Nanoscale Advances,
Год журнала:
2022,
Номер
4(5), С. 1263 - 1307
Опубликована: Янв. 1, 2022
A
comprehensive
survey
is
presented
to
review
the
recent
advances
of
functionalized
hybrid
magnetic
catalytic
systems
for
organic
reactions
and
degradation
dyes.
Abstract
The
fast
increase
of
population
results
in
the
quick
development
industry
and
agriculture.
Large
amounts
contaminants
such
as
metal
ions
organic
are
released
into
natural
environment,
posing
a
risk
to
human
health
causing
environment
ecosystem
problems.
efficient
elimination
from
aqueous
solutions,
photocatalytic
degradation
pollutants
or
in-situ
solidification/immobilization
heavy
solid
phases
most
suitable
strategies
decontaminate
pollution.
Biochar
biochar-based
composites
have
attracted
multidisciplinary
interests
especially
environmental
pollution
management
because
their
porous
structures,
large
functional
groups,
high
adsorption
capacities
photocatalysis
performance.
In
this
review,
application
biochar
adsorbents
and/or
catalysts
for
different
contaminants,
adsorption-photodegradation
pollutants,
adsorption-(photo)reduction
summarized,
mechanism
was
discussed
advanced
spectroscopy
analysis
DFT
calculation
detail.
doping
oxides
is
main
strategy
narrow
band
gap,
generation
separation
photogenerated
e
−
-h
+
pairs,
produce
more
superoxide
radicals
(·O
2
)
hydroxyl
(·OH),
enhance
visible
light
absorption
performance,
which
dominate
(photo)reduction
valent
metals
low
metals.
environmentally
friendly
materials,
promising
candidates
cleanup.
challenge
perspective
provided
end.
Graphical
Abstract
Contamination
of
aquatic
and
soil
systems
by
organic
inorganic
pollutants
has
become
a
serious
issue
concern
worldwide.
Viable
cost-effective
solutions
are
urgently
needed
to
mitigate
the
negative
impacts
diverse
on
environment
human
health.
Biochar
emerged
as
an
effective
green
material
for
remediation
wide
spectrum
(in)organic
pollutants.
However,
applications
pristine
biochar
in
decontamination
have
encountered
bottlenecks
due
its
limited
properties
which
cannot
meet
desired
requirements.
Therefore,
multiple
modification
methods
been
developed
tailoring
physicochemical
enhance
effectiveness
environmental
decontamination.
This
work
provides
holistic
review
recent
advances
synthesis
engineered
using
physical,
chemical,
biological
methods.
Further
related
mechanisms
field
also
summarized
discussed.
In
addition,
existing
challenges
research
gaps
outlined,
future
needs
proposed.
summarizes
scientific
opportunities
comprehensive
understanding
biochars
materials
contaminated
water
soil.
Graphical
abstract
Toxics,
Год журнала:
2023,
Номер
11(2), С. 117 - 117
Опубликована: Янв. 25, 2023
The
current
water
crisis
necessitates
the
development
of
new
materials
for
wastewater
treatment.
A
variety
nanomaterials
are
continuously
being
investigated
their
potential
as
adsorbents
environmental
remediation.
Researchers
intend
to
develop
a
low-cost,
simple,
and
sustainable
material
that
can
cater
removal
pollutants.
Biochar
derived
from
biowaste
is
candidate
existing
problem
pollution.
review
focuses
on
various
aspects
biochar,
such
its
sources,
preparation
methods,
mechanism,
applications
treatment,
regeneration.
Compared
with
other
adsorbents,
biochar
considered
an
environmentally
friendly,
sustainable,
cost-effective
substitute
waste
management,
climate
protection,
soil
improvement,
etc.
special
properties
porosity,
surface
area,
charge,
functional
groups
be
easily
modified
by
chemical
resulting
in
improved
adsorption
properties.
Therefore,
view
increasing
pollution
problems
encountered
researchers
treating
pollutants,
great
importance.
This
also
highlights
challenges
prospective
areas
explored
studied
more
detail
future.
Catalysts,
Год журнала:
2022,
Номер
12(8), С. 817 - 817
Опубликована: Июль 26, 2022
Nowadays,
biochar
is
being
studied
to
a
great
degree
because
of
its
potential
for
carbon
sequestration,
soil
improvement,
climate
change
mitigation,
catalysis,
wastewater
treatment,
energy
storage,
and
waste
management.
The
present
review
emphasizes
on
the
utilization
biochar-based
nanocomposites
play
key
role
in
decontaminating
dyes
from
wastewater.
Numerous
trials
are
underway
synthesize
functionalized,
surface
engineered
that
can
sufficiently
remove
dye-contaminated
removal
via
natural
modified
follows
numerous
mechanisms
such
as
precipitation,
complexation,
ion
exchange,
cation–π
interactions,
electrostatic
attraction.
Further,
production
modification
promote
good
adsorption
capacity
dye
owing
properties
tailored
stage
linked
with
specific
hydrophobic
interactions.
Meanwhile,
framework
artificial
neural
networking
machine
learning
model
efficiency
proposed
even
though
studies
still
their
infancy
stage.
article
recommends
smart
technologies
modelling
forecasting
should
be
included
proper
applications.