La
calidad
del
agua
superficial
es
un
tema
discutido
a
nivel
mundial,
principalmente
por
la
influencia
de
contaminantes
origen
antrópico,
como
resultado
esto,
diversas
entidades
gubernamentales,
ambientales,
universidades
y
organizaciones
dedicadas
conservación
medio
ambiente
se
han
dedicado
evaluar
los
efectos
e
impactos
generados
las
actividades
humanas.
El
río
Cesar
juega
papel
vital
en
el
departamento
ciudades
cercanas,
ya
que
son
áreas
clave
para
económicas
fundamentales
región,
sin
embargo,
estas
tenido
impacto
negativo
ecosistemas
esta
fuente
natural.
Por
lo
tanto,
objetivo
investigación
fue
determinar
cuenca
media
Índice
Calidad
Agua
desarrollado
IDEAM,
cual
tomaron
seis
estaciones
muestreo
analizaron
cinco
parámetros
(pH,
conductividad
eléctrica,
oxígeno
disuelto,
sólidos
suspendidos
Demanda
Química
Oxígeno),
encontrando
varia
una
regular
mala
largo
cuenca.
HydroResearch,
Год журнала:
2024,
Номер
7, С. 225 - 247
Опубликована: Янв. 1, 2024
The
inhabitant
of
Ilaporu
settlements
solely
depends
on
groundwater
for
domestic
and
agricultural
purpose
as
a
result
scarcity
contamination
surface
water.
present
study
therefore
aimed
at
investigating
the
physicochemical
geochemical
composition
suitability.
Hand-dug
well
waters
were
picked
randomly
from
thirty
(30)
major
with
aid
Global
Position
Satellite
(GPS).
physical
parameters
such
Hydrogen
ion
concentration
(pH),
Electrical
conductivity
(EC),)
Total
Dissolved
Solid
(TDS)
measured
in-situ
while
chemical
compositions
cations
(Ca2+,
K+,
Mg2+
Na+)
anions
(Cl−,F−,SO42−,NO3−and
CO32−)
obtained
through
laboratory
procedure.
water
was
subjected
to
an
analytical
measurement
utilizing
Atomic
Absorption
Spectrometer
(AAS)
examine
seven
heavy
metals
(Cd,
Pb,
Ni,
Fe,
Mn,
Co,
Zn).
This
conducted
various
pollution
indicators,
including
degree
(DoC),
modified
(mDoC),
enrichment
factor
(ER),
accumulation
index
(Igeo),
loading
(PLI),
ecological
risk
potential
(ERIP),
health
risks
related
carcinogenic
non-carcinogenic
substances.
Water
quality
indexes
permeability
(PI),
sodium
adsorption
ratio
(SAR),
soluble
percentage
(SSP),
(%Na),
residual
carbonate
bicarbonate
(RSC
RSBC),
Kelly's
(KR),
magnetic
(MR)
also
used
evaluate
suitability
irrigation.
revealed
that
has
no
trace
lead
(Pb)
other
are
within
acceptable
limit
WHO
NSDWQ,
except
cadmium.
(WQI)
range
between
1.11
23.76%.
implies
falls
in
excellent
categories
index,
thereby
making
it
suitable
both
PLI,
DoC
mDoC
contamination/pollution
PLI
<1,
<7
<1.5
all
analysed
samples.
little
or
contamination.
assessment
showed
samples
area
susceptible
Cd
Ni
increase
cancer
(carcinogenic).
irrigation
100%,
93.7%,
60%,
83.3%,
86.7%
90%,
PI,
SAR,
%Na,
MR,
RSC,
RSBC,
KR
SSP,
respectively.
It
is
recommended
should
be
carried
out
least
once
every
three
years
order
minimize
any
hazards,
contamination,
appropriateness
Heliyon,
Год журнала:
2024,
Номер
10(20), С. e39080 - e39080
Опубликована: Окт. 1, 2024
Highlights•The
adsorption
of
zinc
was
achieved
with
97.5%
efficiency
using
Ordu-Unye
bentonite.•Temkin
model
showed
the
highest
fit
for
process.•The
process
is
thermodynamically
spontaneous
and
endothermic.•The
ANN
method
used
in
modeling
prediction
zinc.ABSTRACTIn
this
study,
bentonite
as
an
adsorbent
removal
from
aqueous
solutions.
The
aim
experimental
part
study
to
ascertain
how
affected
by
variables
such
pH,
amount,
contact
time,
initial
concentration.
In
second
experiments,
modified
two
different
acids
performance
also
investigated.
Characterization
raw
bentonites
carried
out
FTIR
XRD.
It
observed
that
acid
modification
negatively
higher
(95%)
obtained
compared
(58.4%
HNO3
activated,
43.8%
H2SO4
activated).
Equilibrium
isotherms
were
modelled
explain
mechanism.
Adsorption
isotherm
studies
fits
well
Langmuir
(R2:
0.99)
Temkin
0.97)
models.
Besides
these
investigations,
various
artificial
neural
network
(ANN)
training
techniques
optimize
process.
By
trial
error,
optimal
changing
number
hidden
neurons
each
layer
architecture.
These
models
under
analyzed
determine
their
R2
mean
square
error
(MSE)
values,
outcomes
identified.
Among
ANN,
it
determined
Bayesian
Regularization
exhibited
optimum
architecture
(R2:0.995)
lowest
MSE
(MSE:0.0008)
ratio.Graphical
abstract
Water Science & Technology Water Supply,
Год журнала:
2024,
Номер
24(2), С. 601 - 614
Опубликована: Янв. 16, 2024
Abstract
Traditional
methods
for
water
quality
assessment
often
overlook
the
uncertainty
of
data
during
sample
collection
process,
leading
to
limitations
in
their
application.
