Advanced Energy Materials,
Год журнала:
2024,
Номер
14(31)
Опубликована: Май 21, 2024
Abstract
Aqueous
batteries
using
non‐metallic
charge
carriers
like
proton
(H
+
)
and
ammonium
(NH
4
ions
are
becoming
more
popular
compared
to
traditional
metal‐ion
batteries,
owing
their
enhanced
safety,
high
performance,
sustainability
(they
ecofriendly
derived
from
abundant
resources).
Ammonium
ion
energy
storage
systems
(AIBs),
which
use
NH
with
tetrahedral
geometry,
a
small
hydrated
ionic
radius,
relatively
low
weight,
emerging
as
strong
candidates
in
non‐metal
battery
chemistry.
Various
electrode
materials
(both
inorganic
organic)
investigated
hosts
for
ions,
however,
comprehensive
understanding
of
these
mechanisms
is
still
lacking.
This
gap
limits
the
ability
optimize
performance
identify
further
research
opportunities
AIBs.
In
this
review,
AIBs
discussed,
offering
insights
into
interactions
between
different
materials.
Additionally,
existing
literature
on
materials,
highlighting
key
structural,
electrochemical
achievements
summarized.
The
review
also
outlines
various
electrolytes
examines
how
properties
influence
AIB
performance.
Finally,
shortcomings
current
discussed
potential
solutions
suggested
advance
technology,
goal
inspiring
researchers
explore
real‐world
applications
batteries.
Journal of Power Sources,
Год журнала:
2024,
Номер
617, С. 235140 - 235140
Опубликована: Авг. 1, 2024
Carbon
materials
play
a
fundamental
role
in
electrochemical
energy
storage
due
to
their
appealing
properties,
including
low
cost,
high
availability,
environmental
impact,
surface
functional
groups,
electrical
conductivity,
alongside
thermal,
mechanical,
and
chemical
stability,
among
other
factors.
Currently,
carbon
can
be
considered
the
most
extensively
explored
family
field
of
supercapacitors
batteries,
which
are
devices
covering
wide
range
applications
demanding
power
energy.
However,
as
with
all
technologies,
there
is
process
adaptation
optimization;
hence,
have
been
aligning
advances
that
emerge.
Similarly,
over
years,
new
methods
processes
discovered
produce
carbons
more
suitable
for
storage,
adapting
them
present
good
synergy
metal-based
compounds
meet
current
standards.
In
this
work,
we
compilation
used
from
inception
these
technologies
day.
Angewandte Chemie International Edition,
Год журнала:
2024,
Номер
63(28)
Опубликована: Май 7, 2024
Alkali
metals
(e.g.
Li,
Na,
and
K)
multivalent
Zn,
Mg,
Ca,
Al)
have
become
star
anodes
for
developing
high-energy-density
rechargeable
batteries
due
to
their
high
theoretical
capacity
excellent
conductivity.
However,
the
inevitable
dendrites
unstable
interfaces
of
metal
pose
challenges
safety
stability
batteries.
To
address
these
issues,
covalent
organic
frameworks
(COFs),
as
emerging
materials,
been
widely
investigated
regular
porous
structure,
flexible
molecular
design,
specific
surface
area.
In
this
minireview,
we
summarize
research
progress
COFs
in
stabilizing
anodes.
First,
present
origins
delve
into
advantages
based
on
physical/chemical
properties
alkali
metals.
Then,
special
attention
has
paid
application
host
design
anodes,
artificial
solid
electrolyte
interfaces,
additives,
solid-state
electrolytes,
separator
modifications.
Finally,
a
new
perspective
is
provided
from
pore
modulation,
synthesis
COFs.
Nano-Micro Letters,
Год журнала:
2024,
Номер
16(1)
Опубликована: Май 14, 2024
Aqueous
zinc-ion
batteries
(AZIBs)
are
one
of
the
most
compelling
alternatives
lithium-ion
due
to
their
inherent
safety
and
economics
viability.
In
response
growing
demand
for
green
sustainable
energy
storage
solutions,
organic
electrodes
with
scalability
from
inexpensive
starting
materials
potential
biodegradation
after
use
have
become
a
prominent
choice
AZIBs.
Despite
gratifying
progresses
molecules
electrochemical
performance
in
AZIBs,
research
is
still
infancy
hampered
by
certain
issues
underlying
complex
electrochemistry.
Strategies
designing
electrode
AZIBs
high
specific
capacity
long
cycling
life
discussed
detail
this
review.
Specifically,
we
put
emphasis
on
unique
electrochemistry
different
redox-active
structures
provide
in-depth
understanding
working
mechanisms.
addition,
highlight
importance
molecular
size/dimension
regarding
profound
impact
performances.
