Langmuir, Год журнала: 2024, Номер 40(45), С. 24131 - 24147
Опубликована: Окт. 31, 2024
The direct conversion of solar energy into clean fuels has emerged as an effective approach for future production and addressing environmental challenges. This research focuses on the synthesis BiOCl using a straightforward hydrothermal method with Ag modification achieved through green synthesis. These materials were applied to enhance photocatalytic processes hydrogen (H2) evolution. Comprehensive characterization synthesized photocatalysts was performed by techniques, such XRD, SEM, BET, XPS, UV–vis spectroscopy. Ag/BiOCl composite demonstrated impressive performance, achieving degradation rates 96% RhB, 87.7% TC, 85% HQ under 18 min irradiation. Additionally, high mineralization rate 92% observed Total Organic Carbon (TOC) analysis. Furthermore, exhibited significant H2 evolution 565 μmol g–1 h–1, which is nearly double that pure BiOCl. interaction between found generation O2– radicals, confirmed radical trapping experiments, underlying mechanism elucidated LC-HRMS. nanoparticles also excellent industrial waste, highlighting potential use in purification sterilization effluents.
Язык: Английский