Employing Nitrogen–Sulfur Synergy: 1,2,3-Triazole-Thiadiazole-Based Energetic Materials

Organic Letters, Год журнала: 2025, Номер unknown

Опубликована: Март 8, 2025

In this study, we synthesized energetic materials integrating thiadiazole and triazole moieties. The newly developed compounds were thoroughly characterized using NMR, IR, elemental analysis, TGA-DSC, single-crystal X-ray diffraction (for compound 3). These exhibited acceptable properties, including high densities (1.88–1.92 g cm–3), moderate to good detonation performance (VOD: 6383–8128 m s–1), thermal stability (143–238 °C), less sensitivity impact (>15 J) friction (360 N). Notably, 4 8 achieved superior velocities compared nearly all reported sulfur-based date. This work highlights the significance of triazole-thiadiazole frameworks in development fine-tuning materials.

Язык: Английский

Combination of Nitropyrazole and Nitroaminotriazole: A Novel High-Energy Insensitive Energetic Material

Crystal Growth & Design, Год журнала: 2025, Номер unknown

Опубликована: Апрель 28, 2025

Язык: Английский