Graphene Oxide‐Modulated CMC/PVA Films with on‐Demand Shape Recovery and Self‐Healing Performance DOI

Changdong Ju,

Huabo Huang,

Xianghua Yu

и другие.

Macromolecular Rapid Communications, Год журнала: 2025, Номер unknown

Опубликована: Май 20, 2025

Abstract With the advancement of artificial intelligence technologies, shape‐memory polymers (SMPs) have attracted significant research interest due to their remarkable environmental responsiveness. However, conventional SMPs are limited single‐stimulus responsiveness and constrained performance, failing meet practical application demands. This study develops a novel carboxymethyl cellulose (CMC) polyvinyl alcohol (PVA) composite film modulated by graphene oxide (GO) with multi‐stimuli responsive capabilities water‐assisted self‐healing properties. The introduction GO significantly enhances mechanical properties, provides efficient swelling‐resistant ability thermal conversion efficiency film, endowing it on‐demand performance under water stimulation. It can achieve shape fixation rate 94.45% recovery 97.22%. Meanwhile, behaviors be precisely tailored modulating content PVA as well interfacial interactions. Furthermore, films water‐triggered 90.6% efficiency, which is attributed inherent hydrophilic nature dynamic physical crosslinking architecture. demonstrates strategy for creating stimuli‐adaptive materials, providing pivotal platform in flexible actuation devices intelligent medical systems.

Язык: Английский

Shape memory polymer and composites for space applications: A review DOI
Avadesh Yadav, Sourabh Kumar Singh,

Sreetam Das

и другие.

Polymer Composites, Год журнала: 2025, Номер unknown

Опубликована: Фев. 27, 2025

Abstract During the last few years, shape memory polymers (SMP) have become popular among researchers and industrialists belonging to various areas of application owing their exceptional qualities such as high recoverable strain, about four times its initial length compared conventional alloys (~8%), good tailorability, lighter weight, cheaper material, processing cost. Enormous work has been done develop SMP multifunctional composites (SMPC). Incorporating functional materials in gives SMPC enhanced properties over SMP, higher recovery load at a rate, improved mechanical properties, controlled remote actuation. Due these remarkable are broadly employed space‐deployable structures components. being stimuli‐responsive polymers, after substantial deformation, may return previous under applied stimuli like direct heating, electrically induced magnetically light, chemical. Among different thermo‐responsive electro‐responsive widely used for structural space applications. This reports thorough review mechanisms, programming, stimulus, modeling, applications space. Highlights exhibits programmability stimulus responsiveness. enhance thermo‐mechanical pristine SMP. Epoxy, PU, styrene, cyanate‐based explored Space environments vacuum UV radiations affect characteristics. can be antennas hinges.

Язык: Английский

Процитировано

2

Shape Memory Polymers, Blends, and Composites: Processing, Properties, and Applications DOI

Chitte Prem Kumar,

N. Sivanagaraju,

Devada Loknath

и другие.

Polymer-Plastics Technology and Materials, Год журнала: 2025, Номер unknown, С. 1 - 29

Опубликована: Фев. 24, 2025

Язык: Английский

Процитировано

1

Dynamic reactive synthesis of bio-based compatibilizer via diepoxide monomers grafting polylactic acid and reactive compatibilization of incompatible polylactic acid/bamboo powder composites DOI
Zijun Zhang,

Xinyue Yao,

Yan Xu

и другие.

International Journal of Biological Macromolecules, Год журнала: 2025, Номер unknown, С. 141928 - 141928

Опубликована: Март 1, 2025

Язык: Английский

Процитировано

0

Tailored Polylactic Acid/Polycaprolactone Blends with Excellent Strength–Stiffness and Shape Memory Capacities DOI Open Access
Todor Batakliev, Vladimir Georgiev, Evgeni Ivanov

и другие.

Processes, Год журнала: 2025, Номер 13(5), С. 1328 - 1328

Опубликована: Апрель 26, 2025

The present work deals with the mixing of two green polymers at several definite ratios that led to receiving biodegradable polylactic acid (PLA)/polycaprolactone (PCL) blends possessing well-expressed macromechanical and shape memory properties. Four non-compatibilized polymer compositions were prepared by using a twin-screw melt extrusion technique, allowing for homogeneous dispersion PCL droplets in PLA matrix higher interfacial adhesion between phases. mechanical behavior specimens was estimated tensile experiments conducted three particular crosshead velocities. It established addition as soft segment redounded an increment toughness elongation ultimate strength composite expense maximum stress Young’s modulus. These latter parameters found be more sensitive, terms reaching high values, content hard blend. Performing thermoresponsive tests disclosed overwhelming reversibility temporary permanent states materials, including significant fixation (Rf) recovery (Rr) rates. SEM analysis PLA/PCL revealed distinct phase-separated microstructure, confirming immiscibility

Язык: Английский

Процитировано

0

Fundamentals and Recent Applications of 3D, 4D, and 5D Printing of Polymer and Its Nanocomposites: Challenges and Its Future Prospects DOI
Abhinay Thakur, Valentine Chikaodili Anadebe, Omar Dagdag

и другие.

Engineering materials, Год журнала: 2025, Номер unknown, С. 345 - 392

Опубликована: Янв. 1, 2025

Язык: Английский

Процитировано

0

Graphene Oxide‐Modulated CMC/PVA Films with on‐Demand Shape Recovery and Self‐Healing Performance DOI

Changdong Ju,

Huabo Huang,

Xianghua Yu

и другие.

Macromolecular Rapid Communications, Год журнала: 2025, Номер unknown

Опубликована: Май 20, 2025

Abstract With the advancement of artificial intelligence technologies, shape‐memory polymers (SMPs) have attracted significant research interest due to their remarkable environmental responsiveness. However, conventional SMPs are limited single‐stimulus responsiveness and constrained performance, failing meet practical application demands. This study develops a novel carboxymethyl cellulose (CMC) polyvinyl alcohol (PVA) composite film modulated by graphene oxide (GO) with multi‐stimuli responsive capabilities water‐assisted self‐healing properties. The introduction GO significantly enhances mechanical properties, provides efficient swelling‐resistant ability thermal conversion efficiency film, endowing it on‐demand performance under water stimulation. It can achieve shape fixation rate 94.45% recovery 97.22%. Meanwhile, behaviors be precisely tailored modulating content PVA as well interfacial interactions. Furthermore, films water‐triggered 90.6% efficiency, which is attributed inherent hydrophilic nature dynamic physical crosslinking architecture. demonstrates strategy for creating stimuli‐adaptive materials, providing pivotal platform in flexible actuation devices intelligent medical systems.

Язык: Английский

Процитировано

0