Iodonium cation stabilizes square-planar configuration of the silver(I) tetratriflate

Inorganica Chimica Acta, Год журнала: 2024, Номер 568, С. 122079 - 122079

Опубликована: Апрель 23, 2024

Язык: Английский

---

Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors

Molecules, Год журнала: 2022, Номер 27(12), С. 3859 - 3859

Опубликована: Июнь 16, 2022

Three supramolecular bromostannates(IV) with "trapped" diiodine molecules, Cat2{[SnBr6](I2)} (Cat = Me4N+ (1), 1-MePy+ (2) and 4-MePyH (3)), were synthesized. In all cases, I2 linkers are connected bromide ligands via halogen···halogen non-covalent interactions. Articles 1-3 studied using Raman spectroscopy, thermogravimetric analysis, diffuse reflectance spectroscopy. The latter indicates that narrow band gap semiconductors.

Язык: Английский

---

Recent Progress in the Theoretical Studies of the Noncovalent Interactions of Supramolecular Complexes with Polyhalides and Halometalates

Compounds, Год журнала: 2022, Номер 3(1), С. 27 - 36

Опубликована: Дек. 30, 2022

Despite the fact that first polyhalides and halometalates have been discovered decades ago, this subject of chemical science has progressing, many supramolecular associates with these compounds exhibiting promising properties were reported. In mini-review, I would like to highlight recent progress in theoretical studies noncovalent interactions complexes from our research group.

Язык: Английский

---