Co-Ce Clay-Based Materials: Their Feasibility as Catalysts for Soot and CO Oxidation Reactions DOI Open Access

Natalia L. Courtalón,

Viviana G. Milt, M.L. Dieuzeide

и другие.

Catalysts, Год журнала: 2024, Номер 14(12), С. 882 - 882

Опубликована: Дек. 3, 2024

A series of Co-Ce clay-based catalysts were prepared via the wet impregnation method and tested for catalytic combustion diesel soot carbon monoxide. The objective this work was to find a suitable catalyst with an optimized active phase composition in order structure system using 3D-printing technique. physicochemical characterization indicated that support mainly composed kaolinite quartz. When supported on commercial clay, mixture oxides (Co3O4 spinel CeO2 fluorite) had higher activity than individual oxides. formation solid solution verified along synergistic effect between these two selected metal optimal molar Co:Ce = 90:10. corresponding showed highest combustion, 335 °C being temperature maximum rate. Also, it produced best CO oxidation. This formulation balanced proportion Co3+ Co2+ surface content Ce3+ species among prepared, which played key role oxidation reactions studied.

Язык: Английский

A Critical Review of Clay Mineral-Based Photocatalysts for Wastewater Treatment DOI Open Access

Yaozhong Qi,

Sikai Zhao, Yanbai Shen

и другие.

Catalysts, Год журнала: 2024, Номер 14(9), С. 575 - 575

Опубликована: Авг. 29, 2024

This review critically examines the latest advancements in clay mineral-based photocatalysts for water purification. Clay minerals, owing to their natural abundance, low cost, and unique physicochemical properties, have emerged as promising candidates enhancing photocatalytic efficiency. article delves into various activation methods including acid, alkali, calcination, mechanochemical activation, highlighting roles surface area, creating active sites, improving performance. Moreover, explores modification strategies photocatalysts, such doping with metal non-metal ions, deposition of metals, design heterojunctions, further boost activity. In particular, utilization kaolinite, montmorillonite, attapulgite, sepiolite mineral supports is discussed detail, showcasing potential wastewater treatment. The underscores significant strides made development effectiveness degrading organic contaminants under light exposure. Nevertheless, there are persisting challenges optimization loading quantities, improvement compatibility between minerals reduction preparation costs large-scale applications. summary, this offers valuable insights current status purification, thereby stimulating future research field.

Язык: Английский

Процитировано

6

Impact of Molecular Structure on Generation in D–A Heterojunction Photocatalysts for Efficient Dye Degradation under Weak Light DOI Open Access
Ciyuan Huang,

Linji Yang,

Nannan Geng

и другие.

Advanced Energy Materials, Год журнала: 2025, Номер unknown

Опубликована: Фев. 5, 2025

Abstract The dual challenges of photocatalysis technology in addressing wastewater pollution and the energy crisis demand advanced photocatalysts with enhanced visible light absorption efficient charge separation. This work utilizes bulk‐heterojunction organic solar cell (BHJ‐OSCs) active layers as photocatalytic sources, presenting PM6:PIID‐ClBF@BC, a biochar‐supported donor‐acceptor (D‐A) heterojunction photocatalyst, designed for water phototreatment clarify impacts molecular structure on activity, simultaneously assist associated OSCs waste disposal resource secondary expansion. PM6:PIID‐ClBF@BC achieves complete RhB degradation within 10 minutes maintains nearly 100% over 20 cycles. Additionally, it generated 28.15 µmol H₂ 3 hours, corresponding to rate 187.67 h⁻¹ g⁻¹. superior performance is attributed its broader visible‐light absorption, increased electronegativity (enhanced dipole moment) induced by chlorine substitution, favorable stacking interactions provide larger electron delocalization, forming strong internal electric field that drives separation intramolecular transfer thereby enhancing reactive oxygen species generation. Electrostatic between facilitate effective adsorption catalysis, higher superoxide radical levels driving degradation. highlights crucial role optimizing performance, offering insights designing next‐generation environmental remediation sustainable energy.

Язык: Английский

Процитировано

0

The ultra efficient magnetic recyclable photocatalyst CoFe2O4/TiO2 based on kaolinite for mineral processing wastewater treatment DOI Creative Commons
Sikai Zhao, Jie Wang, Ruixue Ma

и другие.

Environmental Functional Materials, Год журнала: 2025, Номер unknown

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0

Oxidation and detoxification of butyl xanthate form flotation wastewater by activated persulfate with vacuum ultraviolet: Performance evaluation, mechanism insight, and environmental application DOI
Chuang Wang, Chengzhi Luo, Jinying Du

и другие.

Journal of environmental chemical engineering, Год журнала: 2025, Номер unknown, С. 115841 - 115841

Опубликована: Фев. 1, 2025

Язык: Английский

Процитировано

0

Self-propelled MnO2@MnIn2S4@coal gangue micromotor as high-performance photo-Fenton catalyst for enhanced synergetic degradation of xanthate DOI
Jing Chu, Yanhua Wu,

Haijun Zhang

и другие.

Journal of environmental chemical engineering, Год журнала: 2024, Номер unknown, С. 114599 - 114599

Опубликована: Окт. 1, 2024

Язык: Английский

Процитировано

2

Adsorption-catalytic synergistic Fenton degradation of potassium butyl xanthate in flotation tailing wastewater by renewable iron-loaded sludge: Performance, kinetics and mechanism DOI

Jiping Tang,

Baolin Hou,

Li Zhi

и другие.

Separation and Purification Technology, Год журнала: 2024, Номер 359, С. 130533 - 130533

Опубликована: Ноя. 13, 2024

Язык: Английский

Процитировано

2

Synergizing photothermal and pyroelectric effects: Coal gangue assisted simultaneous ZnS/CuS for degradation of mineral processing wastewater DOI
Meng Li,

Weiji Sun,

Wangkai Hui

и другие.

Journal of Water Process Engineering, Год журнала: 2024, Номер 68, С. 106393 - 106393

Опубликована: Окт. 30, 2024

Язык: Английский

Процитировано

1

D/A heterojunction photocatalysts interspersed onto biochar to couple photocatalysis and adsorption for visible light-responsive efficient removal of pollutants DOI

Liwei Liang,

Songlin Cai, Lan Zhang

и другие.

Journal of Alloys and Compounds, Год журнала: 2024, Номер 1005, С. 176093 - 176093

Опубликована: Авг. 23, 2024

Язык: Английский

Процитировано

0

Co-Ce Clay-Based Materials: Their Feasibility as Catalysts for Soot and CO Oxidation Reactions DOI Open Access

Natalia L. Courtalón,

Viviana G. Milt, M.L. Dieuzeide

и другие.

Catalysts, Год журнала: 2024, Номер 14(12), С. 882 - 882

Опубликована: Дек. 3, 2024

A series of Co-Ce clay-based catalysts were prepared via the wet impregnation method and tested for catalytic combustion diesel soot carbon monoxide. The objective this work was to find a suitable catalyst with an optimized active phase composition in order structure system using 3D-printing technique. physicochemical characterization indicated that support mainly composed kaolinite quartz. When supported on commercial clay, mixture oxides (Co3O4 spinel CeO2 fluorite) had higher activity than individual oxides. formation solid solution verified along synergistic effect between these two selected metal optimal molar Co:Ce = 90:10. corresponding showed highest combustion, 335 °C being temperature maximum rate. Also, it produced best CO oxidation. This formulation balanced proportion Co3+ Co2+ surface content Ce3+ species among prepared, which played key role oxidation reactions studied.

Язык: Английский

Процитировано

0