Advanced Materials Interfaces,
Год журнала:
2024,
Номер
unknown
Опубликована: Окт. 21, 2024
Abstract
Over
90
million
tons
of
fabric
waste
are
generated
annually
by
the
apparel
industry
and
there
exists
an
urgent
need
to
develop
innovative
approaches
for
recycling
garments.
Reversible
adhesives
can
both
enable
automation
labor‐intensive
assembly
processes
facilitate
a
circular
economy.
Herein,
adhesive
formulation
based
on
thermoreversible
Diels–Alder
chemistry
has
been
developed
via
combination
furan‐functionalized
methacrylate
copolymer
(
F
)
with
bismaleimide
M
).
To
establish
fine
balance
between
adhesion
strength
reversible
bonding,
extensive
screening
optimal
composition
molar
mass
is
conducted.
Methyl,
2‐ethylhexyl,
lauryl
used
tune
T
g
copolymers,
whereas
H‐bonding
monomers
such
as
methacrylic
acid
2‐hydroxyethyl
utilized
strengthen
improve
its
interactions
cotton.
Following
optimization
composition,
molecular
weight,
crosslinker,
scaled‐up
studied
rheometry
successfully
dispensed
automated
platform.
The
adhered
fabrics
tested
required
shear
peel
then
separated
short
heat
treatment
followed
simple
solvent
wash
remove
residues.
Molecules,
Год журнала:
2024,
Номер
29(13), С. 3205 - 3205
Опубликована: Июль 5, 2024
This
review
is
dedicated
to
sustainable
practices
in
liquid
chromatography.
HPLC
and
UHPLC
methods
contribute
significantly
routine
analytical
techniques.
Therefore,
the
transfer
of
classical
chromatographic
into
ones
utmost
importance
moving
toward
development
goals.
Among
other
principles
render
a
method
green,
substitution
organic
solvent
component
mobile
phase
with
greener
one
received
great
attention.
concentrates
on
choosing
best
alternative
green
replace
for
easy,
rapid
more
normal
or
reversed-phase
The
main
focus
this
will
be
describing
non-green
white
an
effort
elevate
sustainability
chemistry.
greenness
properties
ranking,
addition
suitability
seventeen
solvents
chromatography,
are
mentioned
have
clear
insight
issue
rapidly
appropriate
one.
A
simple
guide
proposed
making
sustainable.
Chemical Communications,
Год журнала:
2024,
Номер
unknown
Опубликована: Ноя. 25, 2024
Recent
works
on
practical
and
recyclable
catalysts
for
the
cycloaddition
of
CO
2
to
epoxides
are
reviewed
with
an
eye
use
inexpensive,
readily-available,
non-toxic
materials
future
emerging
designs.
Journal of The Electrochemical Society,
Год журнала:
2024,
Номер
171(5), С. 057508 - 057508
Опубликована: Май 1, 2024
Green
and
sustainable
scientific
research
is
crucial
for
health
environmental
improvement.
Electrochemical
analysis
simplifies
complex
processes,
saving
time
cost.
Ion
selective
electrode
method,
a
key
in
green
analytical
chemistry,
was
utilized.
A
highly
solid
contact
sensor
developed
two
applications,
detecting
cinnarizine
(CIN)
dimenhydrinate
(DMH)
pharmaceuticals,
identifying
CIN
diphenhydramine
(DIP)
human
plasma.
Careful
selection
of
ionophores
ensured
accurate
detection.
Multi-wall
carbon-nanotubes
(MWCNTs)
facilitate
rapid
precise
measurement.
The
concentration
range
CIN,
DMH,
DIP
1
×
10
−6
M
to
−2
M,
with
mean
recovery%
100.07
±
0.80,
100.12
0.76,
0.53,
respectively.
Validation
parameters
exhibited
accuracy
precision,
results
100.87
0.89,
99.96
0.42,
99.82
0.31,
LODs
0.5
,
1.0
−7
0.2
DIP,
study
highlighted
benefits
like
speed,
economy,
sustainability,
emphasizing
the
electrode’s
reusability.
SWOT
assessments
further
underscored
its
advantages,
promising
applications
pharmaceutical
quality
control.
