Environmental Science Water Research & Technology,
Год журнала:
2023,
Номер
9(10), С. 2429 - 2445
Опубликована: Янв. 1, 2023
This
work
reviews
transition
metal
catalysts
for
heterogeneous
electro-Fenton,
applied
as
suspended
catalyst
or
modified
cathode.
The
pollutant
degradation
performance
and
mechanism
H
2
O
generation
activation
to
active
species
are
discussed.
Journal of environmental chemical engineering,
Год журнала:
2023,
Номер
12(1), С. 111469 - 111469
Опубликована: Ноя. 10, 2023
In
this
work,
catalytic
activity
of
natural
chalcopyrite
(CuFeS2)
was
improved
by
thermal
activation.
The
modified
used
as
efficient
catalyst
for
degradation
organic
dye
Rhodamine
B
(RhB)
through
advanced
oxidation
process
(AOP).
Effects
dosage,
H2O2
concentration,
reaction
temperature,
solution
pH,
anions,
and
matter
on
the
efficiency
RhB
were
investigated.
This
study
revealed
that
activation
at
300°C
changed
chemical
valency
surface
elements
rather
than
transforming
major
phase
chalcopyrite.
Fenton-like
significantly
thermally
activated
could
be
obtained
under
broad
pH
showed
high
resistance
to
anions.
Under
optimal
conditions
43.0
mM,
0.75
g/L,
initial
4.0,
temperature
25°C,
reached
96.7%
50
min.
Based
rate
constant
kinetics,
energy
calculated
9
kJ/mol.
Radical
scavenging
experiments
electron
paramagnetic
resonance
(EPR)
technique
demonstrated
dominated
generated
hydroxyl
radicals
in
chalcopyrite/H2O2
system.
formation
sulfates
resulted
from
induced
dissolved
copper
or
iron
ions,
promoted
facilitated
reactive
radicals.
work
provides
an
in-depth
understanding
mechanism
behind
enhance
chalcopyrite,
offering
a
theoretical
basis
utilizing
minerals
treatment
wastewater
towards
cleaner
production.