ACS Applied Energy Materials, Год журнала: 2025, Номер unknown
Опубликована: Янв. 19, 2025
Hole selective layers (HSLs) play a crucial role in the efficiency of organic photovoltaics (OPVs). Self-assembled monolayers (SAMs) offer powerful approach to engineer interfacial properties HSLs OPVs. In this work, we utilized 2-(9H-carbazol-9-yl)ethyl)phosphonic acid (2PACz) SAM modify ITO/MoO3 interface and surface MoO3, thereby forming multilayer HSLs. 2PACz regulates work function (WF) electrodes, leading more favorable energy level alignment, reduced resistance, facilitated charge carrier transport extraction. The resulting OPV devices demonstrated improved fill factor (FF) power conversion (PCE). Additionally, reduction defects effectively suppressed recombination, ultimately achieving maximum PCE 16.33%. This indicates that design composite with modification is an effective strategy for improving provides ideas further advancing development.
Язык: Английский