Synthesis, structure, photoluminescence and magnetism of a series of cobalt‐lanthanide heterometallic complexes originated from 2,3‐dichlorobenzoate and 1,10‐phenanthroline DOI
Yue Shen,

Tian‐Biao Qu,

Fei‐Yue Chen

и другие.

Zeitschrift für anorganische und allgemeine Chemie, Год журнала: 2023, Номер unknown

Опубликована: Ноя. 21, 2023

Abstract A series of 3d–4f heterometallic complexes, namely [Ln 2 Co (2,3‐DCB) 10 (phen) ] [Ln=Nd ( 1 ), Sm Eu 3 Gd 4 Tb 5 Dy 6 Er 7 )], were obtained through the self‐assembly reactions Ln(NO ) ⋅ n H O, Co(NO 6H 2,3‐dichlorobenzoic acid (2,3‐HDCB), NaOH and 1,10‐phenanthroline under solvothermal conditions. Their crystal structures determined by single‐crystal X‐ray diffraction. They also characterized elemental analysis, FT‐IR, powder diffraction (PXRD) thermogravimetric analysis (TGA) differential thermoanalysis (DTA). These seven complexes have same molecular formula but different structures. Complexes – , as well are crystallographically isomorphous, respectively. all exhibit zero‐dimensional (0D) linear tetranuclear cluster 0D clusters can be further connected into a two‐dimensional (2D) supramolecular network via extensive intermolecular π–π interactions between 2,3‐DCB phen. The photoluminescent properties magnetic investigated. Complex shows slow relaxation behavior.

Язык: Английский

Photochromic crystalline hybrid materials with switchable properties: Recent advances and potential applications DOI

Jia-Li Zhao,

Meng-Hua Li, Yamin Cheng

и другие.

Coordination Chemistry Reviews, Год журнала: 2022, Номер 475, С. 214918 - 214918

Опубликована: Окт. 31, 2022

Язык: Английский

Процитировано

106
A Three-Component Donor–Acceptor Hybrid Framework with Low-Power X-ray-Induced Photochromism DOI
Yiwen Wang, Meng-Hua Li, Shuquan Zhang

и другие.

Inorganic Chemistry, Год журнала: 2022, Номер 61(21), С. 8153 - 8159

Опубликована: Май 17, 2022

Donor-acceptor (D-A) hybrid frameworks with visual X-ray photochromism at room temperature are fascinating because of their promising applications as detectors. Herein, a 3-fold interpenetrated D-A framework, [Eu(bcbp)1.5(DMF)(H2O)2][Co(CN)6]·4H2O·CH3OH (1), has been obtained by incorporating electron-rich Co(CN)63- into the electron-deficient europium viologen which interestingly exhibits ultraviolet and low-power dual remarkable color change from brown to green. Experimental theoretical studies revealed that photochromic behavior 1 could be attributed its structural feature increasing extent photoinduced electron transfer thus photogenerated radical species upon irradiation. Meanwhile, due introduction emissive lanthanide cations in system, photomodulated luminescence properties.

Язык: Английский

Процитировано

32
Viologen Guest-Mediated Luminescence Emission Tuning and Photochromic Behavior by a Series of Viologen@Zn-MOF Materials DOI
Haitao Han, Zheng Sun, Xia Zhao

и другие.

ACS Applied Materials & Interfaces, Год журнала: 2023, Номер 15(44), С. 51411 - 51420

Опубликована: Окт. 26, 2023

The encapsulation of various guest molecules into the pores metal-organic frameworks (MOFs) to form hybrid materials has attracted significant attention due their unique spatial distribution and certain preferential geometry guests inside MOFs. This arrangement often results in exhibiting physical chemical properties intramolecular interactions with host. In this article, five viologen derivatives were introduced as a Zn-MOF different benzene ring lengths, resulting formation host-guest three-dimensional (3D) compounds exhibited guest-dependent emission wavelength, color, excellent photochromic behavior upon ultraviolet (UV) light radiation distinct electronic transfer π···π stacking between host framework. study provides strategy for designing color-tunable luminescent highly sensitive materials.

Язык: Английский

Процитировано

16
Synthesis, crystal structures, photochromism and selective luminescence sensing property of Zn/Cd-viologen coordination polymers DOI
Ying Gao, Xinyue Ma, Yuanyuan Li

и другие.

Inorganica Chimica Acta, Год журнала: 2024, Номер 568, С. 122074 - 122074

Опубликована: Апрель 19, 2024

Язык: Английский

Процитировано

3
A novel multichromic Cd(I) metal–organic framework based on a crystalline viologen ligand exhibiting photoluminescence property and organic amines detection capability in solid state DOI

Jiayun Zou,

Xiangju Meng, Runwei Wang

и другие.

Inorganic Chemistry Communications, Год журнала: 2025, Номер 174, С. 113983 - 113983

Опубликована: Янв. 22, 2025

Язык: Английский

Процитировано

0
Metal–organic framework radiochromic materials: Recent advances and applications DOI

Qingsong Wei,

Yi‐Ming Di,

Ming‐Hua You

и другие.

