
Proceedings of the National Academy of Sciences, Год журнала: 2022, Номер 119(18)
Опубликована: Апрель 29, 2022
SignificanceThe electroconversion of CO
Язык: Английский
Proceedings of the National Academy of Sciences, Год журнала: 2022, Номер 119(18)
Опубликована: Апрель 29, 2022
SignificanceThe electroconversion of CO
Язык: Английский
Advanced Functional Materials, Год журнала: 2023, Номер 34(6)
Опубликована: Окт. 29, 2023
Abstract Rational immobilization of fragile enzymes on a scaffold is an efficient protocol to achieve robust biocatalyst, yet the construction remains challenging due trade‐off between enzyme activity and framework environment. Herein, enzyme‐engineered assembly strategy enabling in situ fusion acetylcholinesterase (AChE) into Zn‐based metal‐organic frameworks (Zn‐MOF‐74) during rapid nucleation crystal defect growth process, demonstrated. The Zn‐MOF‐74 composites can offer hydrophilic microenvironment for maintaining biological state AChE, with flower‐like porous structure that allows boosting mass transfer process substrates products. Impressively, apparent AChE be well maintained 90% after encapsulation, AChE@Zn‐MOF‐74 produced excellent stability inhospitable environments. Given structural integration, AChE@Zn‐MOF‐74‐based biosensor constructed sensitive detection chlorpyrifos (organophosphorus pesticides) limit 1.0 ng mL −1 , monitoring pesticide degradation extent water body. This study anticipated valuable insight understanding structure‐activity relationship enzyme@MOF encourage applications biosensors precision agriculture.
Язык: Английский
Процитировано
20Green Chemistry, Год журнала: 2023, Номер 25(16), С. 6092 - 6107
Опубликована: Янв. 1, 2023
Stages of the penetration catalytic technology and necessity for fruitful collaboration.
Язык: Английский
Процитировано
19TrAC Trends in Analytical Chemistry, Год журнала: 2024, Номер 172, С. 117554 - 117554
Опубликована: Янв. 26, 2024
Язык: Английский
Процитировано
8Journal of Environmental Management, Год журнала: 2024, Номер 364, С. 121439 - 121439
Опубликована: Июнь 12, 2024
Язык: Английский
Процитировано
6Proceedings of the National Academy of Sciences, Год журнала: 2022, Номер 119(18)
Опубликована: Апрель 29, 2022
SignificanceThe electroconversion of CO
Язык: Английский
Процитировано
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