Ultrahigh Peroxymonosulfate Utilization Efficiency over CuO Nanosheets via Heterogeneous Cu(III) Formation and Preferential Electron Transfer during Degradation of Phenols

Environmental Science & Technology, Год журнала: 2022, Номер 56(12), С. 8984 - 8992

Опубликована: Май 31, 2022

In persulfate activation by copper-based catalysts, high-valent copper (Cu(III)) is an overlooked reactive intermediate that contributes to efficient utilization and organic pollutant removal. However, the mechanisms underlying heterogeneous enhanced are not fully understood. Here, oxide (CuO) nanosheets (synthesized with a facile precipitation method) exhibited high catalytic activity for peroxymonosulfate (PMS) 100% 4-chlorophenol (4-CP) degradation within 3 min. Evidence critical role of surface-associated Cu(III) on PMS 4-CP over wide pH range (pH 3-10) was obtained using in situ Raman spectroscopy, electron paramagnetic resonance, quenching tests. directly oxidized other phenolic pollutants, rate constants inversely proportional their ionization potentials. preferentially oxidizes rather than react two molecules generate one molecule 1O2, thus minimizing this less pathway. Accordingly, much higher efficiency (77% electrons accepted ascribed mineralization) CuO/PMS radical pathway-dominated Co3O4/PMS system (27%) or 1O2 α-MnO2/PMS (26%). Overall, these results highlight potential benefits via oxidation offer mechanistic insight into ultrahigh

Язык: Английский

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Oxygen vacancies-enriched Cu/Co bimetallic oxides catalysts for high-efficiency peroxymonosulfate activation to degrade TC: Insight into the increase of Cu+ triggered by Co doping

Chemical Engineering Journal, Год журнала: 2022, Номер 450, С. 138302 - 138302

Опубликована: Июль 25, 2022

Язык: Английский

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Generation and identification of 1O2 in catalysts/peroxymonosulfate systems for water purification

Water Research, Год журнала: 2023, Номер 245, С. 120614 - 120614

Опубликована: Сен. 11, 2023

Язык: Английский

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Fe-Mn oxycarbide anchored on N-doped carbon for enhanced Fenton-like catalysis: Importance of high-valent metal-oxo species and singlet oxygen

Applied Catalysis B Environment and Energy, Год журнала: 2023, Номер 340, С. 123204 - 123204

Опубликована: Авг. 22, 2023

Язык: Английский

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Facet-dependent CuO/{010}BiVO4 S-scheme photocatalyst enhanced peroxymonosulfate activation for efficient norfloxacin removal

Journal of Material Science and Technology, Год журнала: 2023, Номер 174, С. 30 - 43

Опубликована: Май 19, 2023

Язык: Английский

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Petal-like CuCo2O4 spinel nanocatalyst with rich oxygen vacancies for efficient PMS activation to rapidly degrade pefloxacin

Separation and Purification Technology, Год журнала: 2022, Номер 291, С. 120933 - 120933

Опубликована: Март 26, 2022

Язык: Английский

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Homogeneous/heterogeneous metal-catalyzed persulfate oxidation technology for organic pollutants elimination: A review

Journal of environmental chemical engineering, Год журнала: 2023, Номер 11(3), С. 109586 - 109586

Опубликована: Фев. 28, 2023

Язык: Английский

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Selective activation of peroxymonosulfate govern by B-site metal in delafossite for efficient pollutants degradation: Pivotal role of d orbital electronic configuration

Water Research, Год журнала: 2023, Номер 236, С. 119957 - 119957

Опубликована: Апрель 8, 2023

Язык: Английский

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Photocatalysis toward Microplastics Conversion: A Critical Review

ACS Catalysis, Год журнала: 2024, Номер 14(11), С. 8694 - 8719

Опубликована: Май 20, 2024

Microplastics (MPs, particle size < 5 mm) have become increasingly ubiquitous on Earth due to the cleavage and degradation of heavy use plastics. MPs recently been reported be detected in human blood, alveoli, breast milk, embryos, other organs, raising concerns about their environmental risks. Photocatalysis has identified as a potential means for conversion, which utilizes solar energy stimulate semiconductor photocatalyst. However, study photocatalytic conversion is still incubation period. This review overviews current state-of-the-art technologies conversion. Then, fundamental principles, challenges, analytical techniques, evaluation indexes reforming are highlighted. We systematically summarized recent advances key factors influencing performance. Finally, we propose some perspectives developing efficient systems MPs. will provide guideline applying technology MPs, significantly contribute this emerging research field.

Язык: Английский

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Anchored Cobalt Nanoparticles on Layered Perovskites for Rapid Peroxymonosulfate Activation in Antibiotic Degradation

Advanced Materials, Год журнала: 2024, Номер 36(27)

Опубликована: Апрель 16, 2024

Abstract In the Fenton‐like reaction, revealing dynamic evolution of active sites is crucial to achieve activity improvement and stability catalyst. This study reports a perovskite oxide in which atomic (Co 0 ) situ embedded exsolution occurs during high‐temperature phase transition. unique anchoring strategy significantly improves Co 3+ /Co 2+ cycling efficiency at interface inhibits metal leaching peroxymonosulfate (PMS) activation. The Co@L‐PBMC catalyst exhibits superior PMS activation ability could 99% degradation tetracycline within 5 min. combination experimental characterization density functional theory (DFT) calculations elucidates that electron‐deficient oxygen vacancy accepts an electron from 3d‐orbital, resulting significant delocalization site, thereby facilitating adsorption *HSO /*OH intermediate onto “metal‐V O bridge” structure. work provides insights into mechanism level, will guide rational design next‐generation catalysts for environmental remediation.

Язык: Английский

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