Chemical Communications,
Год журнала:
2024,
Номер
unknown
Опубликована: Дек. 3, 2024
This
feature
article
mainly
outlines
the
advances
in
precise
design
of
inorganic-
and
organic-based
porous
electrocatalysts
towards
enhancement
oxygen
evolution
reaction
(OER)
properties
to
achieve
efficient
water-splitting
reaction.
Journal of Materials Chemistry A,
Год журнала:
2024,
Номер
12(28), С. 17252 - 17259
Опубликована: Янв. 1, 2024
The
selective
oxidation
of
organic
small
molecules
not
only
promotes
cathodic
hydrogen
production,
but
also
acts
as
an
alternative
reaction
to
the
anodic
oxygen
evolution
electrolytic
water,
producing
value-added
products
at
anode.
Energy Technology,
Год журнала:
2025,
Номер
unknown
Опубликована: Фев. 9, 2025
Designing
electrocatalysts
with
high‐performance
potential
requires
a
thorough
investigation
of
the
relationships
between
property
changes
and
electrocatalytic
activity.
This
study
compares
effect
N‐doping
N,
S‐codoping
on
properties
waste
floral
foam
derived
pristine
nanoporous
carbon
to
enhance
modulates
textural,
structural,
chemical
that
are
preferable
oxygen
evolution
reaction
(OER)
hydrogen
(HER)
performance.
S‐codoped
having
large
surface
area
(1231
m
2
g
−1
),
higher
content
defects,
OH−,
CO,
pyridinic
N
exhibits
superior
OER
HER
activity
overpotentials
290
−180
mV,
respectively
at
10
mA
cm
−2
,
emphasizing
synergetic
dual
atoms
nitrogen
(N)
sulfur
(S)
in
enhancing
The
work
proposed
here
presents
implementation
“waste‐to‐energy”
through
repurposing
into
as
metal‐free
bifunctional
electrocatalyst
for
HER.
Energy & Fuels,
Год журнала:
2024,
Номер
38(8), С. 7218 - 7230
Опубликована: Апрель 2, 2024
Oxygen
evolution
reaction
(OER)
impedes
the
electrochemical
water
splitting
for
H2
production,
ascribing
to
depressed
kinetics
of
four
proton-coupled
transfer
process.
Transition
metal
oxides,
especially
bimetallic
have
been
proven
be
promising
OER
electrocatalysts
due
their
part
unoccupied
d-band
characteristics.
More
interestingly,
oxygen
vacancies
(Ov)
easily
constructed
in
transition
oxides
can
modulate
electron
structures
and
thereby
boost
performance.
However,
most
synthesized
processes
involving
vacancy
engineering,
such
as
atom
dopant,
chemical/electrochemical
reduction,
H2/Ar-dependent
calcination,
are
energy-intensive
time-consuming,
largely
hampering
commercial
applications.
Herein,
we
suggest
a
simple
facile
strategy
fabricating
double
spinel
with
abundant
by
calcinating
Ni/Fe@ZIF-67/CC
precursor
under
nonoxidation
condition.
The
obtained
Ov-CF1N2O@NC/CC-550
vast
exhibits
excellent
performance,
representing
lower
overpotential
185
mV
at
10
mA
cm–2,
smaller
Tafel
slope
47.3
dec–1,
well
faster
interface
(Rct
=
0.7336).
Theoretical
calculations
further
confirm
that
activity
strongly
corresponds
center
active
sites
on
Ov-CoFe2O4
(311)
model
decreased
Gibbs
energy
barrier.
work
might
shed
light
engineering
via
inspire
smart
design
multimetallic
oxide
high
ABSTRACT
The
growing
global
energy
demand
and
environmental
concerns
like
greenhouse
gas
emissions
call
for
clean
solutions.
Hydrogen
energy,
with
high
caloric
value
low
impact,
is
a
promising
alternative,
especially
when
produced
via
proton
exchange
membrane
water
electrolysis
(PEMWE).
This
process
relies
on
the
hydrogen
evolution
reaction
(HER)
oxygen
(OER),
both
requiring
efficient
electrocatalysts.
Platinum
(Pt),
most
effective
HER
catalyst,
limited
by
cost
scarcity,
prompting
research
into
Pt
alternatives
ruthenium‐based,
transition
metal
derivatives,
metal‐free
catalysts
that
balance
cost,
efficiency,
stability.
review
explores
mechanisms,
Pt‐free
catalyst
innovations,
impact
of
structural
interfacial
electrode
optimization
performance
in
acidic
media.
It
also
examines
electrochemical
evaluation
techniques,
material
characterization,
role
machine
learning
design.
By
providing
framework
development,
this
supports
advancements
sustainable
technologies.