Hydrogen‐Bonded Organic Frameworks Based on Endless‐Stacked Amides for Iodine Capture and Detection DOI Creative Commons
Bin Li, Weiguang Qiu, Glenn P. A. Yap

и другие.

Advanced Functional Materials, Год журнала: 2023, Номер 34(12)

Опубликована: Дек. 10, 2023

Abstract Recently, hydrogen‐bonded organic frameworks (HOFs) have emerged as a rapidly advancing class of porous materials with significant potential for applications in the absorption and detection various chemicals. Here, unique ability amide groups to form endless‐stacking H‐bonds is implemented design HOFs. Starting from benzene‐1,3,5‐tricarboxamide amide‐containing tribenzocyclynes foundational building blocks, diverse range HOFs featuring 1D, 2D, or 3D has been synthesized. Among those, all three HOFs, HOF_B‐Hex, HOF_T‐Pr HOF_T‐Hex exhibited permanent porosity, thereby demonstrating effectiveness amide‐based strategy. Notably, stands out 42% pore volume an impressive iodine capture efficiency 6.4 g −1 . The capacity influenced not only by but also presence accessible π‐electrons within material (i.e., electrons engaged π–π stacking interaction. Furthermore, some these fluorescent responses positioning them highly promising both sensing iodine.

Язык: Английский

Luminescent sensing platforms based on lanthanide metal-organic frameworks: Current strategies and perspectives DOI
Xinrui Wang, Yupeng Jiang, Antoine Tissot

и другие.

Coordination Chemistry Reviews, Год журнала: 2023, Номер 497, С. 215454 - 215454

Опубликована: Сен. 27, 2023

Язык: Английский

Процитировано

89

Immobilization of the Polar Group into an Ultramicroporous Metal–Organic Framework Enabling Benchmark Inverse Selective CO2/C2H2 Separation with Record C2H2 Production DOI

Shan‐Qing Yang,

Rajamani Krishna, Hongwei Chen

и другие.

Journal of the American Chemical Society, Год журнала: 2023, Номер 145(25), С. 13901 - 13911

Опубликована: Июнь 13, 2023

One-step harvest of high-purity light hydrocarbons without the desorption process represents an advanced and highly efficient strategy for purification target substances. The separation acetylene (C2H2) from carbon dioxide (CO2) by CO2-selective adsorbents are urgently demanded yet very challenging owing to their similar physicochemical properties. Here, we employ pore chemistry adjust environment immobilizing polar groups into ultramicroporous metal-organic framework (MOF), achieving one-step manufacture C2H2 CO2/C2H2 mixtures. Embedding methyl prototype stable MOF (Zn-ox-trz) not only changes but also improves discrimination guest molecules. methyl-functionalized Zn-ox-mtz thus exhibits benchmark reverse uptake ratio 12.6 (123.32/9.79 cm3 cm-3) exceptionally high equimolar selectivity 1064.9 at ambient conditions. Molecular simulations reveal that synergetic effect confinement surfaces decorated with provides recognition CO2 molecules through multiple van der Waals interactions. column breakthrough experiments suggest dramatically achieved capacity mixture a record productivity 2091 mmol kg-1, surpassing all reported so far. In addition, excellent chemical stability under different pH values aqueous solutions (pH = 1-12). Moreover, inverse selective performance showcase its promising application as splitter industrial manufacture. This work paves way developing reverse-selective gas process.

Язык: Английский

Процитировано

84

Recent progress of covalent organic frameworks membranes: Design, synthesis, and application in water treatment DOI Creative Commons
Xiaolu Liu, Yang Li, Zhongshan Chen

и другие.

Eco-Environment & Health, Год журнала: 2023, Номер 2(3), С. 117 - 130

Опубликована: Июль 13, 2023

To date, significant efforts have been devoted to eliminating hazardous components purify wastewater through the development of various nanomaterials. Covalent organic frameworks (COFs), an important branch porous crystalline family, possess peculiarity ultrahigh surface area, adjustable pore size, and facile functionality. Exciting studies from design fabrication potential applications in water treatment by COF-based membranes (COMs) emerged. This review summarizes preparation strategies synthesis mechanisms for COMs, including layer-by-layer stacking, situ growth, interfacial polymerization, electrochemical synthesis, briefly describes advanced characterization techniques COMs. Moreover, application COMs heavy metal removal, dye separation, purification radionuclides, pollutant detection, sea desalination, so on, is described discussed. Finally, perspectives on future opportunities designing proposed.

