Investigation of Metal-Organic Frameworks (MOFs): Synthesis, Properties, and Applications - An In-Depth Review

Chemical Physics Impact, Год журнала: 2025, Номер unknown, С. 100864 - 100864

Опубликована: Март 1, 2025

Язык: Английский

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Recent advances in flexible sensors: From sensing materials to detection modes

TrAC Trends in Analytical Chemistry, Год журнала: 2024, Номер unknown, С. 118027 - 118027

Опубликована: Окт. 1, 2024

Язык: Английский

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Physical Phenomena in Porous Frameworks

Accounts of Chemical Research, Год журнала: 2025, Номер 58(3), С. 327 - 329

Опубликована: Фев. 4, 2025

InfoMetricsFiguresRef. Accounts of Chemical ResearchVol 58/Issue 3Article This publication is free to access through this site. Learn More CiteCitationCitation and abstractCitation referencesMore citation options ShareShare onFacebookX (Twitter)WeChatLinkedInRedditEmailJump toExpandCollapse EditorialFebruary 4, 2025Physical Phenomena in Porous FrameworksClick copy article linkArticle link copied!Thomas Heine*Thomas HeineFaculty Chemistry Food Chemistry, TU Dresden, Bergstrasse 66c, 01069 GermanyHelmholtz-Zentrum Dresden-Rossendorf, Centrum for Advanced Systems Understanding, CASUS, Untermarkt 20, 02826 Görlitz, GermanyDepartment Yonsei University IBS center nanomedicine, Seodaemun-gu, Seoul 120-749, Republic Korea*Email: [email protected]More by Thomas Heinehttps://orcid.org/0000-0003-2379-6251Mircea DincaMircea DincaDepartment Massachusetts Institute Technology, Cambridge, 02139, United StatesMore Mircea Dincahttps://orcid.org/0000-0002-1262-1264Guangshan ZhouGuangshan ZhouKey Laboratory Polyoxometalate Reticular Material Ministry Education, School Northeast Normal University, Changchun 130024, ChinaMore Guangshan Zhouhttps://orcid.org/0000-0002-5794-3822Open PDFAccounts ResearchCite this: Acc. Chem. Res. 2025, 58, 3, 327–329Click citationCitation copied!https://pubs.acs.org/doi/10.1021/acs.accounts.4c00835https://doi.org/10.1021/acs.accounts.4c00835Published February 2025 Publication History Received 23 December 2024Published online 4 2025Published issue 2025editorialCopyright © Published American Society. available under these Terms Use. Request reuse permissionsThis licensed personal use The ACS PublicationsCopyright SocietySubjectswhat are subjectsArticle subjects automatically applied from the Subject Taxonomy describe scientific concepts themes article.Electrical conductivityMaterialsMetal organic frameworksQuantum mechanicsTwo dimensional materialsPorous materials characterized a high internal surface area significant pore volume. Natural examples, such as microporous zeolites, have been known humanity since ancient times, but their systematic investigation only started 1930s flourished with discovery synthetic zeolites critical role modern catalysis, molecular sieving, ion exchange. broader family framework compounds was later enriched development coordination networks (1,2) metal–organic frameworks (MOFs). (2) latter distinguished increased stability permanent porosity. (3,4) MOFs, along purely relatives, covalent (COFs) (5) porous aromatic (PAFs), (6) obtained reticular chemistry, "the chemistry linking building blocks strong bonds make crystalline open frameworks". (7) vast structural complexity results plethora crystal nets that materials. (8) Because structure significantly influences physical properties (e.g., see ref (9) tutorial review on two-dimensional systems), targeting particular topologies can be used rational design element new property-tailored materials.Traditional applications take advantage porosity, instance, gas storage, separation, catalysis. However, offer possibilities beyond these, which long-range order, topology, crystallographic nets, dimensionality extended structures. Indeed, range zero-dimensional cages one-dimensional chains or tubular networks, two- three-dimensional networks. Likewise, thought electronic, structurally exhibiting exotic one- electronic properties, instance. (10) Exotic, complex structures often prerequisite structures, Dirac Weyl points, van Hove singularities, flat