Apart
from
the
visual
effects,
geometric
shapes
of
materials
play
an
important
role
in
their
engineering
and
biomedical
applications.
Responsive
materials-based
patient-specific
anatomical
models
provide
better
insights
into
structure
pathology.
Polymers
are
by
far
most
utilized
class
for
advanced
science
technology.
Because
these
properties,
polymers
have
been
used
as
functional
coatings,
thermoplastics,
materials,
separators,
binders
Li-ion
batteries,
fuel
cell
membranes,
piezoelectric
devices,
high-quality
wires
cables,
so
on.
Reactive
to
stimuli
because
unusual
electrical
characteristics
adaptability,
stimuli-responsive
multiacceptor
conjugated
a
prominent
focus
study.
These
combine
several
electron-accepting
units
inside
backbone,
resulting
increased
functionality
responsiveness
variety
stimuli.
The
production,
workings,
wide
range
applications
this
review.
Hybrid Advances,
Год журнала:
2024,
Номер
6, С. 100233 - 100233
Опубликована: Июнь 26, 2024
This
state-of-the
art
review
is
designed
to
state
the
competence
of
fullerene
nanostructures
in
optoelectronic
devices.
Fullerene
molecules
own
valuable
structural,
electronic,
optical,
electrical,
and
physical
properties
be
employed
optoelectronics
device
sector.
Especially,
modification
nanocomposite
formation
led
high
performance
light
emitting
diodes,
optical
sensors,
photovoltaics
systems.
Combination
conjugated
polymers/molecules
with
has
found
further
enhance
efficacy
towards
these
In
form,
have
been
known
develop
conjugation
conducting
polymers
for
better
charge,
hole,
or
electron
transference
leading
assistances.
Consequently,
like
poly(3-hexylthiophene),
poly(3,4-ethylenedioxythiophene),
poly(3-hexylthiophene-2,5-diyl),
polystyrene
sulfonate,
polycyclopenta-dithiophene-benzothiadiazole,
poly(2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene),
4,4′-bis[(p-trichlorosilylpropylphenyl)phenylamino]
biphenyl,
etc.
reinforced
utilized.
Polymers
grafted
fullerenes
such
as
[6,6]-phenyl
C61-butyric
acid
methyl
ester
[6,6]-phenyl-C61-butyric
hexyl
also
recognized.
addition,
non-conducting
poly(methyl
methacrylate)
was
exploited.
Mostly,
C60
C70
preferred
nanofiller
assemblies.
Effectiveness
nanomaterials
observed
luminescent
solar
cells
(bulk
heterojunction/polymer/perovskite),
sensors
(photo-/organic/bacterial
sensing).
Nevertheless,
designs
need
comprehensively
investigated
by
overcoming
underlying
working
mechanism,
fabrication,
challenges
related
fields.
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 10, 2024
Concurrently
achieving
high
efficiency,
mechanical
robustness
and
thermal
stability
is
critical
for
the
commercialization
of
all-polymer
solar
cells
(APSCs).
However,
APSCs
usually
demonstrate
complicated
morphology,
primarily
attributed
to
polymer
chain
entanglement
which
has
a
detrimental
effect
on
their
fill
factors
(FF)
morphology
stability.
To
address
these
concerns,
an
end-group
extended
acceptor,
PY-NFT,
was
synthesized
studied.
The
analysis
showed
tightly
ordered
molecular
packing
mode
favorable
phase
separation
formed.
PM6
:
PY-NFT-based
device
achieved
exceptional
PCE
19.12
%
(certified
as
18.45
%),
outperforming
control
PY-FT
devices
(17.14
%).
This
significant
improvement
highlights
record-high
binary
APSCs.
aging
study
revealed
that
PY-NFT
blend
exhibited
excellent
morphological
stability,
thereby
superior
retaining
90
initial
efficiency
after
enduring
stress
(65
°C)
1500
hours.
More
importantly,
film
outstanding
ductility
with
crack
onset
strain
24.1
%.
Overall,
rational
chemical
structure
innovation,
especially
conjugation
extension
strategy
trigger
appropriate
stable
key
improved
robust
Apart
from
the
visual
effects,
geometric
shapes
of
materials
play
an
important
role
in
their
engineering
and
biomedical
applications.
Responsive
materials-based
patient-specific
anatomical
models
provide
better
insights
into
structure
pathology.
Polymers
are
by
far
most
utilized
class
for
advanced
science
technology.
Because
these
properties,
polymers
have
been
used
as
functional
coatings,
thermoplastics,
materials,
separators,
binders
Li-ion
batteries,
fuel
cell
membranes,
piezoelectric
devices,
high-quality
wires
cables,
so
on.
Reactive
to
stimuli
because
unusual
electrical
characteristics
adaptability,
stimuli-responsive
multiacceptor
conjugated
a
prominent
focus
study.
These
combine
several
electron-accepting
units
inside
backbone,
resulting
increased
functionality
responsiveness
variety
stimuli.
The
production,
workings,
wide
range
applications
this
review.