Coordination Chemistry Reviews, Год журнала: 2025, Номер 534, С. 216616 - 216616

Опубликована: Март 15, 2025

Язык: Английский

Процитировано

0
Chromotropism of Iron(II) Complexes with Non-Symmetric Heterocyclic Ligands: Polarity Sensing in Aqueous Urea Solutions DOI Creative Commons
Raffaello Papadakis

Nanomaterials, Год журнала: 2025, Номер 15(8), С. 598 - 598

Опубликована: Апрель 13, 2025

This study reports the synthesis and characterization of two solvatochromic pentacyanoferrate(II) complexes. Their structural design incorporates ligands with flexible xylylene bridges distinct heterocycles—one combining 4-dimethylaminopyridine (DMAP) 4,4′-bipyridine, other isoquinoline 4,4′-bipyridine. diversity enables complexes to engage in a broad range solvent–solute interactions, providing valuable insights into behavior solvents media regard polarity, through sizable shifts. solvatochromism is examined using set nine solvent mixtures. The sensitivities polarity changes, expressed variety parameters functions, are determined. Moreover, four complementary linear solvation energy relationships (LSERs), roles solute–solvent interactions molecular responsiveness compounds different investigated. Additionally, their dipole moments ground MLCT-excited states determined suitable model, namely that Suppan Tsiamis. As step further, sensing aptitude aqueous urea solutions at varying concentrations. sensitivity compared model cyanoferrate(II) complex, FeII(CN)2(phen)2. clearly surpass FeII(CN)2(phen)2 subtle changes induced by concentration. An LSER describing predicting effects developed tested.

Язык: Английский

Процитировано

0
Photochromic and photocontrolled luminescent rare-earth D–A hybrid crystals based on rigid viologen acceptors DOI
Yiwen Wang, Meng-Hua Li, Shu‐Quan Zhang

и другие.

CrystEngComm, Год журнала: 2021, Номер 23(36), С. 6267 - 6275

Опубликована: Янв. 1, 2021

Due to the introduction of a strong electron donor, Co III (CN) 6 3− , into structure, rare-earth donor–acceptor (D–A) hybrid crystal shows enhanced photochromism. The coordinative Eu 3+ cation is also beneficial toward improving luminescence.

Язык: Английский

Процитировано

20
A Zn (II)-viologen MOF material: Photochromic, photoswitchable luminescent properties and UV sensing DOI
Chunyan Chen,

Jifa Liu,

Sun Zheng

и другие.

Journal of Molecular Structure, Год журнала: 2023, Номер 1283, С. 135297 - 135297

Опубликована: Март 5, 2023

Язык: Английский

Процитировано

6
Anion-Dependent Structure and Luminescence Diversity in ZnII-LnIII Heterometallic Architectures Supported by a Salicylamide-Imine Ligand DOI

Fu-Qiang Song,

Hao Cheng, Nana Zhao

и другие.

Inorganic Chemistry, Год журнала: 2021, Номер 60(22), С. 17051 - 17062

Опубликована: Окт. 25, 2021

To advance the structural development and fully explore application potential, it is highly desirable but challenging to elucidate relationship between structures properties of ZnII-LnIII heterometallic species. Herein, three types compounds (LnIII = GdIII, TbIII) formulated as [Zn16Ln4L12(μ3-O)4(NO3)12]·8CH3CN (ZnLn-1), [Zn2Ln2L2(NO3)6(H2O)2]·3CH3CN (ZnLn-2), [Zn4Ln2L8(OAc)12]·xCH3CN (ZnLn-3: for Ln Gd, x 5; Tb, 4) were dictated by common inorganic anions, NO3- OAc-, with aid multidentate ligand H2L propane central skeleton 3-methoxysalicylamide 3-methoxysalicylaldimine terminal groups. ZnLn-1 features cubic cages four {Zn4L3} tetrahedral subunits Ln3+ centers positioned at eight vertices alternately when was introduced into reaction system exclusively. An attempt replace in OAc- partially led formation {Zn2Ln2L2} wheels. Meanwhile, ZnLn-3 featuring double-hairpin-like {Zn4Ln2L4} hemicycles that are orthogonal each other assisted intermolecular hydrogen bonds constructed completely replaced OAc-. Their integrity solution ascertained both emission 1H NMR spectroscopy. Ascribed different Zn2+-containing antenna, ZnTb-2 possesses a relatively strong characteristic Tb3+; ZnTb-1 has moderate Tb3+ luminescence, yet an absence found ZnTb-3. Such difference could be mainly attributed antenna effect directed distinct characteristics induced anions. The anion-dictated self-assembly strategy presented herein not only offers facile approach regulate coordination mode such extent obtain diverse species also provides understanding how anions tune coordination-driven self-assemblies well subsequent luminescence properties.

Язык: Английский

Процитировано

9