Communications Materials, Год журнала: 2025, Номер 6(1)
Опубликована: Апрель 4, 2025
Язык: Английский
Chemical Reviews, Год журнала: 2024, Номер 124(13), С. 8011 - 8013
Опубликована: Июль 10, 2024
Язык: Английский
Процитировано
8
Nature Communications, Год журнала: 2024, Номер 15(1)
Опубликована: Июль 16, 2024
Abstract The Mn 4 CaO 5(6) cluster in photosystem II catalyzes water splitting through the S i state cycle ( = 0–4). Molecular O 2 is formed and natural catalyst reset during final 3 → (S ) 0 transition. Only recently experimental breakthroughs have emerged for this transition but without explicit information on -state reconstitution, thus progression after release remains elusive. In report, our molecular dynamics simulations combined with density functional calculations suggest a likely missing link closing cycle, i.e., restoring first catalytic state. Specifically, formation of closed-cubane intermediates all hexa-coordinate observed, which would undergo proton release, dissociation, ligand transfer to produce open-cubane structure Thereby, we theoretically identify previously unknown structural isomerism that acts as origin proposed flexibility prevailing may be functionally important nature’s oxidation catalysis.
Язык: Английский
Процитировано
8
Journal of the American Chemical Society, Год журнала: 2024, Номер unknown
Опубликована: Окт. 4, 2024
Photocatalysis is an intricate process that involves a multitude of physical and chemical factors operating across diverse temporal spatial scales. Identifying the dominant influence photocatalyst performance one central challenges in field. Here, we synthesized series perovskite RTaON
Язык: Английский
Процитировано
4
Sensing and Bio-Sensing Research, Год журнала: 2025, Номер unknown, С. 100736 - 100736
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
0
Analytical Chemistry, Год журнала: 2025, Номер unknown
Опубликована: Фев. 25, 2025
With the growing demand for highly efficient sensors capable of rapid and reliable detection trap states in semiconductors, developing novel chemical physical phenomena induced by at nanomaterial interfaces has thus emerged as a critical technological field. Herein, we developed an innovative time-dependent chemiluminescence (CL) method evaluating semiconductor materials. By leveraging unique Cr3+-activated zinc gallate (ZGOC) semiconductors hydroxyl radical (·OH)-rich EDTA-Fe2+-H2O2 system, achived rational manipulation ·OH-triggered near-infrared (NIR) CL induction. To extract high-information-density outputs from response, ZGOC nanocrystals associated with different Cr3+-related were precisely identified distinct "fingerprint" pattern robust statistical analysis. Remarkably, generalizability this was validated using mixed models containing two typical samples other adjustable systems. The probe state evaluation provides advantages such cost-effectiveness, operational simplicity, offering promising alternative to conventional assessment methods.
Язык: Английский
Процитировано
0
ChemCatChem, Год журнала: 2025, Номер unknown
Опубликована: Март 5, 2025
Abstract Photoelectrochemical (PEC) and photocatalytic (PC) reactions offer promising pathways toward the efficient conversion of intermittent solar energy into high value‐added chemicals. To improve efficiency energy, rational modulation both light absorbers surface sites is required for sunlight‐harvesting capacity reaction activity, yet depending on a comprehensive understanding process. In this regard, X‐ray absorption spectroscopy (XAS) plays critical role in probing electronic geometric structures active materials PEC PC reactions, thereby revealing related structure‒activity relationships providing guide further structural modulation. This review begins with principles PEC/PC reactions. The fundamental knowledge XAS then introduced, including basics near edge structure (XANES) extended fine (EXAFS), general experimental methods, situ technique. Furthermore, we provide several examples to illustrate how can be utilized reveal (e.g., water splitting, CO 2 reduction, N fixation). Finally, major challenges future opportunities exciting field are highlighted.
Язык: Английский
Процитировано
0
Materials Today, Год журнала: 2025, Номер unknown
Опубликована: Май 1, 2025
Язык: Английский
Процитировано
0
Journal of Alloys and Compounds, Год журнала: 2025, Номер unknown, С. 178622 - 178622
Опубликована: Янв. 1, 2025
Язык: Английский
Процитировано
0
Photochemistry and Photobiology, Год журнала: 2025, Номер unknown
Опубликована: Фев. 13, 2025
Abstract Chlorophyll(Chl)‐ a derivatives inserting an ethynylene‐naphthylene linker between the chlorin π‐skeleton and hydroxymethyl group were prepared as models of chlorosomal Chls. Their syntheses achieved via Sonogashira coupling reaction. J ‐aggregation behaviors investigated by electronic absorption circular dichroism spectroscopic measurements. These studies revealed that 2,6‐naphthylene inserted Chl‐ gave single species in aqueous Triton X‐100 micellar solution with larger red‐shift value (1270 cm −1 ) Qy band spite its longer compared p ‐phenylene derivative (970 ). unique optical properties also discussed based on computational studies, which indicated different positional relation rings assemblies structure.
Язык: Английский
Процитировано
0
Communications Materials, Год журнала: 2025, Номер 6(1)
Опубликована: Апрель 4, 2025
Язык: Английский
Процитировано
0