With
the
purpose
of
providing
theoretical
guidance
to
assist
in
regulating
NOx
emissions,
a
thorough
understanding
catalytic
mechanism
NO2
adsorption
reduction
on
surface
carbon
material
under
impact
K
biochar
can
be
significance.
Through
density
functional
theory
(DFT)
calculations,
two
reaction
routes
including
various
zigzag
and
armchair
edge
models
are
identified,
indicating
changes
structure
intermediates
influence
presence.
Mayer
bond
order
analysis
wave
function
is
used
investigate
new
discovery
that
formation
process
pentagon–heptagon
reconstruction
at
edges
(zz-57
structure)
desorption
CO
from
seven-membered
ring
with
an
oxygen
atom.
According
calculation
results,
catalyzes
three
ways:
facilitating
disconnection
N–O
bond,
NO,
CO2
dissociation,
brings
about
decrease
highest
energy
barrier
for
path
char
by
48.04%
39.85%.
Thermodynamic
kinetic
indicates
addition
enhances
upper
limit
maximum
rate
path.
Journal of Environmental Management,
Год журнала:
2024,
Номер
365, С. 121400 - 121400
Опубликована: Июнь 26, 2024
Outdoor
exposure
to
particulate
matter
(PM2.5
and
PM10)
in
urban
areas
can
vary
considerably
depending
on
the
mode
of
transport.
This
study
aims
quantify
this
difference
during
daily
travel,
by
carrying
out
a
micro-sensor
measurement
campaign.
The
pollutant
was
assessed
simultaneously
over
predefined
routes
order
allow
comparison
between
different
transport
modes
having
same
starting
ending
points.
During
six-week
campaign,
average
reference
values
for
PM
background
concentrations
were
13.72
17.92μg/m3
PM2.5
PM10,
respectively.
results
revealed
that
with
highest
adjusted
concentration
(PM2.5Norm)
bus
(1.65)
followed
metro
(1.51),
walking
(1.33),
tramway
(1.31),
car
(1.09)
finally
bike
(1.06).
For
PM10Norm,
had
(1.86),
(1.68),
(1.65),
(1.61),
(1.43)
(1.39).
level
urbanization
around
route
presence
preferential
lanes
public
transportation
influenced
which
commuters
exposed.
active
(bike
walking),
we
observed
frequent
variations
trip,
characterized
punctual
peaks
concentration,
local
characteristics
road
traffic
morphology.
Fluctuations
inside
vehicles
partly
explained
opening
closing
doors
stops,
as
well
passenger
flows,
influencing
re-suspension
particles.
one
least
exposed
overall,
lowest
variability,
although
these
greatly
ventilation
parameters
used.
These
encourage
measures
move
most
users
away
from
traffic,
developing
network
entirely
dedicated
cycling
walking,
particularly
densely
populated
areas,
encouraging
renewal
motorized
use
less
polluting
fuels
efficient
systems.
Atmosphere,
Год журнала:
2024,
Номер
15(5), С. 589 - 589
Опубликована: Май 13, 2024
Assessing
indoor
environmental
quality
(IEQ)
is
fundamental
to
ensuring
health,
well-being,
and
safety.
A
particular
type
of
compartment,
land
transport
cabins
(LTCs),
specifically
those
trains
buses,
was
surveyed.
The
global
rise
in
commute
in-cabin
exposure
time
gives
relevance
the
current
study.
This
study
discusses
climate
(IC)
LTCs
emphasize
risk
well-being
comfort
exposed
occupants
linked
poor
IEQ,
using
objective
assessment
a
communication
method
following
recommendations
CEN-EN16798-1
standard.
measurement
campaign
carried
out
on
36
trips
real-time
travel
15
buses
21
trains,
mainly
EU
region.
Although
measured
operative
temperature,
relative
humidity,
CO2,
VOC
levels
followed
EN16798-1
requirements
most
cabins,
compliance
gaps
were
found
these
as
per
ventilation
requirements.
Also,
PMV-PPD
index
evaluated
two
velocity
ranges
0.1
0.3
m/s
showed
that
39%
56%
respectively,
thermally
inadequate.
parameters
air
(IAQ)
defective
83%
studied
LTCs.
Therefore,
exist
concerning
IC
LTCs,
suggesting
potential
risks
need
for
improved
with
IEQ
criteria
EN16798-1.
Environments,
Год журнала:
2024,
Номер
11(3), С. 50 - 50
Опубликована: Март 7, 2024
Outdoor
and
indoor
atmospheric
pollution
is
one
of
the
major
problems
that
humanity
continues
to
face.
As
a
mitigation
pathway,
numerous
technologies
have
been
developed
for
air
purification,
including
use
fibrous
filters.