bands, excite our fellow physicists. combination functionality order beneficial light harvesting optoelectronics. Concerted flexibility result flexible close upon external stimuli which, hence, change dynamically.This special focuses phenomena emerged recent years. A collection 18 experiment theory cover COFs, PAFs, ranging zero three dimensions, well polymer glasses. They feature mechanical flexibility, electrical conductivity, magnetism, methodological work synthesis, assembly, theoretical description. It contains fine examples where control enables superior performance chemistry-related applications, sensing photocatalysis.One core material conductivity. Most insulators semiconductors. Even if band gap narrow, conductivity hindered largely ionic metal–ligand act charge traps decrease mobility. Hopping transport likewise large distances across wide pores. Recent advances synthesis electrically conductive picture avenues applications. For example, smart route involving nonplanar linkers achieve conjugated 2D MOFs electric described Liu, Xing, Chen. (11) Jeong colleagues discuss strategies fabricate large-area MOF films. (12) Electrical controlled electron hopping achieved manipulating oxidation state metal nodes MOFs. Li Ott how factors redox-conductive frameworks. (13)Enhanced either in-plane conjugation COFs suitably embedded nodes, coupled active groups framework, chemiresistors enable selective sensing, discussed Benedetto Mirica. (14) Electric photocatalytic energy conservation. Fang et al. it via morphology also defects. Moreover, they tune Fermi level proper selection utilize donor–acceptor block pairs facilitate separation. (15) Beyond spin opens door utilization spintronics quantum To this, Lu, Samori, Feng highlight challenges experimental realization, large-scale decoupling out-of-plane manipulation dynamics. (16) Combination chemical sensitivity together local spins noses, qubits allowing specific recognition molecules spin–spin interactions, Yamauchi Yanai. (17)The lattice subject contributions. Chen Jiang emphasize impact transfer separation possibility fine-tune light-harvesting COF photocatalysis. (18) Creating thus establishing nanotubes, allows constrained 1D. (19) An intriguing property some them suffer changes stimuli. If carry lattice-dependent then change. Such responsive serve basis multiferroic (20)The processability structuring relatively hard polycrystalline materials, remains challenging. Two interesting approaches shown here: transformation glasses improves stability. (21) parallel approach overall crystallinity controlling orientation during growth using magnetic fields. (22)On side, Hardiagon summarize predict density-functional theory, machine learning, data-based preselection hierarchical refinement. (23)Framework made ingredients, turn give additional contributions issue. include metal–phosphonate frameworks, construction, properties. (24) capture CO2 molecule unit form stable As pointed out Kadota Horike, may reservoirs potentially even upgrading. (25) Wang, Su, Zuo tetrathiafulvalene (TTF) its analogues remarkable focus TTF-MOFs TTF-COFs, fuel cells, batteries, photo- electrocatalysts sensors crossover devices, among others. (26) entirely blocks, developed centers, introducing coupling reactions. Another novelty PAF research enhanced facilitated variants two different units. (27) Finally, built triangulenes explored means predictive theory. Functionalization diamagnetic tunable including effective carrier masses, gap, positions. exploited create photocatalysts operating without overpotentials. spin-carrying instead, surprisingly crystal, cases couplings, resulting Stoner ferromagnetism, predicted. (28)The compiled suggest will both potential nanotechnology technology. These opportunities twist motivating many more consider stem unique properties.Author InformationClick section linkSection copied!Corresponding AuthorThomas Heine, Faculty Germany; Helmholtz-Zentrum Department Korea, https://orcid.org/0000-0003-2379-6251, Email: protected]AuthorsMircea Dinca, States, https://orcid.org/0000-0002-1262-1264Guangshan Zhou, Key China, https://orcid.org/0000-0002-5794-3822NotesViews expressed editorial those authors not necessarily views ACS.ReferencesClick copied! references 28 other publications. 