Coordination-driven innovations in low-energy catalytic processes: Advancing sustainability in chemical production

Coordination Chemistry Reviews, Год журнала: 2024, Номер 514, С. 215900 - 215900

Опубликована: Май 8, 2024

Catalysis stands as a cornerstone in chemical synthesis, pivotal advancing sustainable manufacturing pathways. The evolution from energy-intensive to catalytic processes has marked transformative shift, notably exemplified by low-energy methods. These processes, operating under milder conditions and emphasizing selectivity recyclability, represent the forefront of chemistry. This review navigates through an array reactions, highlighting their diverse applications culminating exploration recent strides within processes. For example, explores uses such enzyme mimicking, biodiesel production, carbon dioxide capture, organic synthesis. Additionally, it covers enzymatic catalysis photocatalysis for transformations, energy applications, water treatment. Notably, emphasizes capabilities single-atom (SAC) diatomic catalysts (DACs), recognizing exceptional performance catalyzing reactions at minimal activation energies while maintaining high efficiency mild conditions. By elucidating modulation electronic structure offering microelectronic perspective, aims elucidate mechanisms underlying activity SAC DACs. Emphasizing interplay between coordination chemistry principles efficacy, elucidates indispensable role complexes fortifying sustainability these spotlighting fusion with catalysis, this underscore collective influence shaping landscape production.

Язык: Английский

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Effect of Ultrasound-Assisted Extraction (UAE) parameters on the recovery of polyphenols from pecan nutshell waste biomass and its antioxidant activity

Biomass Conversion and Biorefinery, Год журнала: 2024, Номер unknown

Опубликована: Июль 10, 2024

Язык: Английский

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Ultrasound technology assisted colloidal nanocrystal synthesis and biomedical applications

Ultrasonics Sonochemistry, Год журнала: 2024, Номер 103, С. 106798 - 106798

Опубликована: Фев. 1, 2024

Non-invasive and high spatiotemporal resolution mythologies for the diagnosis treatment of disease in clinical medicine promote development modern medicine. Ultrasound (US) technology provides a non-invasive, real-time, cost-effective imaging modality, which plays significant role chemical synthesis translation, especially vivo cancer therapy. On one hand, US is usually accompanied by cavitation, leading to temperature pressure, so-called "hot spot", playing sonochemical-based colloidal synthesis. Compared with classical nucleation synthetic method, sonochemical strategy presents efficiency fabrication nanocrystals due its fast growth procedure. other attractive medical treatment, applications increasing novel contrast agents, such as micro nano bubbles, are widely used neuromodulation, can breach blood–brain barrier temporarily safely, opening new door neuromodulation In terms sonodynamic therapy US-assisted synergetic show great effects against immunotherapy present unparalleled potentiality compared therapies. Further ultrasound revolutionize both translation improving efficiency, precision, accessibility while reducing environmental impact enhancing patient care. this paper, we review biological applications, next generation technology-assisted applications.

Язык: Английский

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A novel deep eutectic solvent-based ultrasound-assisted dispersive liquid–liquid microextraction coupled with high-performance liquid chromatography for the determination of quinolones in environmental water samples

Microchemical Journal, Год журнала: 2023, Номер 195, С. 109374 - 109374

Опубликована: Сен. 16, 2023

Язык: Английский

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New 4-(arylidene)amino-1,2,4-traizole-5-thiol derivatives and their acyclo thioglycosides as α-glucosidase and α-amylase inhibitors: Design, synthesis, and molecular modelling studies

Journal of Molecular Structure, Год журнала: 2022, Номер 1259, С. 132733 - 132733

Опубликована: Март 2, 2022

Язык: Английский

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Green and fast ultrasound-assisted extraction procedures for Fe, Mn, Mg and Ca analysis in cane syrups by FAAS

Journal of Food Composition and Analysis, Год журнала: 2023, Номер 123, С. 105495 - 105495

Опубликована: Июль 4, 2023

Язык: Английский

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Utilizing Herbal Dust: Ultrasound-Assisted Extraction of Green Tea, Hibiscus, and Lemon Balm Filter Tea Industry Waste

