Chemical Communications,
Год журнала:
2024,
Номер
unknown
Опубликована: Янв. 1, 2024
Different
kinds
of
UiO-66-NH
2
with
different
aggregation
morphologies
were
prepared
to
prove
that
morphology
influences
photogenerated
charge
transfer,
and
hence
also
photocatalytic
efficiency.
Nanoscale,
Год журнала:
2024,
Номер
16(37), С. 17616 - 17623
Опубликована: Янв. 1, 2024
Due
to
the
high
charge
separation
efficiency
leading
photocatalytic
activity,
there
has
been
significant
interest
in
enhancing
ability
of
photocatalysts
by
controlling
heterojunction
structure.
Abstract
The
Ag
cluster–POM
assemblies
have
been
shown
to
possess
interesting
and
potentially
useful
properties.
However,
there
is
no
precedent
example
of
atomically
precise
showing
heterojunction
effects
in
photocatalysis.
Herein,
the
synthesis
total
structure
determination
periodically
distributed
molecular
[Ag
12
(SCy)
6
(CH
3
CN)
(PW
O
40
)]
n
(
‐
PW
)
are
reported.
assembly
Ag/W
clusters
into
3D
network
can
endow
resulting
binary
with
an
aesthetic
topology
unique
physicochemical
More
remarkably,
incorporation
cluster
efficiently
facilitate
separation
photogenerated
electrons
holes,
thus
significantly
promoting
catalytic
efficiency
selective
oxidation
sulfides.
be
recovered
reused
five
times
drastic
change
performance.
This
research
expected
assist
rational
design
cluster‐based
catalysts.
increase
activity
A
g
comparison
unassembled
attributed
synergistic
effect
clusters,
offering
splendid
opportunity
for
deciphering
structure–reactivity
relationship
heterostructure‐coupled
photosystem.
Chemical Communications,
Год журнала:
2024,
Номер
unknown
Опубликована: Янв. 1, 2024
Different
kinds
of
UiO-66-NH
2
with
different
aggregation
morphologies
were
prepared
to
prove
that
morphology
influences
photogenerated
charge
transfer,
and
hence
also
photocatalytic
efficiency.