1Hoskins, B. F.; Robson, R. Design construction class scaffolding-like comprising infinite polymeric 3D-linked rods. reappraisal zinc cyanide cadmium diamond-related [N(CH3)4][CuIZnII(CN)4] CuI[4,4′,4″,4″″-tetracyanotetraphenylmethane]BF4.xC6H5NO2. J. Am. Soc. 1990, 112 (4), 1546– 1554, DOI: 10.1021/ja00160a038 Google Scholar1Design CuI[4,4',4'',4'''-tetracyanotetraphenylmethane]BF4.xC6H5NO2Hoskins, RichardJournal Society (1990), 1546-54CODEN: JACSAT; ISSN:0002-7863. proposed extensive afforded centers tetrahedral an octahedral array valences rodlike connecting Some simple general principles concerning presented reasons expecting show unusual useful simplest conceivable systems type isomorphous Zn(CN)2 Cd(CN)2 whose were reexamd. single-crystal x-ray diffraction, confirming earlier description based powder diffraction data 2 interpenetrating frameworks: cubic, space group P‾43m, Z = 2; 5.9002(9) Å (Zn(CN)2) 6.301(1) (Cd(CN)2); 1 surrounded tetrahedrally 4C 4N donors; MCNM rods linear; Zn-C 1.923(6), Zn-N 2.037(5), Cd-C 2.099(5), Cd-N 2.196(4), C-N 1.150(5) Zn(CN)2, 1.162(5) Cd(CN)2. interpenetration sep. demonstrated archetypal likely major concern future studies scaffolding [N(CH3)4][CuZn(CN)4] deliberately designed demonstrate one way preventing interpenetration; F‾43m, 11.609(3) Å; 4. single alternating Cu(I) Zn(II) linear very CuCNZn bond Cu-C 1.877(8) 2.069(15) Å, Z(CH3)4+ ions occupy half adamantane cavities generated remaining being vacant. CuI[4,4',4'',4'''-tetracyanotetraphenylmethane]BF4·xC6H5NO2 (x ≥ 7.7) represents first attempt generate 3-dimensional complexity. tetragonal, I‾4m2, 13.620(2) c 22.642(2) 2. cationic C·C6H4·CN·Cu length 8.856(2) Å. tetragonally elongated axis apparently nonbonded interactions between 8 ortho-H atoms around methane C centers. There no interpenetration. generates adamantane-like occupied disordered C6H5NO2 (at least 7.7 mols. per Cu) BF4- ions. crystals undergo ready anion approx. thirds vol. what undoubtedly effectively liq. provide confidence solids should prove accessible. >> SciFinder ®https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADyaK3cXovVOjtw%253D%253D&md5=2a9efabcd93072e8668a50199c51320c2Yaghi, O. M.; Sun, Z.; Richardson, D. A.; Groy, T. L. Directed Transformation Molecules Solids: Synthesis Microporous Sulfide Molecular Germanium Cages. 1994, 116 (2), 807– 808, 10.1021/ja00081a067 Scholar2Directed CagesYaghi, L.Journal (1994), 807-8CODEN: Ge4S104- mol. sulfide network, MnGe4S10·2(CH3)4N, at room temp. X-ray anal. starting Ge4S10[(CH3)4N]4 [cubic, 19.554(2), P43n, Z=8] revealed presence discrete anions, each contg. four germanium Ge linked doubly-bridging sulfides terminal sulfide. Addn. copolymn. Mn(II) formation solid, cryst. form. performed solid [tetragonal, 9.513(1), 14.281(2) I‾4, Z=2] showed present cage manganese channel system, channels tetramethylammonium cations. Pro. ®https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADyaK2cXhsFaisr0%253D&md5=ae60ea31c8068de18751d7f78ac1bfda3Yaghi, Li, G.; H. Selective binding removal guests framework. Nature 1995, 378 (6558), 703– 706, 10.1038/378703a0 Scholar3Selective metal-organic frameworkYaghi, Guangming; HailianNature (London) (1995), 703-6CODEN: NATUAS; ISSN:0028-0836. (Macmillan Magazines) inorg. find widespread application heterogeneous adsorption ion-exchange processes. rigidity allow shape- size-selective inclusion org. Analogous precise design, shape, size functionalization Here we report metal-org. bind arom. guest selectively. basic sym. mol., binds layers compd. compn. detd. selectively bound. We formed thermally up 350°C, after included mols., inclusions readsorbed. ®https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADyaK2MXhtVSnt7rP&md5=b0f48a6fa756cb3acc150b91b847516e4Li, H.; Eddaoudi, O'Keeffe, Yaghi, M. exceptionally highly 1999, 402 (6759), 276– 279, 10.1038/46248 Scholar4Design frameworkLi, Hailian; Mohamed; M.Nature (1999), 276-279CODEN: Open widely regarded promising sepn., storage recognition. Compared conventionally architecture So far, inability support porosity avoid collapsing absence solvents, has further progress field. Zn4O(BDC)3.