Talanta, Год журнала: 2024, Номер 286, С. 127430 - 127430
Опубликована: Дек. 19, 2024
Язык: Английский
Talanta, Год журнала: 2024, Номер 286, С. 127430 - 127430
Опубликована: Дек. 19, 2024
Язык: Английский
Biosensors, Год журнала: 2025, Номер 15(3), С. 137 - 137
Опубликована: Фев. 23, 2025
Curcumin (CU, turmeric), a polyphenolic phytochemical that is largely used as food spice, has benefits for human health, which have led to increased interest in its therapeutic applications and analysis from different matrices. The two guaiacol moieties of CU are responsible antioxidant properties allow voltammetric quantification. Cyclic differential pulse voltammetry (DPV) investigations at single-use pencil graphite electrode (PGE) emphasized complex pH-dependent processes, involving an equal number protons electrons. Theoretical calculations predicted folded geometry the β-diketone conformers, interact with PGE surface, exposing electroactive only one aromatic ring. Gibbs energy variations structures involved electro-oxidation theoretical electrochemical potential values were calculated. CU’s DPV cathodic peak intensity recorded HB-type 0.05 mol × L−1 H2SO4 varied linearly range 5.00 10−8–5.00 10−6 CU. method’s detection quantification limits 2.12 10−8 6.42 L−1, respectively. practical applicability developed method, successfully tested by assessment dietary supplements, provided recovery 99.28 ± 2.04%.
Язык: Английский
Процитировано
0Talanta, Год журнала: 2024, Номер 286, С. 127430 - 127430
Опубликована: Дек. 19, 2024
Язык: Английский
Процитировано
0