Therefore,
this
study
combines
comprehensive
index
(CWQI)
method
and
improved
CWQI
based
on
CRITIC
with
Monte
Carlo
evaluate
Weishui
Reservoir
watershed.
The
results
indicate
that
(1)
there
is
a
noticeable
difference
between
Shaxiping
Dayanzui
sampling
points.
at
point
excellent,
classification
Class
I.
In
contrast,
comparatively
poorer,
an
average
III.
(2)
Sensitivity
analysis
shows
TN,
NH4+-N,
TP
are
more
sensitive
than
other
indicators,
suggesting
they
primary
factors
influencing
evaluation
results.
(3)
Compared
traditional
method,
combining
CRITIC-based
scientifically
rigorous.
It
considers
variety
allocates
weights
rationally,
provides
align
better
seasonal
variations,
resulting
higher
discriminative
power.
Sustainability,
Год журнала:
2023,
Номер
15(20), С. 14903 - 14903
Опубликована: Окт. 16, 2023
In
this
paper,
the
groundwater
environment
in
farmland
area
around
a
traditional
industrial
park
Shifang
City,
southwest
China,
was
taken
as
research
object.
Geostatistical
methods
with
GIS
technology
were
adopted
to
analyze
spatial
distribution
of
conventional
pollutants
and
heavy
metals
evaluate
potential
ecological
risks.
Chemical
oxygen
demand
(CODMn)
ammonia
nitrogen
(NH3-N)
distributions
showed
poor
continuity
apparent
differentiation,
which
primarily
attributed
intensive
anthropogenic
activities
(e.g.,
discharges).
The
total
relative
hardness
(TH),
SO42−,
Cl−
uniformly
affected
by
external
factors,
little
differentiation.
Concentrations
phosphorus
(TP),
TH,
followed
an
approximately
normal
distribution;
peak
values
detected
concentrations
appeared
frequency
range,
while
CODMn
NH3-N
did
not.
Groundwater
enrichment
for
various
metals,
mainly
Zn
Cu,
differentiation
Cr
consistent
interference.
correlation
coefficients
Cr–Cu
Cu–Pb
0.693
0.629
(p
<
0.01),
respectively,
indicating
similar
pollution
sources.
single-factor
index
Ni
>
Pb
Mn
Cu
Cr.
had
moderate
risk.
six
metals’
average
integrated
risk
(RI)
revealed
that
mild
accounted
96.2%
investigation
area.
Overall,
poses
shallow
surrounding
farmland.
IOP Conference Series Earth and Environmental Science,
Год журнала:
2023,
Номер
1263(1), С. 012033 - 012033
Опубликована: Ноя. 1, 2023
Abstract
Heavy
metal
contributed
in
bio-magnification
process.
So,
its
presence
needs
to
be
monitored
and
evaluated
prevent
control
hazards
human
health
sustainability
river
ecosystem.
One
of
that
heavy
is
lead.
This
study
aims
assessment
the
lead
pollution
Ciliwung
River
because
one
uses
as
water
resources
for
Regional
Drinking
Water
Company
(PDAM).
used
a
survey
analytical
method.
There
were
12
samples
column
10
sediments
distributed
from
upstream
beginning
downstream.
The
parameters
determined
site
checker
included
temperature,
pH,
Electrical
Conductivity
(EC),
Total
Dissolved
Solids
(TDS),
Oxygen
(DO),
Oxidation
Reduction
Potential
(ORP).
While
contained
sample
Automatic
Absorption
Spectrophotometric
(AAS).
result
showed
content
all
exceeded
quality
standards
on
sediment
more
than
column.
Lead
mostly
due
anthropogenic
sources
it
occurred
naturally
small
amounts.
Downstream,
EC,
TDS,
ORP
values
increase,
while
pH
DO
value
decreases.
at
sampling
points
positive.
It
means
deoxygenation
along
River.
implication
needed
additional
raw
processing
accompanied
further
economic
analysis
make
sure
availability
community
sustained.
Frontiers in Public Health,
Год журнала:
2023,
Номер
11
Опубликована: Дек. 15, 2023
The
River
Chief
System
(RCS),
a
pivotal
environmental
governance
policy
promoted
by
the
Chinese
government,
has
far-reaching
implications
for
public
health.
This
study
aims
to
comprehensively
assess
impact
of
RCS
on
corporate
pollution
emissions,
emphasizing
its
role
in
improving
quality
and
safeguarding
Utilizing
database
industrial
enterprises
data
from
heavily
polluting
spanning
2003
2013.
Manual
collation
implementation
across
prefecture-level
cities
during
same
period.
Application
DID
method
verify
extent
emissions.
significantly
reduces
emissions
enterprises.
Heterogeneity
analysis
reveals
be
more
effective
addressing
visible
pollutants
rivers,
non-provincial
capitals,
industries,
resulting
notable
reduction
Mechanism
testing
underscores
importance
increasing
government
attention
protection
strengthening
regulation
as
key
factors
contributing
RCS’s
success
reducing
Additionally,
finds
that
business
environment
enterprises,
measured
through
marketization
index,
enhances
effectiveness
river
introduces
new
perspective
examining
abatement
effects
RCS,
gap
micro-level
research.
findings
not
only
contribute
understanding
but
also
offer
valuable
insights
governments
policymakers
promoting
further
development
policies.
results
this
research
are
significant
By
effectively
controlling
contributes
positively
and,
consequently,
enhancing
health
outcomes.