
morphology.
Controllable
preparation
multiple
sizes
achieved
technology,
which
provides
reference
for
other
energetic
materials.
Energetic Materials Frontiers,
Год журнала:
2024,
Номер
5(2), С. 147 - 157
Опубликована: Май 30, 2024
To
meet
the
requirements
of
explosives
in
military
and
civilian
fields,
researchers
are
committed
to
improving
comprehensive
performance
explosives.
The
explosive
crystals
can
be
significantly
improved
by
regulating
structure
morphology
single-compound
as
well
compounding
crystals.
According
related
research
on
at
home
abroad
from
2022
now,
development
crystal
composites
explosives'
morphology,
particle
size,
form
regulation
study
were
reviewed.
encompass
both
complex
consisting
a
two
separate
types
Simultaneously,
main
problems
encountered
also
analyzed,
such
deficiency
systematic
broadly
applicable
methods
theories.
Finally,
future
direction
was
envisioned,
with
aim
providing
guidance
for
production,
handling,
application
Langmuir,
Год журнала:
2024,
Номер
40(26), С. 13676 - 13687
Опубликована: Июнь 24, 2024
Taking
μ-HMX
particles
as
the
main
research
subject,
a
set
of
microdroplet
sphericalization
coating
technology
platforms
was
designed
and
constructed
to
realize
preparation
composite
microspheres
by
μ-HMX.
The
suspension
stability
mechanism
droplet
formation
were
investigated,
application
effect
nanocarbon
materials
also
analyzed.
results
showed
that
prepared
sample
all
better
spherical
morphology,
well
good
dispersibility;
samples
with
micron-sized
for
had
lower
thermal
decomposition
temperature,
higher
energy
release
efficiency,
mechanical
sensibility,
combustion
performance;
incorporation
CNFs
changed
mode
system,
which
resulted
in
microsphere
system
having
safety
performance.
feasibility
uniform
spheronization
when
dispersed
phase
is
low-concentration
particle
encapsulation
process
verified.
