Reversible regulation of room temperature phosphorescence and fluorescence in cucurbit[8]uril-mediated lanthanide MOFs

Chemical Engineering Journal, Год журнала: 2025, Номер unknown, С. 164465 - 164465

Опубликована: Июнь 1, 2025

Язык: Английский

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Error compensated MOF-based ReRAM array for encrypted logical operations

Dalton Transactions, Год журнала: 2024, Номер unknown

Опубликована: Янв. 1, 2024

Metal-organic frameworks (MOFs) form a unique platform for operation with data using ReRAM technology. Here we report on large-scale fabrication of MOF-based array 6 × cells, demonstrating 50% variation in their electronic parameters. Despite this inhomogeneity, such "non-ideal" is used recording binary information followed by deep learning processes to achieve 95% accuracy reading. Next, the same record numbers (from 0 15) addition. For correct performance an analogue algorithm, determine set coefficients each cell, allowing us use as encrypted key get access logical operations. The obtained results, thereby, demonstrate possibility low error reading coupled

Язык: Английский

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Implementing magnetic properties on demand with a dynamic Lanthanoid-Organic Framework

Chemical Science, Год журнала: 2024, Номер unknown

Опубликована: Дек. 26, 2024

We present the synthesis of a lanthanoid-organic framework (LOF) featuring dynamic structure that exhibits tunable magnetic properties. The LOF undergoes breathing and gate-opening phenomena in response to changes DMF content N2 sorption, leading emergence new crystal phases with distinct characteristics. Notably, desolvated form excels as single-ion magnet, while fully activated demonstrates impressive qubit properties, exhibiting Rabi oscillations up 60 K. Our work enables precise control over LOF's geometry, allowing us selectively tailor its behavior achieve either these two intriguing functionalities.

Язык: Английский

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Recent progress in metal-organic frameworks: part I—material preparation

Science China Chemistry, Год журнала: 2024, Номер unknown

Опубликована: Дек. 31, 2024

Язык: Английский

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Synthesis, crystal structure and fluorescent properties of a novel europium tetracarboxylate

Inorganic Chemistry Communications, Год журнала: 2024, Номер unknown, С. 113582 - 113582

Опубликована: Ноя. 1, 2024

Язык: Английский

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