In
this
study,
particle
capture
efficiencies
pressure
drops
filters
manufactured
with
cellulose
pulp
extracted
from
banana
pseudostems
were
studied
across
three
size
ranges
(PM10,
PM2.5,
PM1).
Two
pretreatments
applied,
alkaline
soda-antraquinone
(alkali-treated
pulp)
subsequent
bleaching
process
(bleached
pulp),
four
manufacturing
processes
tested:
crushing,
freeze-drying,
vacuum
filtration,
pressing.
addition,
study
varying
filter
grammage
(70,
100,
160
g·m−2)
pressing
pressures
(2,
4,
6,
8
t)
was
also
performed.
After
conducting
these
tests,
bleached
pulp,
having
g·m−2
pressed
at
4
t,
deemed
optimal
individual
solution.
It
demonstrated
high
retention
all
(with
values
exceeding
80%),
moderate
drop
below
1000
Pa,
thermal
stability
(degradation
above
220
°C).
However,
combining
freeze-drying
two-ton
yielded
improved
results
(83%
smallest
particles
89%
others)
approximately
half
drop.
Based
on
results,
stands
as
noteworthy
contribution
waste
valorization
advancement
environmentally
friendly
materials
This
achieved
through
adoption
simple
cost-effective
technology,
coupled
utilization
100%
natural
agricultural
primary
material.
Traffic‐related
air
pollutants
inside
vehicle
cabins
are
often
extremely
high
compared
to
background
pollution
concentrations.
The
study
of
the
determinants
these
concentrations
is
particularly
important
for
professional
drivers
and
commuters
who
spend
long
periods
in
vehicles.
This
aimed
at
identifying
quantifying
effect
several
exposure
on
carbon
monoxide
(CO),
equivalent
black
(eBC),
two
particulate
matter
(PM)
fractions
(PM
0.3–1
PM
1–2.5
),
ultrafine
particle
(UFP)
a
passenger
car
cabin.
novelty
this
work
consists
examining
effects
emissions
first
ahead
(henceforth
called
“leading
vehicle”)
pollutant
cabin
following
(i.e.,
that
was
equipped
with
monitoring
devices),
particular
emphasis
role
leading
characteristics
(e.g.,
emission
reduction
technologies).
real‐time
instrumentation
placed
petrol
car,
which
driven
by
same
operator
times
per
day
route
real
driving
conditions.
in‐cabin
ventilation
settings
were
set
as
follows:
windows
closed,
conditioning
recirculation
modes
off,
fanned
system
on.
measurements
conducted
over
total
10
weekdays
during
different
seasons
summer
autumn).
A
video
camera
fixed
windscreen
used
retrieve
information
about
traffic
conditions
through
careful
analysis.
associations
among
their
potential
evaluated
using
generalized
estimating
equation
univariate
multiple
models.
results
confirmed
significant
impact
well‐known
such
seasonality,
microclimatic
parameters,
jam
situations,
characteristics.
Moreover,
outcomes
shed
light
key
determinant
factors
cabins.
Indeed,
tested
conditions,
it
demonstrated
significantly
higher
vehicles
(from
+14.6%
+67.5%)
empty
road
even
though
introduction
newer
technologies
better
helped
mitigate
effect.
Additionally,
diesel‐fuelled
petrol‐fuelled
impactful
CO
(−7.2%)
eBC
(+45.3%)
An
(+30.4%)
in‐vehicle
found
heavy‐duty
light‐duty
Finally,
research
pointed
out
road‐scale
more
than
local
meteorological
Research Square (Research Square),
Год журнала:
2024,
Номер
unknown
Опубликована: Май 21, 2024
Abstract
As
a
part
of
their
occupation,
the
operators
heavy
earth
moving
machineries
(HEMM)
working
in
opencast
mines
are
exposed
to
several
air
pollutants,
prominent
one
being
airborne
particulate
matter.
The
paper
presents
findings
from
study
that
was
aimed
at
investigating
matter
exposure
(HEMM’s)
highly
mechanized
mines.
HEMMs
included
dumper,
shovel
and
drill.
mean
in-cabin
PM10
concentrations
dumper
shovel,
which
had
an
air-conditioning
system
cabin,
were
range
600–650
µg
m−
3.
Operators
inside
drill
cabin
did
not
have
conditioning
systems
as
high
1992
3
However,
cabins
effective
preventing
up
20%
by
comparison
persons
open
mine
atmosphere.
main
haul
road
contributed
~
50%
higher
than
internal
roads.
Coarse
particles
(PM10)
retained
upper
respiratory
tracts
while
fines
(PM2.5
PM1)
travel
via
tracheobronchial
region
reach
alveolar
region.
Occupational
HEMM
different
pollutants
is
present
very
limited
therefore
more
studies
need
be
conducted.