Synthesis of energetic coordination compounds based on pyrazole and 4-chloropyrazole via co-melting crystallization method DOI
Zujia Lu, Tingwei Wang,

Mou Sun

и другие.

CrystEngComm, Год журнала: 2024, Номер 26(8), С. 1178 - 1188

Опубликована: Янв. 1, 2024

Using pyrazole, 4-chloropyrazole, Cu(NO 3 ) 2 , and Cu(ClO 4 as raw materials, the target crystals of ECCs can be directly obtained by co-melting heating, offering a more efficient alternative to traditional solvent-based preparation methods.

Язык: Английский

Comparative study of two copper perchlorate hydrazide complexes: impact of coordination chemistry on laser sensitivity and energetic properties DOI
Bin-shan Zhao, Chao Zhang, Zujia Lu

и другие.

CrystEngComm, Год журнала: 2025, Номер unknown

Опубликована: Янв. 1, 2025

By modulating the coordination chemistry through varying reaction conditions, two novel energetic complex compounds, ECCs-1 and ECCs-2, exhibited different structures, thermal stabilities, mechanical sensitivities, laser ignition performances.

Язык: Английский

Процитировано

0
Assembly of 1D Helical Energetic Coordination Polymers Using a Flexible Bridged Furazan-triazole Cation DOI

Man Xu,

Ping Yin, Siping Pang

и другие.

The Journal of Organic Chemistry, Год журнала: 2024, Номер 89(2), С. 986 - 993

Опубликована: Янв. 9, 2024

Two new energetic coordination compounds with 1D helical chain structures have been synthesized. First, the polyamine precursor 4,5-diamino-2-((4-amino-1,2,5-oxadiazole-3-yl)methyl)-2,4-dihydro-3

Язык: Английский

Процитировано

2
Preparation of Primary Explosive by Self-assembly of Combustible and Oxidizing Agents under Acid DOI
Tingwei Wang, Zhi-ming Xie, Zujia Lu

и другие.

Inorganic Chemistry, Год журнала: 2023, Номер 62(24), С. 9695 - 9701

Опубликована: Июнь 8, 2023

In order to further explore the effect of ligands on performance primary explosives and gain a deeper understanding coordination mechanism, we designed furan-2-carbohydrazide (FRCA), ligand, by using oxygen-containing heterocycles carbohydrazide. Then, FRCA Cu(ClO4)2 were used synthesize compounds [Cu(FRCA)2(H2O)(ClO4)2]·CH3OH (ECCs-1·CH3OH) Cu(FRCA)2(H2O)(ClO4)2 (ECCs-1). The structure ECCs-1 was confirmed single-crystal X-ray diffraction, IR EA characterization. Further experiments show that has good thermal stability, but is sensitive mechanical stimuli (impact sensitivity = IS 8 J, friction FS 20 N). predicted value detonation parameter DEXPLO 5 6.6 km s–1, PEXPLO 18.8 GPa, ignition test, laser lead plate experiment excellent performance, which very worthy attention.

Язык: Английский

Процитировано

4
High-Energetic Salts and Metal Complexes: Comprehensive Overview with a Focus on Use in Homemade Explosives (HME) DOI Creative Commons
Błażej Gierczyk, Maciej Zalas, Tomasz Otłowski

и другие.

Molecules, Год журнала: 2024, Номер 29(23), С. 5588 - 5588

Опубликована: Ноя. 26, 2024

Metal-containing compounds form a large and rapidly expanding group of high-energy materials. Many in this class attract the attention non-professionals, who may attempt illegal production explosives. Several these substances have been commercially available pose significant danger if used by terrorists or for criminal purposes. Others are experimental compounds, kinds curiosities, often created pyrotechnics enthusiasts, which can present serious risks to both creators their immediate surroundings. The internet hosts vast amount information, including recipes discussions on forums, private websites, social media, more. This paper aims review variety metal-containing explosives discuss appeal potential accessibility unauthorized individuals.

Язык: Английский

Процитировано

1
Research progress of energetic coordination complexes with laser ignition performance DOI Creative Commons
Jinxin Wang, Qiang Zhang, Haifeng Wang

и другие.

Energetic Materials Frontiers, Год журнала: 2024, Номер unknown

Опубликована: Ноя. 1, 2024

Язык: Английский

Процитировано

1
Synthesis of energetic coordination compounds based on pyrazole and 4-chloropyrazole via co-melting crystallization method DOI
Zujia Lu, Tingwei Wang,

Mou Sun

и другие.

CrystEngComm, Год журнала: 2024, Номер 26(8), С. 1178 - 1188

Опубликована: Янв. 1, 2024

Using pyrazole, 4-chloropyrazole, Cu(NO 3 ) 2 , and Cu(ClO 4 as raw materials, the target crystals of ECCs can be directly obtained by co-melting heating, offering a more efficient alternative to traditional solvent-based preparation methods.

Язык: Английский

Процитировано

0