Effect of microplastic on sorption, toxicity, and mineralization of 2,4-dichlorophenoxyacetic acid ionic liquids DOI Creative Commons
Natalia Lisiecka, Marta Woźniak-Karczewska, Anna Parus

и другие.

Applied Microbiology and Biotechnology, Год журнала: 2024, Номер 108(1)

Опубликована: Ноя. 26, 2024

Abstract Recently, there has been significant focus on microplastics in the environment, especially regarding their role sorption–desorption processes of emerging contaminants, impacting pollutant migration between aquatic and terrestrial ecosystems. Notably, newest pollutants such environments are herbicide formulations known as ionic liquids (ILs), which integrate structure classic herbicidal anion with surface-active cations acting an adjuvant. In our study, we synthesized ILs by combining 2,4-D cetyltrimethylammonium [CTA] didecyldimethylammonium [DDA] cations. We investigated whether mixture salts, when exposed to polyethylene (PE) microplastics, differ properties. analyzed sorption defined PE particles, evaluated toxicity Pseudomonas putida KT2440 using trans/cis ratio unsaturated fatty acids, assessed biodegradability OECD 301F standard test. Results indicate IL anions behave distinct entities, questioning synthesis feasibility. Hydrophobic adjuvants were found adsorb onto microplastic surfaces (5–60% > [DDA]), posing potential threats xenobiotic accumulation. This highlights need explore microplastics’ sorbents hazardous agriculture, potentially competing humic acids affecting bioavailability. Consequently, xenobiotics may persist longer facilitated mobility Key points • Microplastics act sorbents, accumulating limiting biodegradation. Sorption surfactant reduces soil bacteria toxicity. Research confirms independent action ions from environment. Graphical abstract

Язык: Английский

Rethinking the Esterquats: Synthesis, Stability, Ecotoxicity and Applications of Esterquats Incorporating Analogs of Betaine or Choline as the Cation in Their Structure DOI Open Access
Marcin Wysocki, Witold Stachowiak, Mikołaj Smolibowski

и другие.

International Journal of Molecular Sciences, Год журнала: 2024, Номер 25(11), С. 5761 - 5761

Опубликована: Май 25, 2024

Esterquats constitute a unique group of quaternary ammonium salts (QASs) that contain an ester bond in the structure cation. Despite numerous advantages this class compounds, only two mini-reviews discuss subject esterquats: first one (2007) briefly summarizes their types, synthesis, and structural elements required for beneficial environmental profile covers applications whereas second reviews stability selected betaine-type esterquats aqueous solutions. The rationale writing review is to critically reevaluate relevant literature provide others with “state-of-the-art” snapshot choline-type esterquats. Hence, part survey thoroughly most important scientific reports demonstrating effective synthesis routes leading formation both types In section, susceptibility hydrolysis explained, influence various factors, such as pH, degree salinity, or temperature solution, was subjected thorough analysis includes quantitative components. next sections refer aspects associated ecotoxicity Consequently, biodegradation toxic effects on microorganisms are extensively analyzed crucial factors can affect commercialization. Then, reported discussed, including functionalization macromolecules, cotton fabric well successful utilization commercial scale. last section demonstrates essential conclusions drawbacks allow us elucidate future recommendations regarding development these promising chemicals.

Язык: Английский

Процитировано

4
Polymeric Herbicidal Ionic Liquids DOI Creative Commons
Juliusz Pernak, Michał Niemczak, Damian Krystian Kaczmarek

и другие.

ACS Agricultural Science & Technology, Год журнала: 2025, Номер unknown

Опубликована: Янв. 30, 2025

Процитировано

0
Cytochrome P450 Enzyme-Mediated Enantioselective Biotransformation of Chiral Fungicide Tebuconazole in Earthworm DOI

Jiqiang Fu,

Ziyang Diao,

Jiafu Wang

и другие.

Journal of Agricultural and Food Chemistry, Год журнала: 2025, Номер unknown

Опубликована: Март 17, 2025

Tebuconazole is widely used in agricultural practices, leading to elevated residue levels soils. However, its biotransformation and the ecotoxicological effects of corresponding transformation products (TPs) remain insufficiently explored. To fill this research gap, TPs tebuconazole an earthworm-soil system were identified by UHPLC-QTOF/MS combined with UHPLC-QLiT/MS. Six chiral tentatively identified, four detected both earthworms soil, while two found exclusively earthworm. Significant enantioselectivity was observed for five earthworms, involving cytochrome P450 enzyme-mediated hydroxylation dechlorination. In vitro metabolism experiments using earthworm microsomes revealed that CYP1A2, CYP2J2, CYP2E1 involved pathway tebuconazole. Molecular docking results confirmed S-(+)-tebuconazole produced more hydroxylated than R-(-)-tebuconazole due lower binding energy these enzymes. Predictions from ECOSAR model indicated most significant reducing toxicity These findings provide valuable insights into environmental fate risk assessment at enantiomeric level.

Язык: Английский

Процитировано

0
Enhancing Photostability of Prochloraz via Designing Natural Acid-Derived Prochloraz-Based Ionic Liquids DOI Creative Commons
Zhiqiang Gao, Fengmao Liu, Qingrong Peng

и другие.