(DMF)8.(PhCl) (named MOF-5, BDC 1,4-benzenedicarboxylate), cryst., evidenced analyses, when fully desolvated heated 300°. borrowing ideas carboxylate cluster chem., dicarboxylate linker reaction gives supertetrahedron clusters capped monocarboxylates. rigid divergent character added articulation into higher apparent than most zeolites. universal strategy currently pursued phases composites, gas-storage ®https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADyaK1MXnvFSiuro%253D&md5=68f27e20a7e4e15ea2c2f49a2a61e98a5Côté, A. P.; Benin, I.; Ockwig, N. W.; Matzger, J.; Porous, crystalline, Science (New York, N.Y.) 2005, 310 (5751), 1166– 1170, 10.1126/science.1120411 ScholarThere corresponding record reference.6Ben, T.; Ren, Ma, S.; Cao, D.; Lan, Jing, X.; Xu, Deng, Simmons, Qiu, Zhu, G. Targeted area. Angewandte Chemie (International ed. English) 2009, 48 (50), 9457– 9460, 10.1002/anie.200904637 reference.7Yaghi, Chemistry-Construction, Properties, Precision Reactions Frameworks. 2016, 138 (48), 15507– 15509, 10.1021/jacs.6b11821 Scholar7Reticular FrameworksYaghi, Omar M.Journal (2016), 15507-15509CODEN: (American Society) expanded reference. ®https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADC%252BC28XhvFOgtbnJ&md5=aeeb3573f65a2cb69bb61ed7bcf623038O'Keeffe, Peskov, Ramsden, S. Structure Resource (RCSR) database of, symbols for, nets. 2008, 41 (12), 1782– 1789, 10.1021/ar800124u Scholar8The netsO'Keeffe, Michael; Maxim Stuart M.Accounts Research (2008), 1782-1789CODEN: ACHRE4; ISSN:0001-4842. During past decade, interest grown tremendously constructed atoms. notable (MOFs), polyat. metal-contg. joined polytopic linkers. (Although sometimes referred polymers, prefer differentiate them, because linkages yield robust frameworks.) realization could synthesized led emergence discipline call chem.MOFs represented kind graph called periodic net. descriptions date back earliest crystallog. become much common recently thousands hundreds underlying reported. In diamond), vertices net, links (edges) connect them. case edges net.Because explosive area, need arisen system nomenclature, classification, identification, retrieval topol. identification interest, now use. Account, explain methodol. assigning (RCSR), about 1600 collected illustrated searched symbol, name, keywords, attributes. resource searchable polyhedra layers.The entries come enumerations chem. compds. both. case, refs. occurrences provided. crystallog., topol., attributes reported database. tool Assocd. net natural tiling, partition space-filling tiles. export analyze illustrate tilings. ®https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADC%252BD1cXht1SgsrjF&md5=392c624f403dd8457460a7649aa496f39Springer, T.-J.; Kuc, Topological polymers. Rev. 2020, 49 (7), 2007– 2019, 10.1039/C9CS00893D Scholar9Topological polymersSpringer, Maximilian Tsai-Jung; Agnieszka; ThomasChemical Reviews (2020), 2007-2019CODEN: CSRVBR; ISSN:0306-0012. (Royal Chemistry) review. 200 (2D) topologies. network defines structure. Including rise cones, bands insulators. Tutorial Review, calcd. tight-binding approach, 2nd-neighbor spin-orbit included. det. whether features signatures calcn. Chern nos., Z2 invariants, nanoribbon approach. suggestions realized explicit atomistic given substituted properly selected stitched π-conjugation retained. ®https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADC%252BB3cXlsVegtrY%253D&md5=bc4bd69f131da50fc781af3e8f97580b10Skorupskii, Le, K. N.; Cordova, Yang, L.; Chen, Hendon, C. Arguilla, Q.; Dincă, lanthanide metallic Proc. Natl. Acad. Sci. U.S.A. 2022, 119 (34), e2205127119 10.1073/pnas.2205127119 reference.11Liu, Conjugated Metal-Organic Frameworks: Defined Tailor-Made Functions. 2024, 57 1032– 1045, 10.1021/acs.accounts.3c00788 reference.12Jeong, Park, Jeon, Fabricating Large-Area Thin Films Conductive (16), 2336– 2346, 10.1021/acs.accounts.4c00292 reference.13Li, Ott, Redox-Conductive (19), 2836– 2846, 10.1021/acs.accounts.4c00430 reference.14Benedetto, Mirica, Framework Materials Chemiresistive Detection Differentiation Toxic Gases. 2775– 2789, 10.1021/a

