Chemical Society Reviews,
Год журнала:
2024,
Номер
53(18), С. 9378 - 9418
Опубликована: Янв. 1, 2024
Organic
transformation
by
light-driven
catalysis,
especially,
photocatalysis
and
photothermal
denoted
as
photo(thermal)
is
an
efficient,
green,
economical
route
to
produce
value-added
compounds.
In
recent
years,
owing
their
diverse
structure
types,
tunable
pore
sizes,
abundant
active
sites,
metal-organic
framework
(MOF)-based
catalysis
has
attracted
broad
interest
in
organic
transformations.
this
review,
we
provide
a
comprehensive
systematic
overview
of
MOF-based
for
First,
the
general
mechanisms,
unique
advantages,
strategies
improve
performance
MOFs
are
discussed.
Then,
outstanding
examples
transformations
over
introduced
according
reaction
type.
addition,
several
representative
advanced
characterization
techniques
used
revealing
charge
kinetics
intermediates
presented.
Finally,
prospects
challenges
field
proposed.
This
review
aims
inspire
rational
design
development
materials
with
improved
catalysis.
Chemical Reviews,
Год журнала:
2023,
Номер
123(11), С. 6891 - 6952
Опубликована: Май 3, 2023
All
forms
of
energy
follow
the
law
conservation
energy,
by
which
they
can
be
neither
created
nor
destroyed.
Light-to-heat
conversion
as
a
traditional
yet
constantly
evolving
means
converting
light
into
thermal
has
been
enduring
appeal
to
researchers
and
public.
With
continuous
development
advanced
nanotechnologies,
variety
photothermal
nanomaterials
have
endowed
with
excellent
harvesting
capabilities
for
exploring
fascinating
prospective
applications.
Herein
we
review
latest
progresses
on
nanomaterials,
focus
their
underlying
mechanisms
powerful
light-to-heat
converters.
We
present
an
extensive
catalogue
nanostructured
materials,
including
metallic/semiconductor
structures,
carbon
organic
polymers,
two-dimensional
materials.
The
proper
material
selection
rational
structural
design
improving
performance
are
then
discussed.
also
provide
representative
overview
techniques
probing
photothermally
generated
heat
at
nanoscale.
finally
recent
significant
developments
applications
give
brief
outlook
current
challenges
future
directions
nanomaterials.
ACS Omega,
Год журнала:
2022,
Номер
7(49), С. 44507 - 44531
Опубликована: Дек. 2, 2022
Metal
ions
or
clusters
that
have
been
bonded
with
organic
linkers
to
create
one-
more-dimensional
structures
are
referred
as
metal–organic
frameworks
(MOFs).
Reticular
synthesis
also
forms
MOFs
properly
designated
components
can
result
in
crystals
high
porosities
and
great
chemical
thermal
stability.
Due
the
wider
surface
area,
huge
pore
size,
crystalline
nature,
tunability,
numerous
shown
be
potential
candidates
various
fields
like
gas
storage
delivery,
energy
storage,
catalysis,
chemical/biosensing.
This
study
provides
a
quick
overview
of
current
MOF
techniques
order
familiarize
newcomers
sciences
field
fast-growing
research.
Beginning
classification
nomenclature
MOFs,
approaches
demonstrated.
We
emphasize
applications
such
drug
rechargeable
batteries,
supercapacitors,
separation
membranes.
Lastly,
future
scope
is
discussed
along
prospective
opportunities
for
application
nano-MOFs,
which
will
help
promote
their
uses
multidisciplinary
Materials Horizons,
Год журнала:
2021,
Номер
8(9), С. 2387 - 2419
Опубликована: Янв. 1, 2021
An
emerging
trend
in
the
application
of
metal–organic
frameworks
is
to
engineer
mobile
devices
possess
chemical
detecting
capabilities
for
environmental
monitoring,
point-of-care
testing,
artificial
intelligence,
food
security
and
defence.
Chemical Reviews,
Год журнала:
2023,
Номер
123(16), С. 10432 - 10467
Опубликована: Июль 14, 2023
Metal–organic
frameworks
(MOFs)
and
ionic
liquids
(ILs)
represent
promising
materials
for
adsorption
separation.
ILs
incorporated
into
MOF
(denoted
as
IL/MOF
composites)
have
been
developed,
composites
combine
the
advantages
of
MOFs
to
achieve
enhanced
performance
in
adsorption-based
separation
fluid
mixtures.
The
designed
different
are
introduced
various
tailor
their
functional
properties,
which
affect
optimal
adsorptive
performance.
