Environmental Science & Technology,
Год журнала:
2023,
Номер
57(10), С. 4143 - 4152
Опубликована: Март 2, 2023
To
assess
the
contamination
and
potential
risk
of
snow
melt
with
polar
compounds,
road
background
was
sampled
during
a
melting
event
at
23
sites
city
Leipzig
screened
for
489
chemicals
using
liquid
chromatography
high-resolution
mass
spectrometry
target
screening.
Additionally,
six
24
h
composite
samples
were
taken
from
influent
effluent
wastewater
treatment
plant
(WWTP)
event.
207
compounds
least
detected
once
(concentrations
between
0.80
ng/L
75
μg/L).
Consistent
patterns
traffic-related
dominated
chemical
profile
(58
in
concentrations
1.3
to
μg/L)
among
them
2-benzothiazole
sulfonic
acid
1-cyclohexyl-3-phenylurea
tire
wear
denatonium
used
as
bittern
vehicle
fluids.
Besides,
analysis
unveiled
presence
rubber
additive
6-PPD
its
transformation
product
N-(1.3-dimethylbutyl)-N′-phenyl-p-phenylenediamine
quinone
(6-PPDQ)
known
cause
acute
toxicity
sensitive
fish
species.
The
also
149
other
such
food
additives,
pharmaceuticals,
pesticides.
Several
biocides
identified
major
contributors,
more
site-specific
occurrence,
toxic
risks
algae
(five
samples)
invertebrates
(six
samples).
Ametryn,
flumioxazin,
1,2-cyclohexane
dicarboxylic
diisononyl
ester
are
main
contributing
algae,
while
etofenprox
bendiocarb
found
contributors
crustacean
risk.
Correlations
WWTP
flow
rate
allowed
us
discriminate
urban
runoff
sources
dominant
sources.
Removal
rates
showed
that
some
largely
eliminated
(removal
higher
than
80%)
6-PPDQ,
others
persisted
WWTP.
The Science of The Total Environment,
Год журнала:
2022,
Номер
858, С. 159781 - 159781
Опубликована: Окт. 26, 2022
Urban
areas
play
a
key
role
in
the
production
of
microplastics
(MPs)
and
their
entry
into
water
bodies.
This
article
reviews
literature
on
sources,
transport,
control
MPs
urban
environments
with
aim
clarifying
mechanisms
underlying
these
processes.
Major
MP
sources
include
atmospheric
deposition,
micro-litter,
tire
road
wear
particles
(TRWPs).
deposited
from
atmosphere
are
mostly
fibers
may
be
particularly
important
catchments
without
traffic.
Littering
attrition
textiles
plastic
products
is
another
source.
However,
quantities
originating
this
source
hard
to
estimate.
TRWPs
significant
arguably
best
quantified
The
mobilization
poorly
understood
but
it
appears
that
dry
unconsolidated
sediments
deposits
most
readily
mobilized.
Sequestration
occurs
green
understood.
Consequently,
some
authors
consider
green/pervious
parts
sinks.
Field
studies
have
shown
appreciable
removal
stormwater
quality
facilities.
Street
cleaning
snow
also
remove
(particularly
TRWPs),
efficacy
measures
unknown.
Among
management
facilities,
biofiltration/retention
units
seem
more
effectively
than
facilities
relying
settling.
knowledge
remains
incomplete.
Finally,
although
13
research
papers
reported
concentrations
stormwater,
total
number
field
samples
examined
was
only
189.
Moreover,
results
not
necessarily
comparable
because
they
based
relatively
small
numbers
differ
widely
terms
objectives,
sites,
analytical
methods,
size
fractions,
polymers,
even
terminology.
area
can
thus
considered
"data-poor"
offers
great
opportunities
for
further
many
areas.
Journal of Hazardous Materials Advances,
Год журнала:
2023,
Номер
12, С. 100346 - 100346
Опубликована: Июль 20, 2023
Urbanization
itself
is
a
major
and
furthermost
imperative
contributor
to
the
release
of
microplastics
into
environments.
As
cities
grow
develop,
more
plastic
products
are
consumed
discarded,
resulting
in
increased
pollution
levels.
Although
researches
on
airborne
(AMPs)
urban
regions
scare,
recent
findings
have
shown
high
concentration
them
air
residential
areas.
Textiles
main
source
indoor
ambiance,
while
traffic-related
particles,
textiles
agricultural
marine
appear
be
responsible
for
polluting
cities'
outdoor
atmosphere.
Local
metrological
situation,
topography
physical
features
particles
control
behavior,
distribution
fate
microplastics.
Inhalation
primary
exposure
route
may
induce
toxicity
respiratory
tract.
Understanding
these
factors
crucial
developing
effective
strategies
mitigate
their
impact
human
health
environment.
Current
work
reviews
published
literature
settings
aiming
at
characterizing
parent's
materials,
potential
sources
both
spaces,
possible
impacts
along
with
some
further
suggestions.
Developments in the Built Environment,
Год журнала:
2023,
Номер
15, С. 100188 - 100188
Опубликована: Июнь 23, 2023
Plastics
have
been
extensively
used
in
the
building
and
construction
industries
for
decades.
However,
more
plastics
are
utilised,
microplastics
released.
This
review
analysis
article
summarises
organises
knowledge
from
211
current
related
publications
published
2014–2022.
