Chemical Science,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
Full-color
CPL
composite
films
prepared
using
helical
polymers,
fluorescein
and
substrates
have
excellent
mechanical
processing
properties.
They
exhibit
matrix
universality,
low
cost,
multi-stimulus
responsiveness
to
UV,
heat,
acid/base.
Nanoscale,
Год журнала:
2024,
Номер
16(30), С. 14269 - 14274
Опубликована: Янв. 1, 2024
The
precise
control
of
the
chirality
polymer
assemblies
is
a
challenge
faced
by
scientists
and
has
received
significant
attention
in
recent
years.
In
this
study,
we
employed
polymerization-induced
chiral
self-assembly
(PICSA)
method
to
create
side-chain
cyanobiphenyl
(CB)
block
copolymer
(BCP)
assemblies.
flexible
spacers
CB
monomers
were
regulated
exhibit
two
distinct
odd-even
effects
supramolecular
asymmetrical
arrangement
mesogens
inside
BCP
research
results
indicated
that
liquid
crystalline
properties
significantly
influence
magnitude
sign
their
chiroptical
properties.
These
findings
have
implications
for
design
with
designable
functions.
Advanced Functional Materials,
Год журнала:
2024,
Номер
unknown
Опубликована: Сен. 10, 2024
Abstract
Over
the
past
decade,
there
has
been
growing
research
interest
in
deriving
advanced
carbonaceous
materials
with
unique
architectures,
including
diverse
morphologies
and
compositions,
from
polymer‐based
precursors
tailored
nano/micro‐structures.
The
organic–organic
assembly
between
organic
molecules
block
copolymers
(BCPs)
emerged
as
a
promising
strategy
for
advancing
preformed
polymers
multiple
levels
of
complexity.
This
review
provides
comprehensive
overview
synthesis
potential
applications
nano/micro‐structures
derived
commonly
used
precursors,
phenol/formaldehyde,
dopamine,
biomass.
It
begins
brief
summary
polymerization
mechanism
each
type
precursors.
Following
this,
it
details
delicate
design
preparation
strategies
polymer
formation
mechanisms
first‐level
involving
BCPs
which
form
composite
micelles
building
units,
principles
manipulation
higher‐level
process
micelles,
illustrated
some
representative
examples.
then
highlights
these
heterogeneous
catalysts,
secondary
batteries,
separation,
intelligent
drug
delivery
systems.
Finally,
synthetic
challenges
development
directions
are
outlined,
underscoring
pathway
developing
materials.
Advanced
functional
polymeric
materials
can
possess
chemical
reactivity,
catalytic
properties,
photosensitivity,
electrical
conductivity,
biological
activity,
biocompatibility,
pharmacological
selective
separation,
and
energy
conversion
of
traditional
polymers.
Because
these
the
production
characterization
polymers
has
become
an
essential
part
modern
industry
advanced
technology.
Methacrylate
are
highly
versatile
owing
to
their
exceptional
properties
including
superior
optical
transparency,
excellent
light
transmission,
robust
thermal
stability.
This
study
investigates
a
class
methacrylate
coincorporating
coumarin
tyrosine
units,
aiming
explore
synergistic
effects
moieties
on
polymers'
optoelectronic
properties.
The
were
synthesized
characterized,
revealing
significant
alterations
in
electronic
structure
due
incorporation
coumarin-tyrosine
hybrids
into
backbone.
Optical
assessed
via
UV-vis
photoluminescence
spectroscopy,
demonstrating
solvent-dependent
red
shifts
intense
emission
peaks,
indicative
efficient
charge
transfer
between
coumarin.
results
highlight
potential
novel
for
applications
optoelectronics
offer
new
insights
synthesis,
functionalization,
performance.
In
this
study,
diode
observed
that
exhibited
effective
behavior
with
calculated
ideality
factors
(n)
2.68
2.78,
barrier
heights
(Φb)
0.45
0.46
eV,
respectively,
indicating
more
height
compared
previously
reported
studies.
work
contributes
expanding
knowledge
tunable
semiconducting
polymers,
paving
way
future
innovations
material
science.
Chemical Science,
Год журнала:
2025,
Номер
unknown
Опубликована: Янв. 1, 2025
Full-color
CPL
composite
films
prepared
using
helical
polymers,
fluorescein
and
substrates
have
excellent
mechanical
processing
properties.
They
exhibit
matrix
universality,
low
cost,
multi-stimulus
responsiveness
to
UV,
heat,
acid/base.