Processes, Год журнала: 2024, Номер 12(11), С. 2405 - 2405

Опубликована: Окт. 31, 2024

The rise of the global tea industry market, influenced by growing demands for healthier diet options, resulted in constant increase herbal production. In accordance, increased production leads to waste generation, especially area filter production, which generates form powdered plant material with particle sizes lower than 0.315 mm. generated amount this material, also called dust, can vary range from 10 40% total processed plant, and it is often considered only due its size. Therefore, within study, ultrasound-assisted extraction (UAE) was utilized green (Camellia sinensis L.), lemon balm (Melissa officinalis hibiscus (Hibiscus sabdariffa L.) quality obtained extracts evaluated terms phenolic content (TPC) profile. addition, UAE conducted on three different amplitudes (20, 60, 100%) two times (5 min) order investigate compare influence parameters. results showed that maximum TPC tea, hibiscus, dust 152.91 ± 0.74, 60.63 0.10, 356.22 3.13 mg GAE/g DE, respectively. HPLC analysis all confirmed presence several compounds, highest concentrations epigallocatechin gallate (EGCG) neochlorogenic acid extracts. recorded concentration rosmarinic conditions. reported study indicate previously waste, be successfully extracted application exhibit bioactive compounds comparable commercially available material.

Язык: Английский

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Unprecedented bi- and trinuclear palladium(II)-sodium complexes from a salophen-type Schiff base: Synthesis, characterization, thermal behavior, and in vitro biological activities

Journal of Molecular Structure, Год журнала: 2022, Номер 1272, С. 134224 - 134224

Опубликована: Сен. 27, 2022

Язык: Английский

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In-syringe ultrasound-assisted dispersive liquid–liquid microextraction for the fluorescent determination of aluminum in water and milk samples

Microchemical Journal, Год журнала: 2022, Номер 183, С. 108117 - 108117

Опубликована: Ноя. 1, 2022

Язык: Английский

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Harnessing ROS-Induced Oxidative Stress for Halting Colorectal Cancer via Thiazolidinedione-Based SOD Inhibitors

ACS Omega, Год журнала: 2022, Номер 7(24), С. 21267 - 21279

Опубликована: Июнь 7, 2022

Based on the "canonical" view of reactive oxygen species' (ROS) contribution to carcinogenesis, ROS induce oxidative stress and promote various tumor progression events. However, cells also need defend themselves against damage. This "heresy" was supported by several recent studies underlining role cellular antioxidant capacity in promoting metastasis resistance chemotherapy. Accordingly, harnessing ROS-induced via selective suppression cancer defense machinery has been launched as an innovative anticancer strategy. Within this approach, pharmacological inhibition superoxide dismutases (SODs), first-line enzymes for cells, selectively kills circumvents their acquired resistance. Various SOD inhibitors have introduced, which some were tolerated clinical trials. hit belong diverse chemical classes lack comprehensive structure-activity relationships (SAR). Herein, we probe potential newly synthesized benzylidene thiazolidinedione derivatives inhibit colorectal with special emphasis effects correlated aldehyde dehydrogenase 1 (ALDH1) glutathione peroxidase (GPx). may possibly bring a new dawn utilizing thiazolidinediones (TZDs) therapy through mechanisms. The preliminary 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay showed that all evaluated TZDs exhibited excellent safety profiles normal human recording EC100 up 47.5-folds higher than doxorubicin. Compounds 3c, 6a, 6e (IC50 = 4.4-4.7 μM) superior doxorubicin other Caco-2 within safe doses. agents inhibited 97.2-228.8 μM). Then, they selected further in-depth evaluation level. IC50 doses diminished activities (by 29.7, 70.1, 33.3%, respectively), ALDH1A 85.92, 95.84, 86.48%, GPX 50.17, 87.03, 53.28%, respectively) treated elevating content 21.42, 7.863, 8.986-folds, respectively. Docking simulations conducted display possible binding modes essential structural features. Also, physicochemical parameters pharmacokinetic formulating drug-likeness computed.

Язык: Английский

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