The
explain
kinds
of
employed
built
environment.
Fabrics
or
textiles,
fibres
cementitious
systems,
paints,
tyres
roads
discussed.
entry
points
into
human
body
reviewed
next,
followed
by
management
recycled
wastes.
important
research
gaps
possible
solutions
include
using
high-strength
concretes
surface-hardening
agents
is
suggested
to
encapsulate
inside
matrix;
DPSIR
model
can
be
holistically
adopted
each
composite;
innovative
bio-chemical
technology
like
self-healing
concrete
bio-degradable
a
viable
choice;
social
science,
law
urban
planning
support
awareness
comprehension.
The Science of The Total Environment,
Год журнала:
2021,
Номер
803, С. 149832 - 149832
Опубликована: Авг. 24, 2021
The
share
of
non-exhaust
particles,
including
tire
wear
particles
(TWP),
within
the
airborne
dust
and
particularly
PM10
has
increased
in
recent
years
due
to
a
significant
reduction
other
exhaust
road
traffic
emissions.
However,
quantification
TWP
is
demanding
task
non-specificity
tracers,
fact
that
they
are
commonly
contained
analytically
challenging
low
concentrations
(e.g.
Zn,
styrene,
1,3-butadiene,
vinylcyclohexene).
This
difficulty
amplified
by
chemical
morpho-textural
heterogeneity
resulting
from
interaction
between
tires
surface.
In
contrast
bulk
techniques,
automated
single
particle
SEM/EDX
analysis
can
benefit
ubiquitous
environmental
as
diagnostic
criterion
for
their
identification
quantification.
For
this
purpose,
we
follow
machine-learning
(ML)
approach
makes
use
an
extensive
number
(67)
morphological,
textural
(backscatter-signal
based)
descriptors
differentiate
into
following
classes:
TWP,
metals,
minerals
biogenic/organic.
We
present
ML-based
model
developed
classify
samples
(trained
>100,000
6841
TWP),
its
application
one-year
monitoring
campaign
at
two
Swiss
sites.
study,
mass
fractions
PM80-10,
PM10-2.5
PM2.5-1
were
determined.
Furthermore,
size
distribution
shape
characteristics
5621
evaluated.
A
cut
through
means
FIB-SEM
evidences
mineral
metal
typically
found
not
only
on
surface
but
also
throughout
complete
volume.
At
urban
background
site,
annual
average
fraction
micro-rubber
was
1.8%
(0.28
μg/m3)
0.9%,
respectively.
kerbside
corresponding
values
6
times
higher
amounting
10.5%
(2.24
5.0%
micro-rubber.
Environmental Science & Technology Letters,
Год журнала:
2021,
Номер
8(12), С. 1057 - 1064
Опубликована: Ноя. 11, 2021
Tire
and
road
wear
particles
(TRWPs)
are
generated
from
friction
between
tires
the
contain
polymer
tread
with
pavement
encrustations.
Single
particle
analysis
(SPA)
of
tire
source
contribution
in
environmental
samples
has
been
limited
by
interferences
common
spectroscopic
techniques.
This
study
extends
a
density
separation
chemical
mapping
protocol
for
simulator
TRWPs
toward
identification
characterization
individual
more
complex
dust,
road-dust-spiked
artificial
sediment,
tunnel
settling
pond
sediment
samples.
were
identified
combination
physical
(elongated/round
shape
variable
amounts
mineral
encrustation)
elemental
surface
characteristics
[co-localization
(S
+
Zn/Na)
±
(Si,
K,
Mg,
Ca,
Al)].
Organic
markers
(C7H7+),
overlapping
FTIR
spectra
reference
material,
resistance
to
heat-induced
deformation
selectively
used
confirm
identification.
The
TRWP
size
displayed
an
increasing
average
trend
54,
158,
267
μm
number
(94,
224,
506
volume)
respectively.
distributions
within
dust
10×
diluted
agreed
those
pure
dust.
Our
SPA
methodologies
determined
distribution
sample
types
complexity.
The Science of The Total Environment,
Год журнала:
2021,
Номер
809, С. 151151 - 151151
Опубликована: Окт. 21, 2021
Microplastic
pollution
of
stormwater
can
be
a
serious
threat
to
the
environment.
Gross
pollutant
trap
(GPT)
-
bioretention
treatment
trains
have
been
shown
previously
treat
(inter
alia)
particulate
pollutants
including
microplastic
particles
larger
than
100
μm.
This
study
was
carried
out
investigate
whether
such
also
remove
smaller
20
μm
sized
from
highway
runoff.
Further,
it
investigates
occurrence
and
concentration
in
runoff
which
polymer
types
they
assigned
to.
Volume
proportional
samples
nine
rain
events
were
taken
incoming
stormwater,
gross
effluent
outflow
system
as
well
non-vegetated
sand
filter.
The
analyses
using
μFTIR
FTIR-ATR,
made
possible
detect
where
carbon
black
present.
It
found
that
are
abundant
their
concentrations
highly
variable,
with
median
230
particles/L,
minimum
42
particles/L
maximum
8577
particles/L.
dominant
Polypropylene
(PP),
Ethylene
Propylene
Diene
(EPDM)
rubber
Ethylene-vinyl
acetate
(EVA).
train
treated
200
significantly
better
filter,
26.5
121
respectively.
GPT
had
no
significant
impact
on
particles.