ACS Applied Materials & Interfaces,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 3, 2025
Strong
metal-support
interactions
(SMSIs)
are
essential
for
optimizing
the
performance
of
supported
metal
catalysts
by
tuning
metal-oxide
interface
structures.
This
study
explores
hydrogenation
CO
Applied Sciences,
Год журнала:
2025,
Номер
15(3), С. 1318 - 1318
Опубликована: Янв. 27, 2025
Layered
double
hydroxides
(LDH)
containing
various
exchangeable
anions
were
studied
to
show
how
X-ray
Photoelectron
Spectroscopy
(XPS)
can
provide
information
on
the
local
environments
of
different
elements
within
interlayer
anionic
groups
and
their
possible
influence
LDH
hydroxide
surfaces.
As
such,
XPS
potentially
additional
about
these
systems
that
cannot
be
obtained
by
other
common
spectroscopic
methods,
such
as
infrared
Raman
spectroscopy.
A
Mg6Al2X(OH)16.
4H2O
with
X
representing
CO32−,
PO43−,
SO42−,
MoO42−,
CrO43−,
Fe(CN)64−,
Fe(CN)63−
was
studied.
The
layer
structure
is
characterized
Mg
2p
Al
a
binding
energy
around
50.1
74.5
eV
for
normal
CO32−
LDH.
O
1s
contained
three
peaks
related
OH-groups
at
531.6
eV,
530.5
water
532.4
eV.
Similar
observations
made
showing
characteristic
P
2p,
S
Mo
3d
peaks.
Intercalation
CrO43−
shows
significant
amount
Cr6+
has
been
reduced
Cr3+.
Finally,
intercalation
hexacyanoferrate
in
hydrotalcite
showed
potential
detecting
changes
oxidation
state
Fe
upon
change
shift
possibility
determining
reduction
Fe(III)
Fe(II).
In
general,
high-resolution
scans
3d,
Cr
slightly
lower
energies
are
observed
compared
values
corresponding
part
rigid
crystal
structure,
minerals.
Overall,
nature
anion
(Mg,
Al,
O)
layered
minimal
considered
experimental
error
XPS.
detailed
analysis
data
combination
spectroscopy
not
readily
available
via
vibrational
simultaneously
account
both
surface
bulk
properties
through
methods.
Inorganics,
Год журнала:
2025,
Номер
13(2), С. 45 - 45
Опубликована: Фев. 6, 2025
MXenes,
a
groundbreaking
class
of
two-dimensional
(2D)
transition
metal
carbides,
nitrides,
and
carbonitrides,
have
emerged
as
highly
promising
materials
for
photocatalytic
applications
due
to
their
unique
structural,
electrical,
surface
properties.
These
are
synthesized
by
selectively
etching
the
A
layer
from
MAX
phases,
yielding
compositions
with
general
formula
Mn+1XnTx,
where
M
is
metal,
X
represents
carbon
or
nitrogen,
Tx
refers
terminations
such
–OH,
–O,
–F.
This
review
delves
into
advanced
synthesis
techniques
including
fluoride-free
molten
salt
methods,
explores
potential
in
photocatalysis
environmental
remediation.
MXenes
exhibit
remarkable
light
absorption
capabilities
efficient
charge
carrier
separation,
making
them
effective
degradation
organic
pollutants
under
visible
light.
Modulating
chemistry
bandgap
via
functional
group
modifications
further
enhances
performance.
attributes
position
next-generation
sustainable
applications,
offering
significant
addressing
global
challenges.