
Molecules, Год журнала: 2025, Номер 30(9), С. 1869 - 1869
Опубликована: Апрель 22, 2025
The development of sensitive and selective methods for detecting pesticide residues has become paramount ensuring food safety. In this work, a high-performance molecularly imprinted electrochemical sensor based on the composite Cu-BTC- FeCo-ZIF-derived N-doped carbon (FeCo@NC), synthesized by pyrolysis electrodeposition, was developed Benomyl (BN) detection. materials were characterized scanning electron microscopy (SEM), X-ray diffraction (XRD), photoelectron spectroscopy (XPS). sensing system, Cu-BTC/FeCo@NC used as electrode substrate displayed large specific surface area, high electronic conductivity, rich active catalytic sites, demonstrating excellent electrocatalytic ability toward BN oxidation. Meanwhile, Cu-BTC, with its abundant functional groups, facilitated strong hydrogen bonding interactions template molecule 3,4-ethylenedioxythiophene (EDOT), promoting formation uniform membrane material surface. introduced MIP-PEDOT could enhance recognition enrichment target BN, leading to an amplified detection signal. Thanks synergistic effects between MIP-PEDOT, proposed achieved low limit 1.67 nM. Furthermore, fabricated exhibited selectivity, reproducibility, interference resistance in BN. method been successfully applied determination vegetable fruit samples, indicating potential use practical applications.
Язык: Английский