In
this
Perspective,
rational
fabrication
is
presented,
properties
demonstrated.
This
paper
provides
a
critical
overview
an
emergent
class
termed
well
recent
advances
applications
adsorbents
or
membranes
Furthermore,
gas
separations
(CO2
capture
from
flue
gas,
natural
purification,
acetylene
ethylene,
indoor
pollutants
removal)
liquid
(separation
bioactive
components,
organic-contaminant
removal,
desulfurization,
radionuclide
discussed.
Finally,
existing
challenges
highlighted,
appropriate
design
strategy
direction
effective
exploration
new
proposed.
Chemical Society Reviews,
Год журнала:
2022,
Номер
51(17), С. 7427 - 7508
Опубликована: Янв. 1, 2022
Fluorinated
metal-organic
frameworks
(F-MOFs)
as
fast-growing
porous
materials
have
revolutionized
the
field
of
gas
separation
due
to
their
tunable
pore
apertures,
appealing
chemical
features,
and
excellent
stability.
A
deep
understanding
structure-performance
relationships
is
critical
for
synthesis
development
new
F-MOFs.
This
review
has
focused
on
several
strategies
precise
design
F-MOFs
with
structures
tuned
specific
purposes.
First,
basic
principles
concepts
well
structure,
modification
structure
property
are
studied.
Then,
applications
in
adsorption
membrane
discussed.
detailed
account
capabilities
various
gases
governing
provided.
In
addition,
exceptional
characteristics
highly
stable
engineered
size
put
into
perspective
fabricate
selective
membranes
separation.
Systematic
analysis
position
revealed
that
benchmark
most
challenging
separations.
The
outlook
future
directions
science
engineering
challenges
highlighted
tackle
issues
overcoming
trade-off
between
capacity/permeability
selectivity
a
serious
move
towards
industrialization.
ACS Nano,
Год журнала:
2022,
Номер
16(2), С. 1759 - 1780
Опубликована: Янв. 20, 2022
A
highly
effective
electrocatalyst
is
the
central
component
of
advanced
electrochemical
energy
conversion.
Recently,
two-dimensional
conjugated
metal-organic
frameworks
(2D
c-MOFs)
have
emerged
as
a
class
promising
electrocatalysts
because
their
advantages
including
2D
layered
structure
with
high
in-plane
conjugation,
intrinsic
electrical
conductivity,
permanent
pores,
large
surface
area,
chemical
stability,
and
structural
diversity.
In
this
Review,
we
summarize
recent
advances
c-MOF
for
First,
introduce
design
principles
synthetic
strategies
reported
c-MOFs,
well
functional
electrocatalysis.
Subsequently,
present
representative
in
various
reactions,
such
hydrogen/oxygen
evolution,
reduction
reactions
oxygen,
carbon
dioxide,
nitrogen.
We
highlight
property
tuning
to
boost
catalytic
performance,
offer
our
perspectives
regard
challenges
be
overcome.
Advanced Materials,
Год журнала:
2023,
Номер
35(10)
Опубликована: Янв. 2, 2023
The
highly
selective
photoreduction
of
CO2
into
valuable
small-molecule
chemical
feedstocks
such
as
CO
is
an
effective
strategy
for
addressing
the
energy
crisis
and
environmental
problems.
However,
it
remains
a
challenge
because
complex
process
usually
generates
multiple
possible
products
requires
subsequent
separation
step.
In
this
paper,
2D
monolayer
bilayer
porphyrin-based
metal-organic
frameworks
(MOFs)
are
successfully
constructed
by
adjusting
reaction
temperature
solvent
polarity
with
5,10,15,20-tetrakis(4-pyridyl)porphyrin
light-harvesting
ligand.
MOF
low-dimensional
special
structure
in
which
upper
lower
layers
arranged
dislocation
bridged
halogen
ions.
This
exhibits
100%
ultra-high
selectivity
reduction
to
under
simulated
sunlight
without
any
cocatalyst
or
photosensitizer
can
be
recycled
at
least
three
times.
intrinsic
mechanism
photocatalytic
explored
through
experimental
characterization
density
functional
theory
(DFT)
calculations.
work
shows
that
rational
design
number
structures
tune
stability
these
opens
new
avenue
photocatalysts.
Chemical Science,
Год журнала:
2022,
Номер
13(47), С. 13978 - 14007
Опубликована: Янв. 1, 2022
MOF-based
optical
sensors
can
achieve
volatile
organic
compound
sensing
via
different
mechanisms:
colorimetric
sensing,
luminescent
and
optical-index
modulation
sensing.
