Utilization of bio-based monomer derived from camelina oil and itaconic acid for the synthesis of film-forming latexes
Abstract
The
need
for
the
production
of
synthetic
polymers
from
renewable
and
sustainable
resources
also
affects
area
emulsion
polymerization.
bio-based
monomer
(BM)
was
synthesized
camelina
oil
(CO)
itaconic
acid
through
transesterification
epoxidation
CO,
followed
by
itaconation,
resulting
in
a
blend
methyl
esters
CO-originated
fatty
acids
functionalized
with
reactive
itaconate
groups.
Various
amounts
BM
were
copolymerized
standard
acrylic
monomers
(0−30
wt.
%
mixture)
using
polymerization
technique
to
obtain
film-forming
latexes.
Infrared
Raman
spectroscopies
evidenced
successful
incorporation
into
structure
latex
polymers.
ultra-high
molar
mass
nanogel
fraction
detected
asymmetric
flow-field
flow
fractionation
coupled
multiangle
light
scattering
(AF4-MALS)
comprising
copolymers;
higher
content,
more
extensive
fraction.
Crosslinking
induced
testified
reactivity
itaconated
functions
provided
additional
evidence
copolymerization
ability
BM.
resulted
hardness
glass
transition
temperature
enhancement
(about
11%
9°C,
respectively,
case
30
content
contrast
0
copolymer).
Coatings
excellent
transparency
gloss
obtained
all
latexes
regardless
used.
Slightly
increased
water
repellency
7
°
contact
angle
value)
significantly
improved
whitening
resistance
coatings
80%
decreased
after
1-day
long
exposure)
found
copolymer,
where
phenomenon
highly
dependent
on
content.
Research Square (Research Square), Год журнала: 2024, Номер unknown
Опубликована: Окт. 21, 2024
Язык: Английский