Finally,
challenges
perspectives
developing
point
view
future
We
hope
valuable
evaluation
our
context
give
inspiration
rational
design
high-performance
Nano Energy,
Год журнала:
2024,
Номер
122, С. 109269 - 109269
Опубликована: Янв. 11, 2024
The
primary
Mg-air
battery
shows
extraordinary
theoretical
energy
density
to
satisfy
the
requirements
that
traditional
rechargeable
batteries
cannot
reach.
However,
has
failed
live
its
potential
due
low
operating
discharge
voltage,
parasitical
anodic
hydrogen
reaction
and
irreversible
corrosion.
To
address
these
issues,
we
devised
a
process
generate
ultra-high-purity
(UHP)
Mg-Ge
anodes
for
batteries.
Ge
addition
enhances
activity
suppresses
evolution
(AHER).
Hence,
fabricated
UHP
Mg-0.5Ge
anode
exhibited
remarkably
high
voltage
of
1.69
V
(0.5
mA
cm-2)
coupled
with
2272
mWh
g-1
(20
cm-2).
These
values
are
higher
than
all
reported
Mg-based
in
literature.
Furthermore,
minimal
impurity
content
development
Ge-bearing
surface
layer
contribute
achieving
95%
intermittent
efficiency,
which
is
3.5
times
commonly
employed
AZ31
anode.
outstanding
properties
set
stage
advancing
next
generation
ACS Materials Letters,
Год журнала:
2024,
Номер
6(5), С. 1938 - 1960
Опубликована: Апрель 12, 2024
Aqueous
zinc-ion
batteries
(AZIBs)
are
increasingly
regarded
as
promising
candidates
for
large-scale
energy
storage,
because
of
their
advantageous
features
such
high
safety,
low
cost,
abundant
resources,
and
environmental
friendliness.
However,
challenges
persist
with
zinc
anodes,
including
issues
Coulombic
efficiency
(CE)
poor
long-term
cycle
stability
due
to
dendrites,
hydrogen
evolution,
passivation
reactions.
These
mainly
attributed
the
thermodynamic
instability
anodes
in
aqueous
electrolytes,
leading
a
shorter
battery
life.
The
optimization
electrolyte
structure
has
emerged
straightforward
impactful
strategy,
making
substantial
advancements
addressing
associated
systematic
manner.
This
account
undertakes
comprehensive
analysis
formation
process
interface
between
anode.
Strategies
involve
precise
regulation
Zn
nucleation
layer,
construction
situ
artificial
anode
optimization,
design
solid
interphase
(SEI)
protective
layer.
By
delving
into
these
critical
aspects,
review
aims
provide
concise
synthesis
future
outlook
on
strategies
batteries,
offering
valuable
insights
enhancing
overall
performance.
Chemical Society Reviews,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
This
review
explores
the
latest
advancements
in
potassium
metal
batteries,
including
electrode
design,
interface
engineering,
and
electrolyte
optimization
to
suppress
dendrite
formation
enhance
cycling
stability.
Advanced Materials,
Год журнала:
2023,
Номер
36(9)
Опубликована: Дек. 13, 2023
Abstract
Utilizing
metal
anode
is
the
most
attractive
way
to
meet
urgent
demand
for
rechargeable
batteries
with
high
energy
density.
Unfortunately,
formation
of
dendrites,
which
caused
by
uneven
plating
behavior,
always
threaten
safety
batteries.
To
explore
origin
different
behavior
and
predict
morphology
under
a
variety
operating
conditions,
multifarious
models
have
been
developed.
However,
abuse
has
led
conflictive
views.
In
this
perspective,
clarify
controversial
reports
on
magnesium
(Mg)
previously
proposed
are
elaborated
that
govern
process.
Through
linking
various
clarifying
their
boundary
scheme
drawn
illustrate
strategy
achieving
dense
uniform
morphology,
also
explains
seemingly
contradictory
diffusion
limited
theory
nucleation
plating.
This
perspective
will
undoubtedly
enhance
understanding
process
provide
meaningful
guidance
development
ACS Applied Materials & Interfaces,
Год журнала:
2024,
Номер
16(5), С. 6033 - 6047
Опубликована: Янв. 29, 2024
Transition
metal
selenides
have
received
considerable
attention
as
promising
candidates
for
lithium-ion
battery
(LIB)
anode
materials
due
to
their
high
theoretical
capacity
and
safety
characteristics.
However,
commercial
viability
is
hampered
by
insufficient
conductivity
volumetric
fluctuations
during
cycling.
To
address
these
issues,
we
utilized
bimetallic
metal-organic
frameworks
fabricate
CoNiSe