Язык: Английский

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Effect of Mechanical Properties and Photoluminescence in Elastic Crystals Triggered by Substituent Regioisomerism

Crystal Growth & Design, Год журнала: 2025, Номер 25(5), С. 1448 - 1456

Опубликована: Фев. 13, 2025

Deformable organic photoluminescent crystals are a kind of fundamental material to exploit cutting-edge flexible optoelectronic devices. However, the realization that modulation mechanical and properties is difficult due structural properties, relationships for bendable molecular remain unclear, especially between packing, photoluminescence (PL). Herein, we report different supramolecular structures intermolecular π···π stacking via substituent regioisomerism effect (SRIE), based on three crystalline dicarbazol-9-yl-based pyrazine regioisomers para-, meta-, ortho-convergent substitutions (p-DCzP, m-DCzP, o-DCzP, respectively). We discover elasticity p-DCzP m-DCzP benefit from one-dimensional chains carbazole (Cz) units, while brittleness o-DCzP results multidirectional Cz units. Molecular dynamics (MD) simulations suggest energy beneficial reducing noncovalent interaction stabilizing aggregation structures. In addition, such in elastic can vanish aggregation-caused quenching maintain higher quantum yields blue emission dilute solutions crystals. This research reveals SRIE believe this work will provide new perspectives development functional crystal materials.

Язык: Английский

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Recent progress in metal-organic frameworks (Part II—material application)

Science China Chemistry, Год журнала: 2025, Номер 68(5), С. 1642 - 1702

Опубликована: Янв. 3, 2025

Язык: Английский

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Recent Advances in Transition Metal‐Based Metal‐Organic Frameworks for Hydrogen Production

Small Science, Год журнала: 2025, Номер unknown

Опубликована: Фев. 17, 2025

The escalating global energy demand and the imperative to mitigate carbon emissions have intensified pursuit for sustainable solutions, with hydrogen emerging as a pivotal clean carrier. Transition metal‐based metal‐organic frameworks (MOFs) garnered significant attention their potential in efficient production due high surface area, tunable porosity, versatile catalytic properties. Despite notable advancements MOF synthesis, critical challenges related stability, electrical conductivity, scalability continue hinder widespread application. This review provides comprehensive analysis of recent progress design synthesis transition MOFs, emphasizing role electrocatalytic photocatalytic production. Key synthetic strategies influence on performance are systematically discussed, alongside identification existing limitations knowledge gaps. By highlighting these areas proposing pathways future research, this aims accelerate practical integration MOFs into economy.

Язык: Английский

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Crystal structure of catena-poly[(μ ₃-4,4′-oxydibenzoato- κ ⁵ O,O ^′: O ^″,O ^‴:O ^‴)-bis(2,4,6-tri(3-pyridine)-1,3,5-triazine-κ ¹ N)cadmium(II)], C₅₀H₃₂CdN₁₂O₅

Zeitschrift für Kristallographie - New Crystal Structures, Год журнала: 2025, Номер unknown

Опубликована: Фев. 27, 2025

Abstract C 50 H 32 CdN 12 O 5 , triclinic, P 1 ‾ $P\overline{1}$ (no. 2), a = 9.0273(2) Å, b 15.4626(3) c 15.8910(2) α 96.5060(10) ° β 98.5010(10) γ 97.354(2) V 2155.88(7) Å 3 Z 2, R gt ( F ) 0.0320, w ref 2 0.0849, T 100 K.

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Interpretable machine learning on C3H6 and C3H8 diffusion in covalent organic frameworks: Incorporating the effects of framework flexibility

Chemical Engineering Science, Год журнала: 2025, Номер unknown, С. 121520 - 121520

Опубликована: Март 1, 2025

Язык: Английский

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Dynamic recognition aperture enables sieving of C3H5Cl/C3H7Cl mixtures in a robust-flexible metal–organic frameworks

Separation and Purification Technology, Год журнала: 2025, Номер unknown, С. 132491 - 132491

Опубликована: Март 1, 2025

Язык: Английский

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Controlled encapsulation of metal aggregates in metal–organic framework architectures

Inorganic Chemistry Communications, Год журнала: 2025, Номер unknown, С. 114383 - 114383

Опубликована: Март 1, 2025

Язык: Английский

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