Driving Polymer Brushes from Synthesis to Functioning

Angewandte Chemie International Edition, Год журнала: 2023, Номер 62(27)

Опубликована: Март 23, 2023

The great success of controlled radical polymerizations has encouraged researchers to develop more facile and robust approaches for surface-initiated (SIPs) fabricate polymer brushes, even non-experts. In recent years, external-stimuli-mediated polymerization methods have come the fore as SIPs because their less rigorous synthetic procedures high controllability, which expand opportunities synthesizing macromolecules with desired chemical compositions structures, well tailor-made polymers bioconjugates that show broad applicability physiological compatibility. This review discusses latest developments in methods, particular, external-stimuli mediated atom transfer (ATRP), photo-induced polymerizations, reversible addition-fragmentation chain (RAFT) polymerization, other combination application surface grafting. implementation these is interest due unique possibilities temporally control a process, fast straightforward environmentally benign features, lead established emerging applications biolubrication, antifouling, biosensing.

Язык: Английский

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Hydrophobic silicone modified membranes for efficient oil/water separation: Synthesis, fabrication and application

Separation and Purification Technology, Год журнала: 2024, Номер 353, С. 128485 - 128485

Опубликована: Июнь 19, 2024

Язык: Английский

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Synthesis, Stability, and Tribological Performance of TiO2 Nanomaterials for Advanced Applications

Lubricants, Год журнала: 2025, Номер 13(2), С. 56 - 56

Опубликована: Янв. 29, 2025

The enhancement of tribological properties represents a pivotal strategy for achieving energy efficiency and environmental protection. Titanium dioxide (TiO2) nanomaterials have been garnering significant attention due to their exemplary the abundance titanium reserves. present review is concerned with study TiO2 in lubricants. various synthesis methods are presented. dispersion stability these lubricating oils discussed depth, as well strategies improve stability, such enhancing compatibility base oils, reducing dynamic light scattering (DLS) particle size, modulating zeta potential, optimizing drying step. Aggregation instability remain key challenges nanomaterials, especially bare nanoparticles (NPs). In contrast, situ surface-modified NPs show improved performance, offering promise further research. performance lubricants has demonstrated be enhanced by observed attributed synergistic effect multiple mechanisms, including rolling, patching, polishing, formation protective film. Furthermore, future research suggestions proposed provide reference design high-performance nano-lubricants promote wide application.

Язык: Английский

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Temperature-Responsive Polymer Brush Coatings for Advanced Biomedical Applications

Polymers, Год журнала: 2022, Номер 14(19), С. 4245 - 4245

Опубликована: Окт. 10, 2022

Modern biomedical technologies predict the application of materials and devices that not only can comply effectively with specific requirements, but also enable remote control their functions. One most prospective for these advanced applications are based on temperature-responsive polymer brush coatings (TRPBCs). In this review, methods fabrication characterization TRPBCs summarized, possibilities application, as well advantages disadvantages TRPBCs, presented in detail. Special attention is paid to mechanisms thermo-responsibility TRPBCs. Applications temperature-switchable bacteria killing, temperature-controlled protein adsorption, cell culture, adhesion/detachment cells tissues considered. The criteria required desired discussed.

Язык: Английский

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Polymer Brushes and Surface Nanostructures: Molecular Design, Precise Synthesis, and Self-Assembly

Langmuir, Год журнала: 2024, Номер 40(5), С. 2439 - 2464

Опубликована: Янв. 27, 2024

For over two decades, polymer brushes have found wide applications in industry and scientific research. Now, brush research has been a significant focus the community of science. In this review paper, we give an introduction to synthesis, self-assembly, one-dimensional (1D) on backbones, two-dimensional (2D) flat surfaces, three-dimensional (3D) spherical particles. Examples synthesis different substrates are provided. Studies formation surface nanostructures solid surfaces also reviewed article. Multicomponent able self-assemble into micelles (s-micelles). If s-micelles linked through cleavable linkages, can be cleaved from substrates, hierarchical structures. The by coassembly "free" chains (coassembly approach) or polymerization-induced self-assembly approach, is discussed. colloid biomedical science summarized. Finally, perspectives development offered

Язык: Английский

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Surface functionalization of polyurethanes: A critical review

Advances in Colloid and Interface Science, Год журнала: 2024, Номер 325, С. 103100 - 103100

Опубликована: Фев. 4, 2024

Язык: Английский

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Polymer brushes by SI-PET-RAFT: Synthesis and applications

Polymer, Год журнала: 2025, Номер unknown, С. 128155 - 128155

Опубликована: Фев. 1, 2025

Язык: Английский

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Strategies to improve the mass transfer in the CO2 capture process using immobilized carbonic anhydrase

Journal of Environmental Management, Год журнала: 2023, Номер 332, С. 117370 - 117370

Опубликована: Янв. 28, 2023

Язык: Английский

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Driving Polymer Brushes from Synthesis to Functioning

Angewandte Chemie, Год журнала: 2023, Номер 135(27)

Опубликована: Март 23, 2023

Abstract The great success of controlled radical polymerizations has encouraged researchers to develop more facile and robust approaches for surface‐initiated (SIPs) fabricate polymer brushes, even non‐experts. In recent years, external‐stimuli‐mediated polymerization methods have come the fore as SIPs because their less rigorous synthetic procedures high controllability, which expand opportunities synthesizing macromolecules with desired chemical compositions structures, well tailor‐made polymers bioconjugates that show broad applicability physiological compatibility. This review discusses latest developments in methods, particular, external‐stimuli mediated atom transfer (ATRP), photo‐induced polymerizations, reversible addition‐fragmentation chain (RAFT) polymerization, other combination application surface grafting. implementation these is interest due unique possibilities temporally control a process, fast straightforward environmentally benign features, lead established emerging applications biolubrication, antifouling, biosensing.

Язык: Английский

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Multifunctional coatings based on candle soot with photothermal bactericidal property and desired biofunctionality

Journal of Colloid and Interface Science, Год журнала: 2023, Номер 649, С. 986 - 995

Опубликована: Июнь 27, 2023

Язык: Английский

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