Molecules, Год журнала: 2025, Номер 30(7), С. 1641 - 1641

Опубликована: Апрель 7, 2025

Converting pesticides into ionic liquids by designing counterions can modulate their physicochemical properties, thus improving efficacy and environmental safety. In this study, eight prochloraz-based (PILs) were synthesized using natural organic acids, toxicity, antifungal activity, in postharvest mango preservation evaluated. The results showed that the properties of propiconazole, including water solubility, logKow, surface light stability, could be adjusted selecting with varying structures. These correlated toxicity to zebrafish embryos activity against Colletotrichum gloeosporioides. Notably, except for benzoate PIL, photostability other seven PILs was enhanced under UV irradiation, cinnamate PIL exhibiting a half-life 2.28 times longer than prochloraz. Spectral analysis indicated anions influenced shielding or interacting cations. Furthermore, three selected improved pesticide deposition on during preservation, salicylate penetration fruit, potentially contributing its therapeutic activity. conclusion, liquid strategy offers an effective method modify improve photostability, reduce losses, optimize formulation.

Язык: Английский

Процитировано

0
Degradation of the novel herbicide tiafenacil in aqueous solution: Kinetics, various influencing factors, hydrolysis products identification, and toxicity assessment DOI
Yuqi Li, Jian Chen,

Wenjing Luo

и другие.

The Science of The Total Environment, Год журнала: 2024, Номер 952, С. 175937 - 175937

Опубликована: Авг. 30, 2024

Язык: Английский

Процитировано

3
Cocrystal engineering for sustained release of dicamba: Mitigating secondary drift and reducing leaching DOI

Chuanhua Wu,

Yuntian Xiao, Na Wang

и другие.

Journal of Controlled Release, Год журнала: 2024, Номер 375, С. 178 - 192

Опубликована: Сен. 10, 2024

Язык: Английский

Процитировано

2
Mono- and Dicationic Quaternary Ammonium Salts from Glycine Betaine: Are They Less Ecotoxic Than Currently Applied Commercial Cationic Surfactants? DOI
Witold Stachowiak, Adriana Olejniczak, Tomasz Rzemieniecki

и другие.

ACS Sustainable Chemistry & Engineering, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 28, 2024

Язык: Английский

Процитировано

2
Unraveling the Potential of Vitamin B3-Derived Salts with a Salicylate Anion as Dermal Active Agents for Acne Treatment DOI Creative Commons
Adriana Olejniczak, Witold Stachowiak, Daniel Ziental

и другие.

Molecular Pharmaceutics, Год журнала: 2024, Номер 21(9), С. 4634 - 4647

Опубликована: Авг. 14, 2024

This study is focused on the utilization of naturally occurring salicylic acid and nicotinamide (vitamin B

Язык: Английский

Процитировано

1
Ionic Liquid/Deep Eutectic Solvent-Mediated Calcining Synthesis of Cobalt-Based Electrocatalysts for Water Splitting DOI Creative Commons

Chenyun Zhang,

Jianjiao Jin,

Jiahao Wang

и другие.

Molecules, Год журнала: 2024, Номер 29(18), С. 4435 - 4435

Опубликована: Сен. 18, 2024

The recent advancements of ionic liquids (ILs) and deep eutectic solvents (DESs) in the synthesis cobalt-based catalysts for water splitting is reviewed. ILs DESs possess unique physical chemical properties, serving as solvents, templates, reagents. Combined with calcination techniques, their advantages can be fully leveraged, enhancing stability activity resulted catalysts. In these not only are they suitable simple one-step calcination, but also applicable to more complex multi-step reaction conditions. designability allows them participate reactants, providing metal heteroatoms, simplifying preparation system cobalt phosphide, sulfide, nitride. This work offers insights into design principles electrocatalysts practical guidance development efficient high-performance materials hydrogen production energy storage systems.

Язык: Английский

Процитировано

0
Effect of microplastic on sorption, toxicity, and mineralization of 2,4-dichlorophenoxyacetic acid ionic liquids DOI Creative Commons
Natalia Lisiecka, Marta Woźniak-Karczewska, Anna Parus

и другие.

Applied Microbiology and Biotechnology, Год журнала: 2024, Номер 108(1)

Опубликована: Ноя. 26, 2024

Abstract Recently, there has been significant focus on microplastics in the environment, especially regarding their role sorption–desorption processes of emerging contaminants, impacting pollutant migration between aquatic and terrestrial ecosystems. Notably, newest pollutants such environments are herbicide formulations known as ionic liquids (ILs), which integrate structure classic herbicidal anion with surface-active cations acting an adjuvant. In our study, we synthesized ILs by combining 2,4-D cetyltrimethylammonium [CTA] didecyldimethylammonium [DDA] cations. We investigated whether mixture salts, when exposed to polyethylene (PE) microplastics, differ properties. analyzed sorption defined PE particles, evaluated toxicity Pseudomonas putida KT2440 using trans/cis ratio unsaturated fatty acids, assessed biodegradability OECD 301F standard test. Results indicate IL anions behave distinct entities, questioning synthesis feasibility. Hydrophobic adjuvants were found adsorb onto microplastic surfaces (5–60% > [DDA]), posing potential threats xenobiotic accumulation. This highlights need explore microplastics’ sorbents hazardous agriculture, potentially competing humic acids affecting bioavailability. Consequently, xenobiotics may persist longer facilitated mobility Key points • Microplastics act sorbents, accumulating limiting biodegradation. Sorption surfactant reduces soil bacteria toxicity. Research confirms independent action ions from environment. Graphical abstract

Язык: Английский

Процитировано

0