Iodonium cation stabilizes square-planar configuration of the silver(I) tetratriflate
Inorganica Chimica Acta,
Год журнала:
2024,
Номер
568, С. 122079 - 122079
Опубликована: Апрель 23, 2024
Язык: Английский
Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors
Molecules,
Год журнала:
2022,
Номер
27(12), С. 3859 - 3859
Опубликована: Июнь 16, 2022
Three
supramolecular
bromostannates(IV)
with
"trapped"
diiodine
molecules,
Cat2{[SnBr6](I2)}
(Cat
=
Me4N+
(1),
1-MePy+
(2)
and
4-MePyH
(3)),
were
synthesized.
In
all
cases,
I2
linkers
are
connected
bromide
ligands
via
halogen···halogen
non-covalent
interactions.
Articles
1-3
studied
using
Raman
spectroscopy,
thermogravimetric
analysis,
diffuse
reflectance
spectroscopy.
The
latter
indicates
that
narrow
band
gap
semiconductors.
Язык: Английский
Recent Progress in the Theoretical Studies of the Noncovalent Interactions of Supramolecular Complexes with Polyhalides and Halometalates
Compounds,
Год журнала:
2022,
Номер
3(1), С. 27 - 36
Опубликована: Дек. 30, 2022
Despite
the
fact
that
first
polyhalides
and
halometalates
have
been
discovered
decades
ago,
this
subject
of
chemical
science
has
progressing,
many
supramolecular
associates
with
these
compounds
exhibiting
promising
properties
were
reported.
In
mini-review,
I
would
like
to
highlight
recent
progress
in
theoretical
studies
noncovalent
interactions
complexes
from
our
research
group.
Язык: Английский