Photocatalytic hydrogen production: an overview of new advances in structural tuning strategies

Journal of Materials Chemistry A, Год журнала: 2023, Номер 11(9), С. 4473 - 4486

Опубликована: Янв. 1, 2023

Newly emerged structural tuning strategies, i.e. , singe atom photocatalysts, defect control and S-scheme heterojunctions, display significant advancements for high performance photocatalytic hydrogen production toward the industrialization target.

Язык: Английский

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A review on development and modification strategies of MOFs Z-scheme heterojunction for photocatalytic wastewater treatment, water splitting, and DFT calculations

Heliyon, Год журнала: 2024, Номер 10(13), С. e32861 - e32861

Опубликована: Июнь 13, 2024

Increasing water pollution and decreasing energy reserves have emerged as growing concerns for the environment. These pollutions are due to dangerous effects of numerous pollutants on humans aquatic organisms, such hydrocarbons, biphenyls, pesticides, dyes, pharmaceuticals, metal ions. On other hand, need a clean environment, finding alternatives fossil renewable fuels is very important. Hydrogen (H2) regarded viable promising substitute fuels, range methodologies been devised generate this particular source energy. Metal-organic frameworks (MOFs) new generation nanoporous coordination polymers whose crystal structure composed juxtaposition organic inorganic constituent units. Due their flexible nature, regular structure, high surface area, these materials attracted much attention removing various from wastewater, splitting. MOFs Z-scheme heterojunctions identified an economical eco-friendly method eliminating wastewater systems, produce H2. Their low-cost synthesis unique properties increase application in environment fields. The possess diverse properties, exceptional making them ideal degradation separation. development formulation photocatalytic system using MOFs, which stable potent redox capability, has successful approach addressing environmental shortages recent times. Through utilization benefits offered by photocatalysts, efficient separation migration charge carriers, extensive spectrum light absorption, among advantages, notable enhancements can be attained. This review encompasses techniques, heterojunctions, use treating wastewaters, including heavy metals, Also, it provides overview mechanisms, pathways, theoretical practical aspects heterojunctions. Finally, thoroughly assesses existing challenges suggests further research applications industrial-scale treatment.

Язык: Английский

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Rational Design of Environmentally Friendly Carbon Nanotube Embedded Artificial Vesicle‐Structured Photocatalysts for Organic Pollutants Degradation

Advanced Functional Materials, Год журнала: 2024, Номер 34(16)

Опубликована: Янв. 2, 2024

Abstract Photocatalytic degradation is one of the most promising methods for addressing environmental issues without introducing pollution sources. Nonetheless, majority works are devoted to explore high‐efficiency semiconductor photocatalysts, but potential risks in their application usually neglected. In this work, an environmentally friendly vesicle‐structured photocatalyst rationally designed by employing magnetic layered double oxide‐hollow spheres@antimony tin oxide as a core, phospholipid membrane, and carbon nanotubes (CNTs) channels, yielding multi‐structural material with robust organic pollutants photocatalytic mineralization ability. Materials characterization, computational modeling, cytotoxicity tests suggest that under visible light irradiation, photogenerated charges can be rapidly generated transfer core composite, H 2 O effectively activated generate hydroxyl radical rapid degradation. The construction membranes embedded CNTs not only maintains photodegradation performance material, also restrains its risk. Such synthetic approach advances development bionic materials.

Язык: Английский

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CuO-ZnO nanocomposites-based thin films: Characterization, physical properties and sunlight photocatalytic degradation of organic pollutants

Journal of Alloys and Compounds, Год журнала: 2023, Номер 968, С. 172252 - 172252

Опубликована: Сен. 20, 2023

Язык: Английский

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Integrating BaFe2O4 nanoparticles onto N-doped Bi2WO6 microspheres for eminent visible light-driven photocatalytic performance towards aquaculture contaminants and pathogens

Colloids and Surfaces A Physicochemical and Engineering Aspects, Год журнала: 2024, Номер 692, С. 133905 - 133905

Опубликована: Апрель 4, 2024

Язык: Английский

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Synergistic photocatalytic degradation of crystal violet dye using novel medical waste-derived carbon/ZnO composite: A study on toxicological assessment

Process Safety and Environmental Protection, Год журнала: 2024, Номер 187, С. 145 - 158

Опубликована: Апрель 24, 2024

Язык: Английский

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Full carbon upcycling of organophosphorus wastewater enabled by interface photolysis

Chemical Engineering Journal, Год журнала: 2024, Номер 485, С. 149987 - 149987

Опубликована: Фев. 25, 2024

Язык: Английский

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A review on sustainable photocatalytic degradation of agro-organochlorine and organophosphorus water pollutants using biogenic iron and iron oxide-based nanoarchitecture materials

Desalination and Water Treatment, Год журнала: 2024, Номер 320, С. 100591 - 100591

Опубликована: Июль 11, 2024

Sustainable accessibility and adequate availability of healthy water are preconditions for living effective uninterrupted ecological networking. However, the presence organic pollutants like organochlorine (OC) organophosphorus (OP) compounds in environment has led to continuous shrinkage percentage clean available humanity's basic needs. Interestingly, green nanoparticles biosynthesized using biogenic entities have recently emerged as an appealing choice photocatalytic degradation a wide range owing their eco-benignness. Particularly, iron-based (BIBNPs) demonstrated unique properties such ease fabrication, excellent regenerability, strong redox potential, ability absorb visible light, produce highly reactive oxygen species that can enhance efficiency low aggregation which beneficial remediation contaminants. The BIBNPs maintain stability reactivity under various environmental conditions makes them promising solution cleanup efforts. This review aims critically report empirically juxtapose iron oxide NPs spectrum OC OP aquatic environments. work also generously elucidates potential eco-benign recyclable photocatalysts complete mineralization OP. study pragmatically expounded mechanism presented frontiers future research directions circular economy, financial analysis, artificial intelligence integration, hybrid technology. It was discovered most prevalent end products were CO2 H2O, least amount time needed just five minutes, plant extract widely used bio-reductant bio-fabrication BIBNPs. greatest found be 100 % is testament superior efficacy

Язык: Английский

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High-performance 0D-2D S-scheme CdS-Bi2WO6 heterostructure for bifunctional photoelectrochemical detection and degradation of chlorpyrifos under visible light irradiation

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 132295 - 132295

Опубликована: Март 1, 2025

Язык: Английский

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Novel g-C3N4 nanorods/Cu3BiS3 nanocomposites: Outstanding photocatalysts with p-n heterojunction for impressively detoxification of water under visible light

Journal of Photochemistry and Photobiology A Chemistry, Год журнала: 2023, Номер 443, С. 114862 - 114862

Опубликована: Май 20, 2023

Язык: Английский

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