Energetic Materials Frontiers,
Год журнала:
2020,
Номер
1(1), С. 2 - 15
Опубликована: Июнь 1, 2020
The
research
focus
of
studies
on
energetic
salts
has
been
to
achieve
targeted
synthesis,
structure
and
performance
through
modification
the
organic
anion
cation
by
addition
functional
groups.
In
this
review,
development
direction
trend
synthesis
which
contain
dinitromethyl
groups
are
considered
briefly
from
perspective
structural
design,
strategy
evaluation.
moiety
behaves
as
an
excellent
"explosophore"
in
high
energy
density
materials.
Developing
new
convenient
synthetic
routes
featuring
group
is
great
value
wider
chemistry
community.
As
a
result,
introduction
continued
increase
rapidly.
Crystal Growth & Design,
Год журнала:
2022,
Номер
22(2), С. 954 - 970
Опубликована: Янв. 13, 2022
Crystal
engineering
is
a
highly
efficient
way
to
create
new
materials
with
the
desired
properties.
Energetic
cocrystallization
has
been
thriving
for
∼10
years
since
appearance
of
series
TNT-based
energetic
cocrystals
(ECCs).
ECCs
serve
as
one
important
aspect
crystal
(EMs).
This
article
presents
brief
overview
regarding
component,
intermolecular
interaction,
packing
structure,
main
properties,
and
preparation,
well
theoretical
treatment
some
issues
raised
future
development.
In
most
cases,
properties
an
ECC
are
each
moderated
between
those
pure
components,
setting
basis
tuning
by
existing
molecules,
instead
synthesizing
molecules;
meanwhile,
there
also
exceptions,
such
higher
density,
detonation
or
lower
impact
sensitivity
in
comparison
both
components.
These
exceptions
mutated
will
expand
EMs.
Generally,
currently
staying
at
primary
stage,
much
effort
being
required
solve
urgent
issues,
property
evaluation,
large-scale
fabrication,
applications.
Still,
promising
alternative
EMs
after
all,
it
huge
challenge
synthesize
satisfactory
molecule.
Crystal Growth & Design,
Год журнала:
2024,
Номер
24(16), С. 6790 - 6799
Опубликована: Июль 31, 2024
The
dominance
of
nitro
pyrazole-based
explosives
in
the
recently
reported
high-performing
energetic
materials
motivated
us
to
comprehensively
investigate
energy–stability
correlation
among
different
compounds
based
on
3,5-dinitro
pyrazoles
employing
various
computational
methods.
We
also
explored
and
physicochemical
properties
overlooked
compound
3,5-dinitropyrazole-4-carboxylic
acid
(CDNP).
This
study
revealed
that
CDNP
exhibits
highest
thermal
stability
4-substituted-3,5-dinitropyrazoles,
combined
with
an
acceptable
performance.
These
characteristics
are
attributed
its
layered
packing,
strong
intermolecular
interactions,
carbonyl
bonds.
Furthermore,
dicationic
salt
formation
further
allowed
fine-tune
overall
performance
stability.
dihydroxylammonium
(5)
shows
best
performance,
comparable
well-known
traditional
explosive
TATB,
good
low
sensitivity
toward
impact
friction.
Physical Chemistry Chemical Physics,
Год журнала:
2024,
Номер
26(13), С. 9984 - 9997
Опубликована: Янв. 1, 2024
NNP
models
covering
three
typical
C/H/N/O
element
HEMs
were
developed
to
capture
the
mechanical
and
decomposition
properties
of
RDX,
HMX
CL-20.
The
trajectory
is
mainly
divided
into
two
stages:
pyrolysis
oxidation.
Energetic Materials Frontiers,
Год журнала:
2020,
Номер
1(1), С. 2 - 15
Опубликована: Июнь 1, 2020
The
research
focus
of
studies
on
energetic
salts
has
been
to
achieve
targeted
synthesis,
structure
and
performance
through
modification
the
organic
anion
cation
by
addition
functional
groups.
In
this
review,
development
direction
trend
synthesis
which
contain
dinitromethyl
groups
are
considered
briefly
from
perspective
structural
design,
strategy
evaluation.
moiety
behaves
as
an
excellent
"explosophore"
in
high
energy
density
materials.
Developing
new
convenient
synthetic
routes
featuring
group
is
great
value
wider
chemistry
community.
As
a
result,
introduction
continued
increase
rapidly.