Язык: Английский

Процитировано

81

Hydrogen-bonded organic frameworks for membrane separation DOI
Cheng Chen, Liguo Shen, Hongjun Lin

и другие.

Chemical Society Reviews, Год журнала: 2024, Номер 53(5), С. 2738 - 2760

Опубликована: Янв. 1, 2024

This review provides a comprehensive overview of the fabrication strategies and applications hydrogen-bonded organic frameworks in membrane separation.

Язык: Английский

Процитировано

61

Flexible–robust MOFs/HOFs for challenging gas separations DOI
Abtin Ebadi Amooghin, Hamidreza Sanaeepur, Matineh Ghomi

и другие.

Coordination Chemistry Reviews, Год журнала: 2024, Номер 505, С. 215660 - 215660

Опубликована: Янв. 30, 2024

Язык: Английский

Процитировано

53

A Microporous Hydrogen Bonded Organic Framework for Highly Selective Separation of Carbon Dioxide over Acetylene DOI Open Access
Yunbin Li, Xue Wang, Hao Zhang

и другие.

Angewandte Chemie International Edition, Год журнала: 2023, Номер 62(39)

Опубликована: Авг. 11, 2023

The separation of acetylene (C2 H2 ) from carbon dioxide (CO2 is a very important but challenging task due to their similar molecular dimensions and physical properties. In terms porous adsorbents for this separation, the CO2 -selective materials are superior C2 ones because cost- energy-efficiency have been rarely achieved. Herein we report our unexpected discovery first hydrogen bonded organic framework (HOF) constructed simple linker 2,4,6-tri(1H-pyrazol-4-yl)pyridine (PYTPZ) (termed as HOF-FJU-88) highly material. HOF-FJU-88 two-dimensional HOFs with pore pocket about 7.6 Å. activated takes up high amount (59.6 cm3 g-1 at ambient conditions record IAST selectivity 1894. Its performance /C2 has further confirmed through breakthrough experiments, in situ diffuse reflectance infrared spectroscopy simulations.

Язык: Английский

Процитировано

46

Intriguing Room Temperature Phosphorescence in Crystalline Porous Organic Frameworks DOI Open Access
Yuqi Zhu, Xinghuo Wang, Ming‐Xue Wu

и другие.

Advanced Functional Materials, Год журнала: 2023, Номер 33(52)

Опубликована: Сен. 13, 2023

Abstract Organic room temperature phosphorescence (RTP) materials have become a hot topic in the field of luminescence wherein crystalline porous organic frameworks (metal–organic (MOFs), hydrogen‐bonded (HOFs), covalent (COFs))‐based RTP are receiving considerable attention. Beyond all doubt, frameworks‐based perfectly integrate advantages and materials. This review provides timely brief outline for development including construction strategy MOFs/HOFs/COFs‐based their performance as well potential applications. Moreover, conclusion outlook also discussed to present challenges prospects further high‐performance

Язык: Английский

Процитировано

44

Organic Frameworks Memristor: An Emerging Candidate for Data Storage, Artificial Synapse, and Neuromorphic Device DOI
Zheng Xu, Yixiang Li, Xia Yang

и другие.

Advanced Functional Materials, Год журнала: 2024, Номер 34(16)

Опубликована: Янв. 4, 2024

Abstract Memristors have recently become powerful competitors toward artificial synapses and neuromorphic computation, arising from their structural electrical similarity to biological neurons. From the diversity of materials, numerous organic inorganic materials proven exhibit great potential in application memristors. Herein, this work focuses on a class memristors based frameworks (OFs) pay attention most advanced experimental demonstrations. First, typical device structures memristive switching mechanisms are introduced. Second, latest progress OFs‐based is comprehensively summarized, including metal‐organic (MOFs), covalent (COFs), hydrogen‐bonded (HOFs), as well applications data storage, synapses, devices. Finally, future challenges prospects deeply discussed.

Язык: Английский

Процитировано

37

Stimulus-responsive hydrogen-bonded organic frameworks: Construction strategies, research progress and applications DOI
Wuji Wei, Lei He,

Guanrui Han

и другие.

Coordination Chemistry Reviews, Год журнала: 2024, Номер 507, С. 215760 - 215760

Опубликована: Март 5, 2024

Язык: Английский

Процитировано

32

Hydrogen-bonded organic frameworks in solution enables continuous and high-crystalline membranes DOI Creative Commons
Qi Yin,

Kuan Pang,

Ya‐Nan Feng

и другие.

Nature Communications, Год журнала: 2024, Номер 15(1)

Опубликована: Янв. 20, 2024

Язык: Английский

Процитировано

31