Journal of The Electrochemical Society,
Год журнала:
2024,
Номер
171(7), С. 077512 - 077512
Опубликована: Июль 1, 2024
This
study
presents
a
sustainable
electrochemical
investigation
of
pramipexole
(PRA)
in
pharmaceuticals
and
human
plasma,
using
cyclic
differential
pulse
voltammetry.
Key
parameters,
including
potential
range,
buffer
pH,
accumulation
period,
scan
rate
were
optimized,
establishing
efficient
voltammetric
methods
for
PRA
analysis.
The
analytical
range
was
0.60–12.00
μ
g
ml
−1
,
with
detection
limit
0.14
correlation
coefficient
0.9998.
Recovery
rates
ranged
from
98.60
±
0.26%
to
101.33
0.38%,
validating
the
methodology’s
applicability
plasma
an
average
recovery
99.25
0.45%.
highlights
environmental
sustainability
developed
electrode,
evaluated
through
SWOT
analysis,
assesses
greenness
impact
tools
like
Complementary
Green
Analytical
Procedure
Index
(ComplexGAPI),
(AGREE)
sample
preparation
(AGREEprep).
Significantly,
this
work
aligns
numerous
United
Nations
Sustainable
Development
Goals
(UN-SDGs),
specifically
goals
3,
4,
5,
7,
9,
11,
12,
13,
14,
15,
17,
illustrating
our
commitment
pharmaceutical
research.
method
further
quantified
newly
introduced
Need,
Quality,
Sustainability
(NQS)
index,
demonstrating
significant
alignment
practices.
Future Journal of Pharmaceutical Sciences,
Год журнала:
2024,
Номер
10(1)
Опубликована: Июнь 6, 2024
Abstract
Background
The
management
of
pain
presents
a
significant
challenge
in
healthcare,
particularly
cases
where
conventional
therapies
prove
inadequate.
In
response
to
this
need,
study
aims
devise
two
innovative
UV
spectrophotometric
techniques
rooted
the
principles
green
analytical
chemistry
for
analysis
Aceclofenac
(ACE),
Paracetamol
(PAR),
and
Tramadol
(TRM)
both
bulk
tablet
forms.
Results
Utilizing
advanced
mathematical
methodologies
such
as
double
divisor
ratio
spectra
method
area
under
curve,
concentrations
these
drugs
were
accurately
determined.
Validation
developed
methods
adhered
guidelines
outlined
by
International
Council
Harmonisation
Q2
(R1),
revealing
linear
calibration
curves
ACE
(8–12
µg/mL),
PAR
(22.75–35.75
TRM
(2.62–4.12
µg/mL).
Furthermore,
statistical
analyses
employing
Student’s
t
test
F
conducted
ensure
robustness
proposed
method.
evaluation
environmental
impact
through
metric
tools
confirmed
eco-friendliness
methodologies.
Conclusion
assessment
performed
utilizing
has
substantiated
sustainability
approach.
Thus,
methodology
offers
accurate
reliable
outcomes
determination
three
drugs,
indicated
complete
overlap
observed
zero-order
spectra.
ABSTRACT
The
proposed
study
uses
a
special
procedure
to
verify
that
an
analyte
assessment
operation
is
sustainable
and
environmentally
friendly.
When
the
targeted
molecule
(alogliptin
drug,
ALT)
lacks
chromophoric
or
fluorogenic
groups,
it
cannot
be
analyzed
without
marking
structural
amendment.
obeyed
phenomenon
(marking
process)
could
achieved
via
fluorescence
probing
using
tagging
agents.
An
innovative
reagent
pair
consisting
of
trioxosulfate
ion
o
‐Phthaldialdehyde
(OPD)
used
in
described
analytical
approach.
This
build
novel
fluorescent
nucleus
can
detected
developed
fluorimetric
ALT's
amino
moiety
condense
trioxosulfate/OPD.
presents
new,
facile,
green,
fluorometric
assay
ALT
drug.
product's
response
linear
at
50.00–800.00
ng
mL
−1
concentration
range
(LOD
=
15.74
LOQ
47.69
).
method
validation
was
considered
following
International
Council
for
Harmonisation
(ICH)
recommendations.
planned
probe
applied
crude
powder
dose
forms,
excipients
had
no
influence.
identified
as
white
by
WAC
(White
Analytical
Chemistry)
indications
Green/Red/Blue
(RGB
12)
pattern.
Additionally,
new
tools
(BAGI
GSST)
were
current
work.
