Eu(III) functionalized ZnMOF based efficient dual-emission sensor integrated with self-calibrating logic gate for intelligent detection of epinephrine

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, Год журнала: 2024, Номер 315, С. 124254 - 124254

Опубликована: Апрель 4, 2024

Язык: Английский

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Ambient conversion of CO₂ and epoxides to cyclic carbonates using 3D amide-functionalized MOFs

Catalysis Science & Technology, Год журнала: 2024, Номер 14(7), С. 1888 - 1901

Опубликована: Янв. 1, 2024

The amide functionalized 3D zinc( ii )-5,5′-(([1,1′-biphenyl]-4,4′-dicarbonyl)bis(azanediyl))diisophthalate framework (Zn-MOF) efficiently catalyzes the fixation of CO 2 into cyclic carbonate under ambient conditions with very low catalyst loading.

Язык: Английский

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Multifunctional Dysprosium(III)–Organic Framework for Efficiently Catalyzing the Cycloaddition of CO₂ and Knoevenagel Condensation under Mild Conditions

ACS Sustainable Chemistry & Engineering, Год журнала: 2023, Номер 11(50), С. 17837 - 17848

Опубликована: Дек. 6, 2023

Two-dimensional (2D) materials with higher order in-plane nanoscale pores play a crucial role in innumerable applications, but their precise and reasonable preparation remains huge challenge. Herein, we report the highly robust 2D dysprosium(III)–organic framework {[Dy(H2BDTP)(DMF)2]·2DMF·3H2O}n (NUC-101) (15.2 × 6.4 Å2) (H5BDTP = 2,6-bis(2,4-dicarboxyphenyl)-4-(2H-tetrazol-5-yl)pyridine). After activation, scarcely reported host [Dy2(H2BDTP)2]n is of great interest due to that it not only contains voids 15.2 11.7 Å3 also functionalized by free carboxyl, pyridinyl, tetrazolyl groups upper lower parts. Thanks excellent physicochemical properties including omnidirectional opening pores, ultrahigh porosity, larger specific surface area, plentiful coexisting Lewis acid–base sites open dinuclear Dy3+ ions, groups, cycloaddition CO2 epoxides Knoevenagel condensation malonitrile aldehydes can be efficiently catalyzed NUC-101a under comparatively mild conditions high selectivity turnover frequency. This work provides valuable insight development nanoporous more feasible for achieving goal catalytic applications.

Язык: Английский

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Bifunctional two-dimensional copper-organic framework for high catalytic performance on cycloaddition of CO2 with epoxides and deacetalization-Knoevenagel condensation

Journal of Molecular Structure, Год журнала: 2024, Номер 1306, С. 137849 - 137849

Опубликована: Фев. 22, 2024

Язык: Английский

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Heterogeneous catalytic conversion of carbon dioxide and epoxides to cyclic carbonates

Surfaces and Interfaces, Год журнала: 2024, Номер 45, С. 103845 - 103845

Опубликована: Янв. 3, 2024

Язык: Английский

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Robust Nitro-Functionalized {Zn₃}-Organic Framework for Excellent Catalytic Performance on Cycloaddition Reaction of CO₂ with Epoxides and Knoevenagel Condensation

Crystal Growth & Design, Год журнала: 2024, Номер 24(8), С. 3473 - 3482

Опубликована: Апрель 8, 2024

Adjusting the Lewis acid–base sites in MOF-based catalysts to meet demand for catalytic CO2 chemical fixation is a huge challenge. Herein, highly robust rectilinear {Zn3}-based metal–organic framework of {[Zn3(TNTNB)2(4,4′-bip)(H2O)2]·5DMF·9H2O}n (NUC-80) was generalized from solvothermal condition (H3TNTNB = 1,3,5-tri(3-nitro-4-carboxyphenyl)-2,4,6-trinitrobenzene, 4,4′-bip 4,4′-bipyridine). Activated NUC-80a not only owns large void volume (58%) and two kinds solvent-accessible channels: rhombic-like (ca. 14.24 × 14.57 Å) along axis rectangular-like 11.72 14.48 b axis, but also functionalized by rich metal plentiful nitro groups on its inner surface. Performed experiments confirmed that could efficiently catalyze cycloaddition reaction with epoxides Knoevenagel condensations aldehydes malononitrile under mild conditions high turnover frequency (TOF). Hence, this work provides nitro-functionalized cluster-based nanoporous wide range potential applications such as catalysis, gas adsorption, separation.

Язык: Английский

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NH2-Functionalized InIIIDyIII−Organic Frameworks for Efficient Catalytic Performance on Chemical Fixation of CO2 and Knoevenagel Condensation

Journal of Molecular Structure, Год журнала: 2025, Номер unknown, С. 141361 - 141361

Опубликована: Янв. 1, 2025

Язык: Английский

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Ultrahigh Stable Heterometallic InCo-Organic Framework for Efficiently Catalyzing Cycloaddition of CO2 with Epoxides and Knoevenagel condensation

Journal of Molecular Structure, Год журнала: 2024, Номер 1318, С. 139223 - 139223

Опубликована: Июль 6, 2024

Язык: Английский

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Robust {Pb₁₀}-Cluster-Based Metal–Organic Framework for Capturing and Converting CO₂ into Cyclic Carbonates under Mild Conditions

Inorganic Chemistry, Год журнала: 2024, Номер 63(30), С. 14183 - 14192

Опубликована: Июль 15, 2024

Developing a highly active catalyst that can efficiently capture and convert carbon dioxide (CO2) into high-value-added energy materials remains severe challenge, which inspires us to explore effective metal–organic frameworks (MOFs) with high chemical stability high-density sites. Herein, we report robust 3D lead(II)-organic framework of {(Me2NH2)2[Pb5(PTTPA)2(H2O)3]·2DMF·3H2O}n (NUC-111) unreported [Pb10(COO)22(H2O)6] clusters (abbreviated as {Pb10}) nodes (H6PTTPA = 4,4′,4″-(pyridine-2,4,6-triyl)triisophthalic acid). After thermal activation, NUC-111a is functionalized by the multifarious symbiotic acid–base sites open Pb2+ uncoordinated pyridine groups on inner surface void volume. Gas adsorption tests confirm displays higher separation performance for mixed gases f CO2 CH4 selectivity CO2/CH4 at 273 K 101 kPa being 31 (1:99, v/v), 23 (15:85, 8 (50:50, respectively. When temperature rises 298 K, 26 22 11 v/v). Moreover, activated exhibited excellent catalytic performance, stability, recyclability cycloaddition epoxides under mild conditions. Hence, this work provides valuable insight designing MOFs multifunctionality capture, separation, conversion.

Язык: Английский

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Review on the recent advances in catalytic conversion of carbon dioxide for synthesis of cyclic propylene carbonate

Molecular Catalysis, Год журнала: 2023, Номер 553, С. 113720 - 113720

Опубликована: Дек. 8, 2023

Язык: Английский

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