Aza-metallacycle with a heptavalent Re(d0) center DOI

Qianhang Wang,

Yarong Wang, Yue Zhao

и другие.

Dalton Transactions, Год журнала: 2024, Номер 53(31), С. 12872 - 12875

Опубликована: Янв. 1, 2024

The oxidation state of the metal center is important for a conjugated metallacycle. Although high valent d

Язык: Английский

Preparation and Aromaticity of Rhenacycloprop-2-ene-containing Polycyclic Compounds DOI

Liyan Zhan,

Yukang Fu,

Yue Zhao

и другие.

Organometallics, Год журнала: 2023, Номер 42(19), С. 2800 - 2805

Опубликована: Сен. 21, 2023

In this work, we present the synthesis and characterization of fused rhenabenzofuran rhenapyrylium complexes with a metallacycloprop-2-ene unit from reactions ReCl3(PMePh2)3 alkynylphenols alkynylacetophenones, respectively. The aromaticity these structures is investigated by DFT studies, showing σ-predominant in three-membered units.

Язык: Английский

Процитировано

2
Metallacyclopropene Complexes from the Reactions of ReCl3(PMePh2)3 with o-Halophenylacetylenes DOI

X.F. Zhang,

Peiqi Wang, Yue Zhao

и другие.

Journal of Organometallic Chemistry, Год журнала: 2024, Номер unknown, С. 123496 - 123496

Опубликована: Дек. 1, 2024

Язык: Английский

Процитировано

0
Aza-metallacycle with a heptavalent Re(d0) center DOI

Qianhang Wang,

Yarong Wang, Yue Zhao

и другие.

Dalton Transactions, Год журнала: 2024, Номер 53(31), С. 12872 - 12875

Опубликована: Янв. 1, 2024

The oxidation state of the metal center is important for a conjugated metallacycle. Although high valent d

Язык: Английский

Процитировано

0