The Science of The Total Environment, Год журнала: 2024, Номер 921, С. 170318 - 170318
Опубликована: Янв. 25, 2024
Язык: Английский
The Science of The Total Environment, Год журнала: 2024, Номер 921, С. 170318 - 170318
Опубликована: Янв. 25, 2024
Язык: Английский
npj Climate and Atmospheric Science, Год журнала: 2025, Номер 8(1)
Опубликована: Май 9, 2025
Язык: Английский
Процитировано
0Toxics, Год журнала: 2024, Номер 12(2), С. 105 - 105
Опубликована: Янв. 26, 2024
Sulfate (SO42−) is an essential chemical species in atmospheric aerosols and plays influential role their physical–chemical characteristics. The mechanisms of secondary SO42− aerosol have been intensively studied air-polluted cities. However, few studies focused on cities with good air quality. One-year PM2.5 samples were collected the tropical island city Haikou, water-soluble inorganic ions, as well Fe Mn, analyzed. results showed that non-sea-salt (nss-SO42−) was dominant accounting for 40–57% total ions Haikou. S(IV)+H2O2 pathway main formation wintertime contributing to 57% formation. By contrast, 54% produced by S(IV)+Fe×Mn summer. In spring autumn, S(IV)+H2O2, S(IV)+Fe×Mn, S(IV)+NO2 pathways contributed equally ionic strength controlling parameter pathway, while pH identified a key factor mediates produce SO42−. This study contributes our understanding production under low concentrations but high percentages.
Язык: Английский
Процитировано
3PNAS Nexus, Год журнала: 2024, Номер 3(8)
Опубликована: Июль 25, 2024
Abstract Atmospheric sulfate aerosols contribute significantly to air pollution and climate change. Sulfate formation mechanisms during winter haze events in northern China have recently received considerable attention, with more than 10 studies published high-impact journals. However, the conclusions from in-field measurements, laboratory studies, numerical simulations are inconsistent even contradictory. Here, we propose a physically based yet simple method clarify debate on dominant pathway. Based hazes evolving synoptic scale, first, characteristic rate is derived using Eulerian mass conservation equation constrained by situ observations. Then, this value treated as guideline determine pathway 0D chemical box model. Our observation-derived results establish linkage between experiments transport model simulations. A convergent understanding could therefore be reached China's wintertime haze. This universal can applied various conditions different secondary products.
Язык: Английский
Процитировано
3The Science of The Total Environment, Год журнала: 2023, Номер 880, С. 163234 - 163234
Опубликована: Апрель 4, 2023
Язык: Английский
Процитировано
8The Science of The Total Environment, Год журнала: 2024, Номер 921, С. 170318 - 170318
Опубликована: Янв. 25, 2024
Язык: Английский
Процитировано
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