Sustainability,
Год журнала:
2024,
Номер
16(23), С. 10761 - 10761
Опубликована: Дек. 8, 2024
The
presence
of
pharmaceuticals
in
aquatic
ecosystems
is
an
issue
increasing
concern.
Regardless
the
low
concentration
water,
they
can
have
a
toxic
effect
on
both
humans
and
organisms.
Advanced
oxidation
processes
(AOPs)
been
described
as
promising
technique
for
eliminating
due
to
their
high
efficiency.
However,
cost
associated
with
application
these
reagents
energy
requirements
affected
implementation
AOPs
at
large
scales.
Biochar
has
suggested
be
used
catalyst
overcome
limitations.
considered
alternative
heterogeneous
thanks
its
physicochemical
characteristics
like
specific
surface
area,
porous
structure,
oxygen-containing
functional
groups,
electrical
conductivity,
persistent
free
radicals
(PFRs),
modifiable
properties,
structure
defects.
This
carbonaceous
material
presents
capacity
activate
oxidizing
agents
leading
formation
radical
species,
which
are
needed
degrade
pharmaceuticals.
Additionally,
AOP/biochar
systems
destroy
pharmaceutical
molecules
following
non-radical
pathway.
To
enhance
biochar
catalytic
performance,
modifications
such
iron
(Fe)
impregnation,
heteroatom
doping,
supporting
semiconductors
surface.
Although
efficiently
combination
several
mineralization
from
further
research
must
conducted
evaluate
different
regeneration
techniques
increase
biochar’s
sustainable
applicability
reduce
operational
combined
process.
Moreover,
conditions
influencing
system
required
evaluated
discern
find
that
maximize
degradation
by
systems.
Materials,
Год журнала:
2025,
Номер
18(2), С. 439 - 439
Опубликована: Янв. 18, 2025
Nanoparticles
(NPs)
are
excellent
antibacterial
agents
due
to
their
ability
interact
with
microorganisms
at
the
cellular
level.
However,
antimicrobial
capacity
can
be
limited
by
tendency
agglomerate.
Functionalizing
NPs
suitable
ligands
improves
stability
and
dispersion
in
different
media
enhances
activity.
The
present
work
studied
functionalization
of
SiO2
using
sonochemical
method
Influence
organic
on
activity
(AA).
were
citric
acid
(CA)
monoethanolamine
(MEA).
X-ray
diffraction
(XRD)
photoelectron
spectroscopy
(XPS)
results
confirmed
amorphous
structure
functionalization.
Thermogravimetric
analysis
(TGA)
showed
that
MEA
(SiO2-MEA
NPs)
is
more
favored
compared
AC
(SiO2-CA
NPs),
ligand
content
was
34.42%
28.0%,
respectively.
Fourier-transform
infrared
(FTIR)
RAMAN
through
presence
carboxyl
amino
groups.
Scanning
electron
microscopy
(SEM),
transmission
(TEM),
zeta
potential
helped
improve
prevent
agglomeration.
Furthermore,
against
Staphylococcus
aureus
Escherichia
coli
provided
a
significant
improvement
(AA)
NPs,
where
SiO2-CA
highest
activity,
99.99%
inhibition
percentage
concentrations
200
ppm
both
E.
S.
strains.
AA
maintained
high
1200
ppm,
which
essential
applications
requiring
percentages
biocidal
such
as
marine
coatings.